吡咯亚胺配体与过渡金属的反应性及其催化烯烃聚合

doi:10.3724/SP.J.1088.2011.10423

催化学报 ›› 2011, Vol. 32 ›› Issue (9): 1439-1445.DOI: 10.3724/SP.J.1088.2011.10423

吡咯亚胺配体与过渡金属的反应性及其催化烯烃聚合

苏碧云*, 拓宏兵, 张群正

西安石油大学化学化工学院, 陕西西安 710065

收稿日期:2011-04-27 修回日期:2011-06-26 出版日期:2011-09-09 发布日期:2015-01-24

Reactivity of Iminopyrrole Ligands with Transition Metals and Catalytic Activity of Complexes for Olefin Polymerization

SU Biyun*, TA Hongbing, ZHANG Qunzheng

College of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, Shaanxi, China

Received:2011-04-27 Revised:2011-06-26 Online:2011-09-09 Published:2015-01-24

摘要/Abstract

摘要： 在经典的 Brookhart 吡啶双亚胺后过渡金属烯烃聚合催化剂基础上, 用吡咯五元环代替吡啶六元环骨架可得到具有不同电子效应的新型吡咯亚胺配体. 通过吡咯环特殊的电子效应和位阻效应可设计出种类繁多的有别于吡啶亚胺配体的配合物. 综述了吡咯亚胺配体与前过渡金属 (Ti, Zr 等)、后过渡金属 (Fe, Co, Ni, Pd 等)、稀土金属 (Y, Ir, Lu, Nd 等) 以及其它金属 (Cu, U, Cr 等) 的配位方式、配合物的结构类型、反应性及其催化烯烃聚合反应性能.

关键词: 吡咯亚胺配体, 过渡金属配合物, 烯烃聚合, 电子效应

Abstract: Nitrogen-based variations of the bis(imino)pyridine incorporated late transition metal catalysts for olefin polymerization have recently attracted attention owing to their flexible complexation to transition metals. Because steric and electronic demands can be readily introduced to the iminopyrrole unit, a wide variety of ligands and corresponding complexes have been designed and synthesized. In this contribution, we briefly review reactivity and structural features of iminopyrrolyl ligands with early transition metals Ti and Zr, late transition metals Fe, Co, Ni, and Pd, rare earth metals Y, Ir, Lu, and Nd as well as other metals such as Cu, U, and Cr and their catalytic activity for olefin polymerization.

Key words: iminopyrrolyl ligand, transition metal complex, olefin polymerization, electronic effect

苏碧云, 拓宏兵, 张群正. 吡咯亚胺配体与过渡金属的反应性及其催化烯烃聚合[J]. 催化学报, 2011, 32(9): 1439-1445.

SU Bi-Yun, TUO Hong-Bing, ZHANG Qun-Zheng. Reactivity of Iminopyrrole Ligands with Transition Metals and Catalytic Activity of Complexes for Olefin Polymerization[J]. Chinese Journal of Catalysis, 2011, 32(9): 1439-1445.

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吡咯亚胺配体与过渡金属的反应性及其催化烯烃聚合

Reactivity of Iminopyrrole Ligands with Transition Metals and Catalytic Activity of Complexes for Olefin Polymerization

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