催化学报

催化学报 ›› 2011, Vol. 32 ›› Issue (9): 1452-1456.DOI: 10.1016/S1872-2067(10)60256-2

• 研究论文 • 上一篇    下一篇

CO2 辅助老化制备的 Cu/ZnO/Al2O3 催化剂上 CO2 加氢制甲醇

王丹君 1,2, 陶芙蓉 1,2, 赵华华 1,2, 宋焕玲 1, 丑凌军 1,*   

  1. 1 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室, 甘肃兰州 730000; 2 中国科学院研究生院, 北京 100049
  • 收稿日期:2011-04-10 修回日期:2011-05-27 出版日期:2011-09-09 发布日期:2015-01-24

Preparation of Cu/ZnO/Al2O3 Catalyst for CO2 Hydrogenation to Methanol by CO2 Assisted Aging

WANG Danjun1,2, TAO Furong1,2, ZHAO Huahua1,2, SONG Huanling1, CHOU Lingjun1,*   

  1. 1State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China; 2Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2011-04-10 Revised:2011-05-27 Online:2011-09-09 Published:2015-01-24

PDF

1255

摘要： 对传统共沉淀法进行改进, 在老化阶段通入 CO2 促进母液中前驱体物相的转变, 制备了 Cu/ZnO/Al2O3 催化剂. N2 吸附、X 射线衍射、场发射扫描电子显微镜、程序升温还原、程序升温分解结果表明, 改进共沉淀法制备的催化剂前驱体中碱式硝酸铜更易转变为碱式碳酸铜, 从而提高了前驱体的稳定性, 并使得焙烧后的催化剂具有较大的比表面积和孔体积及较小的颗粒. 在 200~260 °C 范围内对 CO2 加氢制甲醇活性测试表明, 改进方法制备的催化剂活性明显优于传统共沉淀法制备的催化剂.

关键词: 二氧化碳辅助老化, 铜, 氧化锌, 氧化铝, 二氧化碳加氢, 甲醇合成

Abstract: A Cu/ZnO/Al2O3 catalyst prepared by adding CO2 during the aging step was used for methanol synthesis from CO2 and H2. The catalysts were characterized by N2 adsorption-desorption, X-ray diffraction, field emission scanning electron microscope, temperature-programmed decomposition, and temperature-programmed reduction. The precursor from the modified method with added CO2 had malachite and hydrotalcite-like phases and was more stable than that of the sample without added CO2. After calcination, the modified catalyst had a higher surface area, larger pore volume, and smaller particle size. The modified catalyst gave a higher activity for methanol synthesis from CO2 hydrogenation in the reaction temperature range of 200–260 ºC.

Key words: carbon dioxide assisted aging, copper, zinc oxide, alumina, hydrogenation of carbon dioxide, methanol synthesis