无溶剂条件下锰 (Ⅲ)-席夫碱配合物催化过氧化氢氧化醇

催化学报 ›› 2010, Vol. 31 ›› Issue (6): 615-618.

无溶剂条件下锰 (Ⅲ)-席夫碱配合物催化过氧化氢氧化醇

Hamid GOLCHOUBIAN1,*, Seyyed Ebrahim BABAEI2

1Department of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran;2Departmant of Chemistry, Islamic Azad University-Ghaemshahr Branch, Ghaemshahr, Iran

收稿日期:2010-06-25 出版日期:2010-06-25 发布日期:2013-12-05

Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant

Hamid GOLCHOUBIAN1,*, Seyyed Ebrahim BABAEI2

1Department of Chemistry, University of Mazandaran, Babolsar 47416-95447, Iran;2Departmant of Chemistry, Islamic Azad University-Ghaemshahr Branch, Ghaemshahr, Iran

Received:2010-06-25 Online:2010-06-25 Published:2013-12-05

摘要/Abstract

摘要： Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(III) Schiff-base complex as a catalyst under solvent-free conditions. The oxidation of alcohols occurred at 50 °C to give the corresponding ketones or carboxylic acids with a yield higher than 60%.

关键词: alcohol, oxidation, hydrogen peroxide, Schiff-base complex, Mn(III) complex, ketone

Abstract: Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(III) Schiff-base complex as a catalyst under solvent-free conditions. The oxidation of alcohols occurred at 50 °C to give the corresponding ketones or carboxylic acids with a yield higher than 60%.

Key words: alcohol, oxidation, hydrogen peroxide, Schiff-base complex, Mn(III) complex, ketone

Hamid GOLCHOUBIAN;*;Seyyed Ebrahim BABAEI. 无溶剂条件下锰 (Ⅲ)-席夫碱配合物催化过氧化氢氧化醇[J]. 催化学报, 2010, 31(6): 615-618.

Hamid GOLCHOUBIAN;*;Seyyed Ebrahim BABAEI. Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant[J]. Chinese Journal of Catalysis, 2010, 31(6): 615-618.

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