催化学报

催化学报 ›› 2007, Vol. 28 ›› Issue (9): 749-751.

• 研究快讯 •    下一篇

直接氨固体氧化物燃料电池

张丽敏1,2,丛铀1,杨维慎1,林励吾1   

  1. 1 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连 116023; 2 中国科学院研究生院, 北京 100049
  • 收稿日期:2007-09-25 出版日期:2007-09-25 发布日期:2011-09-28

A Direct Ammonia Tubular Solid Oxide Fuel Cell

ZHANG Limin1,2, CONG You1, YANG Weishen1*, LIN Liwu1   

  1. 1 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2007-09-25 Online:2007-09-25 Published:2011-09-28

PDF

1288

被引次数

8

摘要： 塑性挤压成型阳极支撑管,采用真空浸涂法在阳极表面制备了均一、致密的氧化钇稳定的氧化锆电解质层,然后在电解质表面刷涂上阴极层,成功制备了阳极支撑型管状固体氧化物燃料电池. 分别以氢气和氨气为燃料,考察了该管状固体氧化物燃料电池的电池性能. 在800 ℃操作时,以氢气和氨气为燃料的电池最大输出功率密度分别为202和200 mW/cm2. 表明氨气可以作为固体氧化物燃料电池的替代燃料.

关键词: 氨气, 真空浸涂, 阳极支撑管, 固体氧化物燃料电池

Abstract: A Ni-anode-supported tubular solid oxide fuel cell (SOFC) with a dense yttria-stabilized zirconia (YSZ) thin film was fabricated. The YSZ film was prepared using the vacuum-assisted dip-coating method. The performance of the single SOFC-based system running on ammonia was compared with that running on hydrogen. At 800 ℃, the peak power densities were 202 and 200 mW/cm2 with hydrogen and ammonia as the fuel, respectively. A GC analysis of the effluent from the anode showed considerable amounts of nitrogen and hydrogen, but no trace of NOx, when using ammonia as the fuel. The ammonia performance is comparable to hydrogen, suggesting that ammonia can be an attractive alternative fuel.

Key words: ammonia, vacuum-assisted dip-coating, anode-supported tube, solid oxide fuel cell