Recent Developments in the Catalytic Conversion of Cellulose into Valuable Chemicals

doi:10.1016/S1872-2067(10)60232-X

摘要/Abstract

摘要： Currently, under huge pressure from energy demands and environmental problems, much attention is being paid to biomass conversion, which will play an important role in meeting the requirements for a sustainable society. As the most abundant biomass on earth, cellulose is usually used as the first research target for biomass conversion. In this review, the recalcitrant structure of cellulose is discussed and non-catalytic hydrolysis by hot-compressed water and catalytic hydrolysis using solid acids are then considered. We also review the catalytic conversion of cellulose into valuable chemicals including hexitols (sorbitol and mannitol), ethylene glycol, and related compounds using various heterogeneous catalysts.

关键词: biomass, cellulose, heterogeneous catalyst, glucose, sorbitol, hot-compressed water, hydrolysis, hydrogenation

Abstract: Currently, under huge pressure from energy demands and environmental problems, much attention is being paid to biomass conversion, which will play an important role in meeting the requirements for a sustainable society. As the most abundant biomass on earth, cellulose is usually used as the first research target for biomass conversion. In this review, the recalcitrant structure of cellulose is discussed and non-catalytic hydrolysis by hot-compressed water and catalytic hydrolysis using solid acids are then considered. We also review the catalytic conversion of cellulose into valuable chemicals including hexitols (sorbitol and mannitol), ethylene glycol, and related compounds using various heterogeneous catalysts.

Key words: biomass, cellulose, heterogeneous catalyst, glucose, sorbitol, hot-compressed water, hydrolysis, hydrogenation

Pengfei YANG, Hirokazu KOBAYASHI, Atsushi FUKUOKA. Recent Developments in the Catalytic Conversion of Cellulose into Valuable Chemicals[J]. 催化学报, 2011, 32(5): 716-722.

Pengfei YANG, Hirokazu KOBAYASHI, Atsushi FUKUOKA. Recent Developments in the Catalytic Conversion of Cellulose into Valuable Chemicals[J]. Chinese Journal of Catalysis, 2011, 32(5): 716-722.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(10)60232-X

https://www.cjcatal.com/CN/Y2011/V32/I5/716

参考文献

1Huber G W, Corma A. Angew Chem, Int Ed, 2007, 46: 7184

2Corma A, Iborra S, Velty A. Chem Rev, 2007, 107: 2411

3Dhepe P L, Fukuoka A. Catal Surv Asia, 2007, 11: 186

4Stöcker M. Angew Chem, Int Ed, 2008, 47: 9200

5Krässig H A. Cellulose: Structure, Accessibility, and Reactiv-ity. Yverdon: Gordon and Breach Science Publishers, 1993. 26

6Dhepe P L, Fukuoka A. ChemSusChem, 2008, 1: 969

7Rinaldi R, Schüth F. ChemSusChem, 2009, 2: 1096

8Van de Vyver S, Geboers J, Jacobs P A, Sels B F. ChemCatChem, 2011, 3: 82

9Swatloski R P, Spear S K, Holbrey J D, Rogers R D. J Am Chem Soc, 2002, 124: 4974

10Huber G W, Iborra S, Corma A. Chem Rev, 2006, 106: 4044

11Nisizawa K. J Ferment Technol, 1973, 51: 267

12Nishiyama Y, Sugiyama J, Chanzy H, Langan P. J Am Chem Soc, 2003, 125: 14300

13Yu Y, Wu H. Ind Eng Chem Res, 2010, 49: 3902

14Yu Y, Lou X, Wu H. Energy Fuels, 2008, 22: 46

15Akiya N, Savage P E. Chem Rev, 2002, 102: 2725

16Yu Y, Wu H. Ind Eng Chem Res, 2009, 48: 10682

17Fukuoka A, Dhepe P L. Angew Chem, Int Ed, 2006, 45: 5161

18Jollet V, Chambon F, Rataboul F, Cabiac A, Pinel C, Guillon E, Essayem N. Green Chem, 2009, 11: 2052

19Jollet V, Chambon F, Rataboul F, Cabiac A, Pinel C, Guillon E, Essayem N. Top Catal, 2010, 53: 1254

20Palkovits R, Tajvidi K, Procelewska J, Rinaldi R, Rupper A. Green Chem, 2010, 12: 972

21Luo C, Wang S A, Liu H C. Angew Chem, Int Ed, 2007, 46: 7636

22Van de Vyver S, Geboers J, Dusselier M, Schepers H, Vosch T, Zhang L, Van Tendeloo G, Jacobs P A, Sels B F. Chem-SusChem, 2010, 3: 698

23Kobayashi H, Komanoya T, Hara K, Fukuoka A. Chem-SusChem, 2010, 3: 440

24Kobayashi H, Ito Y, Komanoya T, Hosaka Y, Dhepe P L, Kasai K, Hara K, Fukuoka A. Green Chem, 2011, 13: 326

25Toda M, Takagaki A, Okamura M, Kondo J N, Hayashi S, Domen K, Hara M. Nature, 2005, 438: 178

26Suganuma S, Nakajima K, Kitano M, Yamaguchi D, Kato H, Hayashi S, Hara M. J Am Chem Soc, 2008, 130: 12787

27Okamura M, Takagaki A, Toda M, Kondo J N, Domen K, Tatsumi T, Hara M, Hayashi S. Chem Mater, 2006, 18: 3039

28Yamaguchi D, Kitano M, Suganuma S, Nakajima K, Kato H, Hara M. J Phys Chem C, 2009, 113: 3181

29Onda A, Ochi T, Yanagisawa K. Green Chem, 2008, 10: 1033

30Van de Vyver S, Peng L, Geboers J, Schepers H, De Clippel F, Gommes C J, Goderis B, Jacobs P A, Sels B F. Green Chem, 2010, 12: 1560

31Pang J, Wang A, Zheng M, Zhang T. Chem Commun, 2010, 46: 6935

32Takagaki A, Tagusagawa C, Domen K. Chem Commun, 2008: 5363

33Tagusagawa C, Takagaki A, Iguchi A, Takanabe K, Kondo J N, Ebitani K, Tatsumi T, Domen K. Chem Mater, 2010, 22: 3072

34Yan N, Zhao C, Luo C, Dyson P J, Liu H, Kou Y. J Am Chem Soc, 2006, 128: 8714

35Deng W P, Tan X S, Fang W H, Zhang Q H, Wang Y. Catal Lett, 2009, 133: 167

36Ding L, Wang A, Zheng M, Zhang T. ChemSusChem, 2010, 3: 818

37Kobayashi H, Matsuhashi H, Komanoya T, Hara K, Fukuoka A. Chem Commun, 2011, 47: 2366

38Ji N, Zhang T, Zheng M, Wang A, Wang H, Wang X, Chen J G. Angew Chem, Int Ed, 2008, 47: 8510

39Ji N, Zhang T, Zheng M, Wang A, Wang H, Wang X, Shu Y, Stotllemyer A L, Chen J G. Catal Today, 2009, 147: 77

40Zheng M, Wang A, Ji N, Pang J, Wang X, Zhang T. ChemSusChem, 2010, 3: 63

41Zhao G, Zheng M, Wang A, Zhang T. Chin J Catal, 2010, 31: 928

42Zhang Y, Wang A, Zhang T. Chem Commun, 2010, 46: 862

43Geboers J, Van de Vyver S, Carpentier K, De Blochouse K, Jacobs P, Sels B. Chem Commun, 2010, 46: 3577

44Tan X, Deng W, Liu M, Zhang Q, Wang Y. Chem Commun, 2009: 7179

45Ishida T, Kinoshita N, Okatsu H, Akita T, Takei T, Haruta M. Angew Chem, Int Ed, 2008, 47: 9265

46Biella S, Prati L, Rossi M. J Catal, 2002, 206: 242

47Onda A, Ochi T, Yanagisawa K. Catal Commun, 2011, 12: 421

[1]	Marzieh Mohammadi, Ghasem Rezanejade Bardajee, Nader Noroozi Pesyan. Efficient solvent-free synthesis of pyridopyrazine and quinoxaline derivatives using copper-DiAmSar complex anchored on SBA-15 as a reusable catalyst[J]. 催化学报, 2015, 36(8): 1379-1386.
[2]	Md. Amir, U. Kurtan, A. Baykal. Synthesis and application of magnetically recyclable nanocatalyst Fe₃O₄@Nico@Cu in the reduction of azo dyes[J]. 催化学报, 2015, 36(8): 1280-1286.
[3]	Sanjay Srivastava, Pravakar Mohanty, Jigisha K. Parikh, Ajay K. Dalai, S. S. Amritphale, Anup K. Khare. Cr-free Co-Cu/SBA-15 catalysts for hydrogenation of biomass-derived α-, β-unsaturated aldehyde to alcohol[J]. 催化学报, 2015, 36(7): 933-942.
[4]	Laxmikant D. Chavan, Sunil G. Shankarwar. KSF supported 10-molybdo-2-vanadophosphoric acid as an efficient and reusable catalyst for one-pot synthesis of 2,4,5-trisubstituted imidazole derivatives under solvent-free condition[J]. 催化学报, 2015, 36(7): 1054-1059.
[5]	Dana Bílková, Petr Jansa, Iva Paterová, Libor Červený. Hydrogenation of coumarin to octahydrocoumarin over a Ru/Ccatalyst[J]. 催化学报, 2015, 36(7): 957-960.
[6]	U. Kurtan, Md. Amir, A. Baykal. A Fe₃O₄@Nico@Ag nanocatalyst for the hydrogenation of nitroaromatics[J]. 催化学报, 2015, 36(5): 705-711.
[7]	Kin Hong Liew, Wan Zurina Samad, Norazzizi Nordin, Poh Lee Loh, Joon Ching Juan, Mohd Ambar Yarmo, Badrul Hisham Yahaya, Rahimi M. Yusop. Preparation and characterization of HypoGel-supported Pd nanocatalysts for Suzuki reaction under mild conditions[J]. 催化学报, 2015, 36(5): 771-777.
[8]	Nasir Iravani, Mosadegh Keshavarz, Hossein Ali Shojaeian Kish, Rasool Parandvar. Tin sulfide nanoparticles supported on activated carbon as an efficient and reusable Lewis acid catalyst for three-component one-pot synthesis of 4H-pyrano[2, 3-c]pyrazole derivatives[J]. 催化学报, 2015, 36(4): 626-633.
[9]	Susmit Basu. High enantioselectivity in the asymmetric hydrogenation of ketones by a supported Pt nanocatalyst on a mesoporous modified MCM-41 support[J]. 催化学报, 2015, 36(4): 634-638.
[10]	Sara Sobhani, Farzaneh Zarifi. Pd-isatin Schiff base complex immobilized on γ-Fe₂O₃as a magnetically recyclable catalyst for the Heck and Suzuki cross-coupling reactions[J]. 催化学报, 2015, 36(4): 555-563.
[11]	Abdol R. Hajipour, Ghobad Azizi. Immobilized Pd nanoparticles on Tris-modified SiO₂：Synthesis, characterization, and catalytic activity in Heck cross-coupling reactions[J]. 催化学报, 2014, 35(9): 1547-1554.
[12]	Cuong Duong-Viet, Housseinou Ba, Yuefeng Liu, Lai Truong-Phuoc, Jean-Mario Nhut, Cuong Pham-Huu. Nitrogen-doped carbon nanotubes on silicon carbide as a metal-free catalyst[J]. 催化学报, 2014, 35(6): 906-913.
[13]	Filoklis D. Pileidis, Maham Tabassum, Sam Coutts, Maria-Magdalena Titirici. Esterification of levulinic acid into ethyl levulinate catalysed by sulfonated hydrothermal carbons[J]. 催化学报, 2014, 35(6): 929-936.
[14]	Daniel E. Resasco. Carbon nanohybrids used as catalysts and emulsifiers for reactions in biphasic aqueous/organic systems[J]. 催化学报, 2014, 35(6): 798-806.
[15]	De Chen, Anders Holmen, Zhijun Sui, Xinggui Zhou. Carbon mediated catalysis：A review on oxidative dehydrogenation[J]. 催化学报, 2014, 35(6): 824-841.