催化学报

催化学报 ›› 2011, Vol. 32 ›› Issue (12): 1787-1789.DOI: 10.3724/SP.J.1088.2011.10839

• 研究快讯 • 上一篇    下一篇

铜-氮羟基吡啶二甲酰亚胺配合物催化烃类选择氧化

张巧红 1, 陈晨 2, 马红 2, 高进 2, 徐杰 2,a, 夏春谷 1,b   

  1. 1 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室, 甘肃兰州 730000; 2 中国科学院大连化学物理研究所, 洁净能源国家实验室(筹), 催化基础国家重点实验室, 辽宁大连 116023
  • 收稿日期:2011-08-30 修回日期:2011-10-13 出版日期:2011-12-21 发布日期:2015-04-23

N-Hydroxyquinolinimide Copper Complex Catalyzing Selective Oxidation of Hydrocarbon

ZHANG Qiaohong1, CHEN Chen2, MA Hong2, GAO Jin2, XU Jie2,*, XIA Chungu1,*   

  1. 1State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China; 2State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China
  • Received:2011-08-30 Revised:2011-10-13 Online:2011-12-21 Published:2015-04-23

PDF

793

被引次数

15

摘要： 合成了铜-氮羟基吡啶二甲酰亚胺配合物催化体系, 通过元素分析与红外光谱表征确定了配合物的组成与结构. 该催化体系在 90 oC 和 p(O2) = 0.5 MPa的温和条件下实现了环己烯、乙苯等烃类的高效选择氧化.

关键词: 铜-氮羟基吡啶二甲酰亚胺配合物, 烃类, 选择氧化

Abstract: A N-hydroxyquinolinimide copper complex was synthesized and its composition and structure were characterized by elemental analysis and FT-IR. This complex is an efficient catalytic system for selective oxidation of hydrocarbons such as cyclohexene, ethylbenzene, etc., and higher activity can be obtained under mild conditions.

Key words: N-hydroxyquinolinimide copper complex, hydrocarbon, selective oxidation