催化学报

催化学报 ›› 2008, Vol. 29 ›› Issue (9): 831-838.

• 综述 • 上一篇    下一篇

二氧化碳与环氧化合物合成环状碳酸酯的研究进展

高志文1,肖林飞1,2,陈静1,夏春谷1   

  1. 1 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室, 甘肃兰州 730000; 2 黑龙江大学化学化工与材料学院, 黑龙江哈尔滨 150080
  • 收稿日期:2008-09-25 出版日期:2008-09-25 发布日期:2012-07-19

Recent Advances in the Synthesis of Cyclic Carbonates from Carbon Dioxide and Epoxides

GAO Zhiwen1, XIAO Linfei1,2*, CHEN Jing1, XIA Chungu1*   

  1. 1 State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, Gansu, China; 2 College of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, Heilongjiang, China
  • Received:2008-09-25 Online:2008-09-25 Published:2012-07-19

PDF

2543

被引次数

86

摘要： 二氧化碳作为温室气体和储量大、无毒且可循环利用的碳资源,其化学利用受到了人们的广泛关注. 二氧化碳与环氧化合物通过环加成反应制备环状碳酸酯是二氧化碳化学法利用最为有效的途径之一. 本文综述了近年来该反应的研究进展,讨论了催化剂作用下的反应机理.

关键词: 二氧化碳, 环氧化合物, 环状碳酸酯, 离子液体

Abstract: The synthesis of cyclic carbonate from carbon dioxide and epoxides is one of t he most effective routes for chemical utilization of carbon dioxide as a C1 buildi ng block. The latest progress in the synthesis of cyclic carbonate from carbon d ioxide and epoxides was reviewed and the catalytic reaction mechanism was discus sed.

Key words: carbon dioxide, epoxide, cyclic carbonate, ionic liquid