Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide

催化学报 ›› 2010, Vol. 31 ›› Issue (12): 1427-1432.

Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide

Arash SHOKROLAHI*, Abbas ZALI, Mohammad Hossein KESHAVARZ

Chemistry Department, Malek-Ashtar University of Technology, Shahin-Shahr, P.O.Box 83145-115, Iran

收稿日期:2010-05-19 出版日期:2010-12-13 发布日期:2014-04-26

Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide

Arash SHOKROLAHI*, Abbas ZALI, Mohammad Hossein KESHAVARZ

Chemistry Department, Malek-Ashtar University of Technology, Shahin-Shahr, P.O.Box 83145-115, Iran

Received:2010-05-19 Online:2010-12-13 Published:2014-04-26

摘要/Abstract

摘要： The oxidation of organic compounds by sulfonated porous carbon and H2O2 was studied at room temperature. Alkyl and aryl sulfides were oxidized to the corresponding sulfoxides or sulfones in excellent yields. Secondary alcohols were also converted to the corresponding esters/lactones and aldehydes to methyl esters in good yields. Moreover, aliphatic tertiary amines and substituted pyridines were oxidized to N-oxides.

关键词: sulfonated porous carbon, oxidation, hydrogen peroxide, sulfoxides, sulfones, ester, N-oxide

Abstract: The oxidation of organic compounds by sulfonated porous carbon and H2O2 was studied at room temperature. Alkyl and aryl sulfides were oxidized to the corresponding sulfoxides or sulfones in excellent yields. Secondary alcohols were also converted to the corresponding esters/lactones and aldehydes to methyl esters in good yields. Moreover, aliphatic tertiary amines and substituted pyridines were oxidized to N-oxides.

Key words: sulfonated porous carbon, oxidation, hydrogen peroxide, sulfoxides, sulfones, ester, N-oxide

Arash SHOKROLAHI*, Abbas ZALI, Mohammad Hossein KESHAVARZ. Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide[J]. 催化学报, 2010, 31(12): 1427-1432.

Arash SHOKROLAHI*, Abbas ZALI, Mohammad Hossein KESHAVARZ. Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide[J]. Chinese Journal of Catalysis, 2010, 31(12): 1427-1432.

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Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide

Oxidation of Organic Compounds by Sulfonated Porous Carbon and Hydrogen Peroxide

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