催化学报

催化学报 ›› 2010, Vol. 31 ›› Issue (8): 895-911.DOI: 10.3724/SP.J.1088.2010.00450

• 综述 • 上一篇    下一篇

反应控制相转移催化研究的进展

李军, 高爽, 奚祖威   

  1. 中国科学院大连化学物理研究所, 辽宁大连 116023
  • 收稿日期:2010-04-28 出版日期:2010-08-30 发布日期:2013-12-26
  • 通讯作者: 高爽

Progress in Reaction-Controlled Phase-Transfer Catalysis

LI Jun, GAO Shuang*, XI Zuwei   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China
  • Received:2010-04-28 Online:2010-08-30 Published:2013-12-26

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被引次数

61

摘要： 反应控制相转移催化是近年来发展起来的一类新的催化体系.??该催化体系在反应过程中具有均相催化的本征,?当反应结束后,?催化剂发生相的变化而从反应介质中析出,?从而可实现催化剂的分离和循环使用.??本文就反应控制相转移催化原理及其在烯烃环氧化、醇氧化、烯烃断键氧化、苯羟基化、硒催化羰基化和酯化反应等方面应用的最新进展进行了综述.?

关键词: 反应控制相转移催化, 氧化, 过氧化氢, 羰基化, 酯化

Abstract: Reaction-controlled phase-transfer catalysis is a new catalytic system. This catalytic system is homogeneous during the reaction. After the reaction the catalyst becomes insoluble solid and precipitates from the reaction medium, so that the catalyst can be easily separated and reused. This paper presents recent progress made in reaction-controlled phase transfer catalysis for the epoxidation of olefins, oxidation of alcohols, hydroxylation, reductive carbonylation of nitroaromatics, esterification, and other reactions by us and other groups.

Key words: reaction-controlled phase-transfer catalysis, oxidation, hydrogen peroxide, carbonylation, esterification