催化学报

催化学报 ›› 2010, Vol. 31 ›› Issue (6): 677-682.

• 研究论文 • 上一篇    下一篇

氮化硼载体对 Ru-Ba/BN 氨合成催化剂性能的影响

徐春凤, 欧阳亮, 张佳, 周斌, 李瑛, 刘化章   

  1. 浙江工业大学工业催化研究所, 绿色化学合成技术国家重点实验室培育基地, 浙江杭州 310032
  • 收稿日期:2010-06-25 出版日期:2010-06-25 发布日期:2013-12-05

Effect of Boron Nitride Support on Catalytic Activity of Ru-Ba/BN for Ammonia Synthesis

XU Chunfeng, OUYANG Liang, ZHANG Jia, ZHOU Bin, LI Ying*, LIU Huazhang   

  1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Institute of Industry Catalysis, Zhejiang University of Technology, Hangzhou 310032, Zhejiang, China
  • Received:2010-06-25 Online:2010-06-25 Published:2013-12-05

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1252

被引次数

32

摘要： 研究了不同方法合成的氮化硼 (BN) 的性质及其负载的 Ru-Ba 催化剂对氨合成的催化性能. 采用 X 射线粉末衍射、N2 吸附-脱附、扫描电镜和傅里叶变换红外光谱等手段对所合成的 BN 样品进行了表征. 结果表明, 采用程序升温氮化和程序升温还原法均能在低于 900 oC 的条件下合成出较纯的六方相 BN, 其比表面积分别达到 103 和 138 m2/g. 其中前者负载 Ru-Ba 的催化剂活性更高, 在 475 oC, 10 MPa 和 10 000 h–1 的条件下出口氨浓度达 7.3%, 且在 550 oC 热处理 30 h 后, 活性基本保持不变.

关键词: 程序升温氮化, 程序升温还原, 钌, 钡, 氮化硼, 负载型催化剂, 氨合成

Abstract: Boron nitride (BN) nanoparticles with high surface area were prepared by temperature-programmed nitridation and temperature-programmed reduction methods. The catalytic activity of the Ru-Ba/BN ammonia synthesis catalyst was studied. Characterizations by X-ray diffraction, N2 adsorption-desorption, scanning electron microscopy, and Fourier transform infrared spectroscopy were performed to study the crystalline structure, pore structure, and surface properties of the BN material. The characterization results showed that using the above two methods can prepare hexagonal boron nitride with higher surface area, being 103 and 138 m2/g, respectively. The outlet ammonia concentration reached 7.3% under the conditions of 475 oC, 10 MPa, and 10 000 h–1 for the Ru-Ba/BN catalyst, and the activity was stable after thermal treatment at 550 oC for 30 h.

Key words: temperature-programmed nitridation, temperature-programmed reduction, ruthenium, barium, boron nitrite, supported catalyst, ammonia synthesis