负载脯氨酸及其衍生物催化的不对称 C–C 键形成反应研究进展

doi:10.3724/SP.J.1088.2011.10344

摘要/Abstract

摘要： 近年来脯氨酸及其衍生物催化的不对称有机反应受到了广泛关注, 将其负载于载体上使用也引起了人们的极大兴趣. 负载方式大致分为 3 种: 共价键负载, 离子对结合或物理吸附等作用负载, 以及在离子液体中的两相催化剂. 本文对近年来出现的负载脯氨酸及其衍生物催化的不对称反应 (Aldol 反应、Michael 加成反应) 研究进展进行了综述.

关键词: 负载型催化剂, 有机催化, L-脯氨酸, 碳-碳键形成反应

Abstract: In recent years, L-proline and L-proline derivatives were successfully used as organocatalysts in asymmetric reactions. There are three different general approaches for organocatalyst immobilization: covalently supported catalysts, non-covalently supported catalysts, and biphasic catalysts in ionic liquids. This review summarizes some immobilized organocatalysts, highlighting their application, recoverability, and reusability in Aldol and Michael addition reactions.

Key words: supported catalyst, organocatalysis, L-proline, carbon-carbon bong formation reaction

刘玉霞, 杨柳, 马志伟, 王川川, 陶京朝. 负载脯氨酸及其衍生物催化的不对称 C–C 键形成反应研究进展[J]. 催化学报, 2011, 32(8): 1295-1311.

LIU Yu-Xia, YANG Liu, MA Zhi-Wei, WANG Chuan-Chuan, TAO Jing-Chao. Research Progress in Supported Proline and Proline Derivatives as Recyclable Organocatalysts for the Asymmetric C–C Bond Formation Reactions[J]. Chinese Journal of Catalysis, 2011, 32(8): 1295-1311.

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