催化学报

催化学报 ›› 2009, Vol. 30 ›› Issue (12): 1222-1226.

• 研究论文 • 上一篇    下一篇

磷钼杂多酸离子液体催化氧化脱硫

安莹, 陆亮, 李才猛, 程时富, 高国华   

  1. 华东师范大学化学系, 上海市绿色化学与化工过程绿色化重点实验室, 上海 200062
  • 收稿日期:2009-12-25 出版日期:2009-12-25 发布日期:2013-09-29

Oxidative Desulfurization Catalyzed by Molybdophosphate-Based Ionic Liquid

AN Ying, LU Liang, LI Caimeng, CHENG Shifu, GAO Guohua*   

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, Shanghai 200062, China
  • Received:2009-12-25 Online:2009-12-25 Published:2013-09-29

PDF

1520

被引次数

104

摘要： 合成了新型的磷钼杂多酸离子液体 [hmim]3PMo12O40, 并将其用于室温离子液体 1-甲基咪唑四氟硼酸盐 ([hmim]BF4) 为溶剂的模拟油品氧化脱硫反应. 结果表明, 在温和的反应条件下, 过氧化氢与硫摩尔比为 4:1 时, 二苯并噻吩脱硫率为 90%, 二苯硫醚、苯甲硫醚和二乙硫醚的脱除率可达 100%. 离子液体催化体系循环使用 4 次后, 脱硫率没有明显下降.

关键词: 磷钼杂多酸离子液体, 二苯并噻吩, 过氧化氢, 氧化脱硫

Abstract: Oxidative desulfurization of dibenzothiophene and other sulfides in ionic liquid for model oil was investigated over molybdophosphate-based ionic liquid [hmim]3PMo12O40. Under the mild conditions, high desulfurization was obtained for dibenzothiophene (90%) and dialkyl sulfides (100%). The effects of catalyst, reaction temperature, and amount of H2O2 were investigated. The ionic liquid can be recycled 4 times without a significant decrease in activity.

Key words: molybdophosphate-based ionic liquid, dibenzothiophene, hydrogen peroxide, oxidative desulfurization