Amberlite IR-120：一种可重复利用的微波辅助条件下胺类化合物与甲酸N-甲酰化反应的催化剂

催化学报 ›› 2010, Vol. 31 ›› Issue (5): 518-520.

Amberlite IR-120：一种可重复利用的微波辅助条件下胺类化合物与甲酸N-甲酰化反应的催化剂

Madhusudana Reddy MVTHUKUR BHOJEGOWD, Aatika NIZAM, Mohamed Afzal PASHA*

Department of Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru 560 001, India

收稿日期:2010-05-25 出版日期:2010-05-25 发布日期:2013-12-05

Amberlite IR-120: A Reusable Catalyst for N-Formylation of Amines with Formic Acid Using Microwaves

Madhusudana Reddy MVTHUKUR BHOJEGOWD, Aatika NIZAM, Mohamed Afzal PASHA*

Department of Studies in Chemistry, Central College Campus, Bangalore University, Bengaluru 560 001, India

Received:2010-05-25 Online:2010-05-25 Published:2013-12-05

摘要/Abstract

摘要： A rapid and practical green route for the N-formylation of amines with formic acid using Amberlite IR-120 as a catalyst is described. This method provides an efficient and much improved modification over the reported methods in terms of yield, reaction time, and work-up procedure. A wide variety of substituents is tolerated, which is not the case for existing procedures.

关键词: N-formylation, Amberlite IR-120, formic acid, amine, microwave

Abstract: The report presents a simple and efficient method for the N-formylation of amines with formic acid using Amberlite IR-120 as the catalyst. The highlighting features are excellent yields, short reaction time, and use of a recyclable catalyst.

Key words: N-formylation, Amberlite IR-120, formic acid, amine, microwave

Madhusudana Reddy MVTHUKUR BHOJEGOWD;Aatika NIZAM;Mohamed Afzal PASHA*. Amberlite IR-120：一种可重复利用的微波辅助条件下胺类化合物与甲酸N-甲酰化反应的催化剂[J]. 催化学报, 2010, 31(5): 518-520.

Madhusudana Reddy MVTHUKUR BHOJEGOWD;Aatika NIZAM;Mohamed Afzal PASHA*. Amberlite IR-120: A Reusable Catalyst for N-Formylation of Amines with Formic Acid Using Microwaves[J]. Chinese Journal of Catalysis, 2010, 31(5): 518-520.

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