生物油中酚类化合物加氢脱氧催化剂研究进展

doi:10.3724/SP.J.1088.2012.10922

摘要/Abstract

摘要： 随着化石能源日益匮乏, 生物质热裂解制备生物油广受关注. 然而, 生物油中含有大量酚、呋喃、醛、酮等含氧化合物, 含氧量高达 50%, 导致其热值低、化学稳定性差等, 因而阻碍了它的广泛应用, 必须对其进行加氢脱氧精制降低含氧量. 在生物油中众多含氧化合物中, 酚羟基氧被认为是最难被脱除的. 对酚类含氧化合物加氢脱氧催化剂及反应进行了简单综述, 并提出了如何进一步提高催化剂性能的有效方法.

关键词: 酚类化合物, 加氢脱氧, 生物油, 清洁燃油

Abstract: With the declining of crude oil resources, the development of bio-oil from biomass into fast pyrolysis has attracted much attention. However, the bio-oil contains many oxygenic compounds such as phenols, funans, aldehyde, ketone, etc., and its oxygen content is high up to 50%, leading to its low heating value and thermal instability, which hinders its extensive application. It is necessary to remove the oxygen from bio-oil by a hydrodeoxygenation (HDO) process. Among many oxygenic compounds, phenolic hydroxyl oxygen is considered the most difficult one to be removed. The HDO of phenols was reviewed and the effective way for further improving the catalyst activity was proposed.

Key words: phenol compound, hydrodeoxygenation, bio-oil, clean fuel

王威燕, 张小哲, 杨运泉, 杨彦松, 彭会左, 刘文英. 生物油中酚类化合物加氢脱氧催化剂研究进展[J]. 催化学报, 2012, 33(2): 215-221.

WANG Wei-Yan, ZHANG Xiao-Zhe, YANG Yun-Quan, YANG Yan-Song, PENG Hui-Zuo, LIU Wen-Ying. Progress in the Catalysts for the Hydrodeoxygenation of Phenols in Bio-oil[J]. Chinese Journal of Catalysis, 2012, 33(2): 215-221.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.3724/SP.J.1088.2012.10922

https://www.cjcatal.com/CN/Y2012/V33/I2/215

参考文献

1徐向阳. 自然资源学报 (Xu X Y. J Nat Resour), 2010, 25: 1806
2Huber G W, Iborra S, Corma A. Chem Rev, 2006, 106: 4044
3Furimsky E. Appl Catal A, 2000, 199: 147
4Zakzeski J, Bruijnincx P C A, Jongerius A L, Weckhuysen B M. Chem Rev, 2010, 110: 3552
5姚勇, 邸敏艳. 小型内燃机与摩托车 (Yao Y, Di M Y. Small Internal Comb Engine Motor), 2008, 37(3): 93
6王树荣, 骆仲泱, 谭洪, 洪军, 董良杰, 方梦祥, 岑可法. 工程热物理学报 (Wang Sh R, Luo Zh Y, Tan H, Hong J, Dong L J, Fang M X, Cen K F. J Eng Thermophys), 2004, 25: 1049
7Crossley S, Faria J, Shen M, Resasco D E. Science, 2010, 327: 68
8Li Ch L, Xu Z R, Gates B C. Ind Eng Chem Process Des Dev, 1985, 24: 92
9Vuori A, Helenius A, Bredenberg J B S. Appl Catal, 1989, 52: 41
10Ferrari M, Bosmans S, Maggi R, Delmon B, Grange P. Catal Today, 2001, 65: 257
11Ferrari M, Maggi R, Delmon B, Grange P. J Catal, 2001, 198: 47
12Viljava T R, Komulainen R S, Krause A O I. Catal Today, 2000, 60: 83
13?enol O I, Ryymin E M, Viljava T R, Krause A O I. J Mol Catal A, 2007, 277: 107
14Ryymin E M, Honkela M L, Viljava T R, Krause A O I. Appl Catal A, 2010, 389: 114
15Laurent E, Delmon B. Appl Catal A, 1994, 109: 77
16Laurent E, Delmon B. Ind Eng Chem Res, 1993, 32: 2516
17Badawi M, Paul J F, Cristol S, Payen E, Romero Y, Richard F, Brunet S, Lambert D, Portier X, Popov A, Kondratieva E, Goupil J M, El Fallah J, Gilson J P, Mariey L, Travert A, Maugé F. J Catal, 2011, 282: 155
18Odebunmi E O, Ollis D F. J Catal, 1983, 80: 56
19Odebunmi E O, Ollis D F. J Catal, 1983, 80: 65
20Odebunmi E O, Ollis D F. J Catal, 1983, 80: 76
21Wandas R, Surygata J, Sliwka E. Fuel, 1996, 75: 687
22Bredenberg J B, Huuska M, Toropainen P. J Catal, 1989, 120: 401
23Gevert B S, Otterstedt J E, Massoth F E. Appl Catal, 1987, 31: 119
24Gevert S B, Eriksson M, Eriksson P, Massoth F E. Appl Catal A, 1994, 117: 151
25Centeno A, Laurent E, Delmon B. J Catal, 1995, 154: 288
26de la Puente G, Gil A, Pis J J, Grange P. Langmuir, 1999, 15: 5800
27Yang Y Q, Tye C T, Smith K J. Catal Commun, 2008, 9: 1364
28Yang Y Q, Luo H A, Tong G Sh, Kevin J S, Tye C T. Chin J Chem Eng, 2008, 16: 733
29Romero Y, Richard F, Brunet S. Appl Catal B, 2010, 98: 213
30Bui V N, Laurenti D, Delichère P, Geantet C. Appl Catal B, 2011, 101: 246
31Bui V N, Laurenti D, Afanasiev P, Geantet C. Appl Catal B, 2011, 101: 239
32Gutierrez A, Kaila R K, Honkela M L, Slioor R, Krause A O I. Catal Today, 2009, 147: 239
33Ruiz P E, Leiva K, Garcia R, Reyes P, Fierro J L G, Escalona N. Appl Catal A, 2010, 384: 78
34Zhao C, Kou Y, Lemonidou A A, Li X B, Lercher J A. Angew Chem, Int Ed, 2009, 48: 3987
35Zhao C, He J, Lemonidou A A, Li X, Lercher J A. J Catal, 2011, 280: 8
36Zhao C, Kou Y, Lemonidou A A, Li X, Lercher J A. Chem Commun, 2010, 46: 412
37Yan N, Yuan Y, Dykeman R, Kou Y A, Dyson P J. Angew Chem, Int Ed, 2010, 49: 5549
38Hong D Y, Miller S J, Agrawal P K, Jones C W. Chem Commun, 2010, 46: 1038
39Lin Y C, Li C L, Wan H P, Lee H T, Liu C F. Energy Fuels, 2011, 25: 890
40Gonza?lez-Borja M A, Resasco D E. Energy Fuels, 2011, 25: 4155
41Yang Y, Gilbert A, Xu C. Appl Catal A, 2009, 360: 242
42Whiffen V M L, Smith K J. Energy Fuels, 2010, 24: 4728
43Gandarias I, Barrio V L, Requies J, Arias P L, Cambra J F, Güemez M B. Int J Hydrogen Energy, 2008, 33: 3485
44Echeandia S, Arias P L, Barrio V L, Pawelec B, Fierro J L G. Appl Catal B, 2010, 101: 1
45Sepúlveda C, Leiva K, García R, Radovic L R, Ghampson I T, DeSisto W J, Fierro J L G, Escalona N. Catal Today, 2011, 172: 232
46Wang W Y, Yang Y Q, Bao J G, Luo H A. Catal Commun, 2009, 11: 100
47Wang W Y, Yang Y Q, Luo H A, Liu W Y. Reac Kinet Mechan Catal, 2010, 101: 105
48王威燕, 杨运泉, 罗和安, 王锋, 胡韬, 刘文英. 燃料化学学报 (Wang W Y, Yang Y Q, Luo H A, Wang F, Hu T, Liu W Y. J Fuel Chem Technol), 2011, 39: 367
49Wang W Y, Yang Y Q, Luo H A, Hu T, Liu W Y. Catal Commun, 2011, 12: 436
50Wang W Y, Yang Y Q, Luo H A, Hu T, Liu W Y. React Ki-net Mechan Catal, 2011, 102: 207
51王威燕, 杨运泉, 罗和安, 彭会左, 张小哲, 胡韬. 催化学报 (Wang W Y, Yang Y Q, Luo H A, Peng H Z, Zhang X Zh, Hu T. Chin J Catal), 2011, 32: 1645
52Wang W Y, Yang Y Q, Luo H A, Peng H Z, Wang F. Ind Eng Chem Res, 2011, 50: 10936

[1]	Enara Fernandez, Laura Santamaria, Irati García, Maider Amutio, Maite Artetxe, Gartzen Lopez, Javier Bilbao, Martin Olazar. 不同固定床位置生物质热解挥发物蒸汽催化重整反应中焦炭的形成和演化[J]. 催化学报, 2023, 48(5): 101-116.
[2]	曾严, 王慧, 杨惠茹, 隽超, 李丹, 温晓东, 张帆, 邹吉军, 彭冲, 胡常伟. 镍纳米粒子耦合氧空位高效催化转化棕榈酸制备烷烃[J]. 催化学报, 2023, 47(4): 229-242.
[3]	汪东东, 龚万兵, 张继方, 韩苗苗, 陈春, 张云霞, 汪国忠, 张海民, 赵惠军. 限域NiCo合金纳米颗粒高效催化生物质衍生物水相加氢脱氧[J]. 催化学报, 2021, 42(11): 2027-2037.
[4]	刘云庆, 夏培玉, 李凌宇, 王欣月, 孟佳琪, 杨雨昕, 郭伊荇. 原位法制备石墨相碳/TiO₂复合光催化剂及其高效降解新兴酚类污染物性能[J]. 催化学报, 2020, 41(9): 1378-1392.
[5]	林凯, 赵晨. 亲水性介孔碳负载Ru纳米粒子催化海藻油低温水相加氢脱氧制烷烃[J]. 催化学报, 2020, 41(8): 1174-1185.
[6]	Nhung N. Duong, Darius Aruho, Bin Wang, Daniel E. Resasco. 不同Rh表面上苯甲醚加氢脱氧[J]. 催化学报, 2019, 40(11): 1721-1730.
[7]	王晓菲, 陈吉祥. In对Ni/SiO₂催化剂苯甲醚加氢脱氧性能的影响:苯环加氢及C-C键氢解的抑制作用[J]. 催化学报, 2017, 38(11): 1818-1830.
[8]	王树荣, 蔡勤杰, 王相宇, 张力, 王誉蓉, 骆仲泱. 生物油酸酮类模化物与乙醇在HZSM-5上共裂化制备生物汽油[J]. 催化学报, 2014, 35(5): 709-722.
[9]	刘琪英, 左华亮, 张琦, 王铁军, 马隆龙. Ni/SAPO-11催化剂上棕榈油加氢脱氧制异构烃燃料[J]. 催化学报, 2014, 35(5): 748-756.
[10]	张兴华, 张琦, 陈伦刚, 徐莹, 王铁军, 马隆龙. Ni/SiO₂-ZrO₂催化剂焙烧温度对其催化愈创木酚加氢脱氧性能的影响[J]. 催化学报, 2014, 35(3): 302-309.
[11]	谭顺, 张志军, 孙剑平, 王清文. HZSM-5上生物质催化裂解的近期研究进展[J]. 催化学报, 2013, 34(4): 641-650.
[12]	王威燕, 杨运泉, 罗和安, 彭会左张小哲, 胡韬. Ni-Co-W-B 非晶态催化剂的制备及其加氢脱氧性能[J]. 催化学报, 2011, 32(10): 1645-1650.
[13]	张凤;蒋晓原;洪俊杰;楼辉;郑小明. ZnCl2改性离子交换树脂的制备及其催化乙醇和乙酸酯化反应性能[J]. 催化学报, 2010, 31(6): 666-670.
[14]	郑小明;楼辉. 生物质热解油品位催化提升的思考和初步进展[J]. 催化学报, 2009, 30(8): 765-769.
[15]	于荟;朱银华;刘畅;杨祝红;陆小华;冯新. 新型介孔SO42-/TiO2固体酸的制备及其催化酯化性能[J]. 催化学报, 2009, 30(3): 265-271.