]*>","")" /> 离子液体催化丙烯腈氯化合成2,3-二氯丙腈
催化学报

催化学报 ›› 2006, Vol. 27 ›› Issue (2): 106-108.

• 研究快讯 • 上一篇    下一篇

离子液体催化丙烯腈氯化合成2,3-二氯丙腈

李雪辉,郑宾国,赵荆感   

  1. 华南理工大学化学工程系, 广东省绿色化学产品技术重点实验室, 广东广州 5106400
  • 收稿日期:2006-02-25 出版日期:2006-02-25 发布日期:1985-02-26

  • Received:2006-02-25 Online:2006-02-25 Published:1985-02-26

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1126

被引次数

31

摘要： Ionic liquids formed by imidazolium and pyridinium cations with Cl-, Br-, BF-4, and PF-6 anions were used for the catalytic synthesis of 2,3-dichloropropionitrile by the chlorination of acrylonitrile. The ionic liquids containing Cl- and Br- show good catalytic properties. The Cl- and Br- ions act as strong Lewis bases and molecular chlorine is activated by the induction effect of Cl- and Br-. Due to the stronger steric hindrance effect of the BF-4 and PF-6 anions, the chlorination of acrylonitrile is limited in the ionic liquids containing BF-4 and PF-6 anions.

关键词: 离子液体, 丙烯腈, 催化氯化, 3-二氯丙腈