从工业催化角度看分子筛催化剂未来发展的若干思考

doi:10.1016/S1872-2067(10)60299-9

摘要/Abstract

摘要： 从工业催化的角度思考和探讨了分子筛催化剂合成、催化及应用方面存在的一些问题与挑战, 并从沸石分子筛的高效催化、新结构分子筛合成与催化应用、沸石分子筛的经济合成、分子筛在绿色环保领域的新应用等几个方面, 综述了国内外相关的最新研究进展, 探讨了分子筛催化剂未来的发展方向. 旨在引发人们对分子筛催化未来向经济、可控、高效催化、绿色环保和新应用等方面发展的思考与探索.

关键词: 沸石分子筛, 工业催化剂, 石油化工, 未来发展, 高效催化, 经济合成, 绿色环保

Abstract: Problems and challenges in the production and catalysis of zeolitic catalysts were addressed from an industrial point of view. The recent progress and developments in zeolitic catalysts were reviewed. The highly efficient catalysis of zeolitic catalysts, the synthesis and application of novel zeolitic catalysts, the economic production of zeolites, the application of zeolites to environmental protection and green chemistry, etc., were covered. It is intended to stimulate thought and focus on the future development of zeolitic catalysts with regard to economic synthesis, catalyst design, high efficiency catalysis, green processes, new applications, etc.

Key words: zeolite, industrial catalyst, petrochemical industry, development, high efficiency catalysis, economic synthesis, green process

刘志成, 王仰东, 谢在库. 从工业催化角度看分子筛催化剂未来发展的若干思考[J]. 催化学报, 2012, 33(1): 22-38.

LIU Zhi-Cheng, WANG Yang-Dong, XIE Zai-Ku. Thoughts on the Future Development of Zeolitic Catalysts from an Industrial Point of View[J]. Chinese Journal of Catalysis, 2012, 33(1): 22-38.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(10)60299-9

https://www.cjcatal.com/CN/Y2012/V33/I1/22

参考文献

1Plank C J. In: Davis B H, Hettinger W P Jr eds. Heterogeneous Catalysis, Selected American Histories, ACS Symposium Series 222. Washington: American Chemical Society, 1983. 253
2Vermeiren W, Gilson J P. Top Catal, 2009, 52: 1131
3谢在库. 新结构高性能多孔催化材料. 北京 : 中国石化出版社 (Xie Z K. Porous Catalytic Materials With New Structure And Improved Performance. Beijing: Sinopec Press), 2010. 4
4王亚军, 唐颐, 王星东. 石油化工 (Wang Y J, Tang Y, Wang X D, Petrochem Technol), 2002, 31: 217
5Schoeman B J, Sterte J, Otterstedt J E. Zeolites, 1994, 14: 110
6Tsapatsis M, Lovallo M, Okubo T, Davis M E, Sadakata M. Chem Mater, 1995, 7: 1734
7Persson A E, Schoeman B J, Sterte J, Otterstedt J E. Zeo-lites, 1995, 15: 611
8Camblor M A, Corma A, Mifsud A, Perez-Pariente J, Valencia S. Stud Surf Sci Catal, 1997, 105: 341
9柳云骐, 刘春英, 刘晨光. 化学进展 (Liu Y Q, Liu Ch Y, Liu Ch G. Progress Chem), 2005, 17: 666
10Yang H Q, Liu Zh Ch, Gao H X, Xie Z K. J Mater Chem, 2010, 20: 3227
11Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246
12Christensen C H, Johannsen K, Schmidt I, Christensen C H. J Am Chem Soc, 2003, 125: 13370
13Schmidt I, Boisen A, Gustavsson E, Stahl K, Pehrson S, Dahl S, Carlsson A, Jacobsen C J H. Chem Mater, 2001, 13: 4416
14刘志成, 孔德金, 王仰东, 谢在库. 石油学报 (石油加工)( Liu Zh Ch, Kong D J, Wang Y D, Xie Z K. Acta Petrol Sin (Petrol Process Sect)), 2008, 24(Z1): 124
15Zhu H B, Liu Zh Ch, Wang Y D, Kong D J, Yuan X H, Xie Z K. Chem Mater, 2008, 20: 1134
16Xiao F Sh, Wang L F, Yin C Y, Lin K F, Di Y, Li J X, Xu R R, Su D S, Schlögl R, Yokoi T, Tatsumi T. Angew Chem, Int Ed, 2006, 45: 3090
17Zhu H B, Liu Zh Ch, Kong D J, Wang Y D, Yuan X H, Xie Z K. J Colloid Inter Sci, 2009, 331: 432
18Choi M, Cho H S, Srivastava R, Venkatesan C, Choi D H, Ryoo R. Nature Mater, 2006, 5: 718
19Fan W, Snyder M A, Kumar S, Lee P S, Yoo W C, McCor-mick A V, Lee Penn R, Stein A, Tsapatsis M. Nature Mater, 2008, 7: 984
20刘志成, 王仰东, 孔德金, 谢在库. 见: 王静康主编. 现代化工、冶金与材料技术前沿, 中国工程院第七届学术会议论文集 (上册). 北京: 化学工业出版社 (Liu Zh Ch, Wang Y D, Kong D J, Xie Z K. In: Wang J K ed. Fron-tiers of Modern Chemical Engineering, Metallurgy, and Material Technologies: Proceedings of the 7th Chinese Academy of Engineering Symposium. Beijing: Chem Ind Press), 2009. 557
21Zhu H B, Liu Zh Ch, Kong D J, Wang Y D, Xie Z K. J Phys Chem C, 2008, 112: 17257
22Yang H Q, Liu Zh Ch, Gao H X, Xie Z K. Appl Catal A, 2010, 379: 166
23Thomas J, Ramdas S, Millward B. New Scientist, 1982, 96: 435
24Xie S J, Liu Sh L, Liu Y, Li X J, Zhang W P, Xu L Y. Mi-croporous Mesoporous Mater, 2009, 121: 166
25Niu X L, Song Y Q, Xie S J, Liu Sh L, Wang Q X, Xu L Y. Catal Lett, 2005, 103: 211
26谢素娟, 刘盛林, 张玲, 徐龙伢. 石油学报 (石油加工)(Xie S J, Liu Sh L, Zhang L, Xu L Y. Acta Petrol Sin (Petrol Process Sect)), 2009, 25(S1): 37
27祁晓岚, 李斌, 李士杰, 刘希尧, 林炳雄. 催化学报 (Qi X L, Li B, Li Sh J, Liu X Y, Lin B X. Chin J Catal), 2006, 27: 228
28Kaeding W W, Chu C,Young L B, Weinstein B, Butter S A. J Catal, 1981, 67: 159
29Zhao G L, Teng J W, Xie Z K, Jin W Q, Yang W M, Chen Q L, Tang Y. J Catal, 2007, 248: 29
30Xue N H, Chen X K, Nie L, Guo X F, Ding W P, Chen Y, Gu M, Xie Z K. J Catal, 2007, 248: 20
31Davis M E, Saldarriaga C, Montes C, Garces J, Crowder C. Nature, 1988, 331: 698
32Dessau R M, Schlenker J L, Higgins J B. Zeolite, 1990, 10: 522
33Vogt E T C, Richardson J W Jr. J Solid State Chem, 1990, 87: 469
34Estermann M, McCusker L B, Baerlocher C, Merrouche A, Kessler H. Nature, 1991, 352: 320
35Huo Q S, Xu R R, Li S G, Ma Z G, Thomas J M, Jones R H, Chippindale A M. J Chem Soc, Chem Commun, 1992: 875
36Loiseau T, Ferey G. J Solid State Chem, 1994, 111: 403
37Maeda K, Akimoto J, Kiyozumi Y, Mizukami F. Angew Chem, Int Ed, 1995, 34: 1199
38Khan M I, Meyer L M, Haushalter R C, Schweitzer A L, Zubieta J, Dye J L. Chem Mater, 1996, 8: 43
39Loiseau T, Ferey G. Mater Res Soc Confer Proc, 1996, 431: 27
40Freyhardt C C, Tsapatsis M, Lobo R F, Balkus K J Jr, Davis M E. Nature,1996, 381:295
41Cavellec M, Greneche J M, Riou D, Ferey G. Microporous Mater, 1997, 8: 103
42Wagner P, Yoshikawa M, Tsuji K, Davis M E, Lovallo M, Taspatsis M. Chem Commun, 1997: 2179
43Li H L, Laine A, O’Keeffe M, Yaghi O M. Science, 1999, 283: 1145
44Guillou N, Gao Q M, Nogues M, Morris R E, Hervieu M, Ferey G, Cheetham A K. C R Acad Sci, Ser IIc, 1999, 2: 387
45Yang G Y, Sevov S C. J Am Chem Soc, 1999, 121: 8389
46Guillou N, Gao Q M, Forster P M, Chang J-S, Nogues M, Park S-E, Ferey G, Cheetham A K. Angew Chem, Int Ed, 2001, 40: 2831
47Zhou Y M, Zhu H G, Chen Z X, Chen M Q, Xu Y, Zhang H Y, Zhao D Y. Angew Chem, Int Ed, 2001, 40: 2166
48Lin C-H, Wang S-L, Lii K-H. J Am Chem Soc, 2001, 123: 4649
49Cheetham A K, Fjellvg H, Gier T E, Kongshaug K O, Lillerud K P, Stucky G D. Stud Surf Sci Catal, 2001, 135: 158
50Corma A , Diaz-Cabanas M J, Martinez-Triquero J, Rey F, Rius J. Nature, 2002, 418: 514
51Castaneda R, Corma A, Fornes V, Rey F, Rius J. J Am Chem Soc, 2003, 125: 7820
52Burton A, Elomari S, Chen C-Y, Medrud R C, Chan I Y, Bull L M, Kibby C, Harris T V, Zones S I, Vittoratos E S. Chem Eur J, 2003, 9: 5737
53Strohmaier K G, Vaughan D E W. J Am Chem Soc, 2003, 125: 16035
54Paillaud J-L, Harbuzaru B, Patarin J, Bats N. Science, 2004, 304: 990
55Corma A, Díaz-Cabañas M J, Jordá J L, Martínez C, Moliner M. Nature, 2006, 443: 842
56Sun J L, Bonneau C, Cantin A, Corma A, Diaz-Cabanas M J, Moliner M, Zhang D L, Li M R, Zou X D. Nature, 2009, 458: 1154
57Simancas R, Dari D, Velamazán N, Navarro M T, Cantín A, Jordá J L, Sastre G, Corma A, Rey F. Science, 2010, 330: 1219
58Jiang J X, Jorda J L, Diaz-Cabanas M J, Yu J H, Corma A. Angew Chem, Int Ed, 2010, 49: 4986
59Jiang J X, Jorda J L, Yu J H, Baumes L A, Mugnaioli E, Diaz-Cabanas M J, Kolb U, Corma A. Science, 2011, 333: 1131
60Davis M E, Lobo R F. Chem Mater, 1992, 4: 756
61Harrison W T A, Gier T E, Stucky G D, Broach R W, Bedard R A. Chem Mater, 1996, 8: 145
62Feng P Y, Bu X H, Tolbert S H, Stucky G D. J Am Chem Soc, 1997, 119: 2497
63Gier T, Bu X H, Feng P Y, Stucky G D. Nature, 1998, 395: 154
64Tang L Q, Shi L, Bonneau C, Sun J L, Yue H J, Ojuva A, Lee B-L, Kritikos M, Bell R G, Bacsik Z, Mink J, Zou X D. Nature Mater, 2008, 7: 381
65Roth W J, Dorset D L. Microporous Mesoporous Mater, 2011, 142: 32
66Corma A, Corell C, Llopis F, Martínez A, Pérez-Pariente J. Appl Catal A, 1994, 115: 121
67Guarino R F, Li C H. Hydrocarbon Eng, 1999, 4: 39
68Maerz B, Chen S S, Venkat C R, Mazzone D N. Hydrocabon Tech Intern, 1996: 21
69Rouleau L, Lacombe S, Alario F. Merlen E, Kolenda F, Magne-Drisch J. US 6 337 063. 2002
70Martens J A, Souverijns W, Verrelst W, Parton R, Groment G F, Jacobs P A. Angew Chem, Int Ed, 1995, 34: 2528
71Souverijns W, Martens J A, Froment G F, Jacobs P A. J Catal, 1998, 174: 177
72Zones S I, Hwang S-J. Chem Mater, 2002, 14: 313
73Zones S I. US 20 080 075 656. 2008
74Bull I, Muller U. WO 2 011 064 186. 2011
75Lee G S, Nakagawa Y, Zones S I. US 6 156 290. 2000
76Zones S I, Zhang G, Krishna K R, Biscardi J A, Marcanto-nio P, Vittoratos E. US 20 050 092 651. 2005
77Blackwell C S, Broach R W, Gatter M G, Holmgren J S, Jan D-Y, Lewis G J, Mezza B J, Mezza T M, Miller M A, Moscoso J G, Patton R L, Rohde L M, Schoonover M W, Sinkler W, Wilson B A, Wilson S T. Angew Chem, Int Ed, 2003, 42: 1737
78Knight L M, Lewis G J. Stud Surf Sci Catal, 2005, 154A: 171
79Moscoso J G, Lewis G J, Gisselquist J L, Miller M A, Knight L M. US 6 713 041. 2004
80奈特 L M, 刘易斯 G J, 米勒 M A, 莫斯科索 J G, 吉塞尔奎斯特 J L, 巴顿 R L, 威尔逊 S T, 詹登阳, 柯斯特 S C (Rohde L M, Lewis G J, Miller M A, Moscoso J G, Gis-selquist J L, Patton R L, Wilson S T, Zhan Dengyang, Kos-ter S C). CN 1 997 593. 2007
81Wang J Y, Song J W, Yin C Y, Ji Y Y, Zou Y C, Xiao F Sh. Microporous Mesoporous Mater, 2009, 117: 561
82周朋燕, 李晓峰, 王裕鑫, 武行洁, 窦涛. 石油学报 (石油加工) (Zhou P Y, Li X F, Wang Y X, Wu X J, Dou T. Acta Petrol Sin (Petrol Process Sect)), 2008, 24(Z1): 226
83McWilliams J P, Rubin M K. US 4 894 212. 1990
84Moini A, Valyocsik E W. US 5 192 521. 1993
85Zones S I, Holtermann D, Innes R A. US 5 200 377. 1993
86Nakagawa Y, Zones S I. US 5 707 600. 1998
87Nakagawa Y. US 5 316 753. 1994
88李赫咺, 项寿鹤, 吴德明, 刘月亭, 张晓森, 刘述铨. 高等学校化学学报 (Li H X, Xiang Sh H, Wu D M, Liu Y T, Zhang X S, Liu Sh Q. Chem J Chin Univ), 1981, 2: 517
89王福生, 程文才, 张式. 催化学报 (Wang F Sh, Cheng W C, Zhang Sh. Chin J Catal), 1981, 2: 282
90Shiralkar V P, Clearfield A. Zeolites, 1989, 9: 363
91孟祥举, 谢彬, 肖丰收. 催化学报 (Meng X J, Xie B, Xiao F Sh. Chin J Catal), 2009, 30: 965
92Song J W, Dai L, Ji Y Y, Xiao F Sh. Chem Mater, 2006, 18: 2775
93Wu Z F, Song J W, Ji Y Y, Ren L M, Xiao F Sh. Chem Mater, 2008, 20: 357
94Xie B, Song J W, Ren L M, Ji Y Y, Li J X, Xiao F Sh. Chem Mater, 2008, 20: 4533
95Kamimura Y, Chaikittisilp W, Itabashi K, Shimojima A, Okubo T. Chem Asian J, 2010, 5: 2182
96Kamimura Y, Tanahashi S, Itabashi K, Sugawara A, Wakihara T, Shimojima A, Okubo T. J Phys Chem C, 2011, 115: 744
97汪靖, 程晓维, 杨晓蔚, 龙英才. 化学学报 (Wang J, Cheng X W, Yang X W, Long Y C. Acta Chim Sin), 2008, 66: 769
98Warrender S J, Wright P A, Zhou W Z, Lightfoot P, Camblor M A, Shin C H, Kim D J, Hong S B. Chem Mater, 2005, 17: 1272
99Zhang H Y, Guo Q, Ren L M, Yang C G, Zhu L F, Meng X J, Li C, Xiao F Sh. J Mater Chem, 2011, 21: 9494
100Yokoi T, Yoshioka M, Imai H, Tatsumi T. Angew Chem, Int Ed, 2009, 48: 9884
101Xie B, Zhang H Y, Yang C G, Liu S Y, Ren L M, Zhang L, Meng X J, Yilmaz B, Muller U, Xiao F Sh. Chem Commun, 2011, 47: 3945
102Kuznicki S M. US 4 453 202. 1989
103Kuznicki S M, Bell V A, Nair S, Hillhouse H W, Jacubinas R M, Braunbarth C M, Toby B H, Tsapatsis M. Nature, 2001, 412: 720
104Taramasso M, Perego G, Notarir B. US 4 410 501. 1983
105Reddy J S, Kumar R, Ratnasamy P. Appl Catal, 1990, 58: L1
106Camblor M A, Corma A, Martinez A, Perez-Pariente J. J Chem Soc, Chem Commun, 1992: 589
107van der Waal J C, Kooyman P J, Jansen J C, van Bekkum H. Microporous Mesoporous Mater, 1998, 25: 43
108Tatsumi T, Jappar N. J Phys Chem, 1998, 102: 7126
109Tuel A. Zeolites, 1995, 15: 236
110Serrano D P, Li H X, Davis M E. J Chem Soc, Chem Com-mun, 1992: 745
111Wu P, Komatsu T, Yashima T. J Phys Chem, 1996, 100: 10316
112Dartt C B, Davis M E. Appl Catal A, 1996, 143: 53
113Diaz-Cabanas M J, Villaescusa L A, Camblor M A. Chem Commun, 2000: 761
114Wu P, Tatsumi T, Komatsu T, Yashima T. J Phys Chem B, 2001, 105: 2897
115Wu P, Tatsumi T. Chem Commun, 2002: 1026
116Wu P, Miyaji T, Liu Y M, He M Y, Tatsumi T. Catal Today, 2005, 99: 233
117Kubota Y, Koyama Y, Yamada T, Inagaki S, Tatsumi T. Chem Commun, 2008: 6224
118Fan W B, Duan R G, Yokoi T, Wu P, Kubota Y, Tatsumi T. J Am Chem Soc, 2008, 130: 10150
119林民, 朱斌, 舒兴田, 汪燮卿. 石油学报 (石油加工)(Lin M, Zhu B, Shu X T, Wang X Q. Acta Petrol Sin (Petrol Process Sect)), 2005, 34(Z1): 377
120谢伟, 刘月明, 汪玲玲, 吴鹏. 催化学报 (Xie W, Liu Y M, Wang L L, Wu P. Chin J Catal), 2010, 31: 502
121Bull I, Xue W M, Burk P, Boorse R S, Jaglowski W M, Koermer G S, Moini A, Patchett J A, Dettling J C, Caudle M T. US 7 601 662. 2009
122Andersen P J, Bailie J E, Casci J L, Chen H Y, Fedeyko J M, Foo R K S, Rajaram R R. WO 2 008 132 452. 2008
123Houel V, James D, Millington P, Pollington S, Poulston S, Rajaram R, Torbati R. J Catal, 2005, 230: 150
124Grossale A, Nova I, Tronconi E, Chatterjee D, Weibel M. Top Catal, 2009, 52: 1837

[1]	刘润泽, 邵雪, 王畅, 戴卫理, 关乃佳. 甲醇制烃反应机理: 基础及应用研究[J]. 催化学报, 2023, 47(4): 67-92.
[2]	肖丰收. 绿色合成:制备沸石分子筛催化材料的新路线[J]. 催化学报, 2019, 40(s1): 26-29.
[3]	于东霓, 戴卫理, 武光军, 关乃佳, 李兰冬. 分子筛稳定的Cu物种催化乙醇脱氢制乙醛[J]. 催化学报, 2019, 40(9): 1375-1384.
[4]	李玮杰, 孙兰兰, 谢林君, 邓欣, 关乃佳, 李兰冬. 沸石分子筛结构内配位不饱和位点:构筑与催化应用[J]. 催化学报, 2019, 40(9): 1255-1281.
[5]	章芬, 章凌, 杨志超, 韩世超, 朱秋艳, 王亮, 刘晨光, 孟祥举, 肖丰收. 高温快速合成纳米MAZ分子筛[J]. 催化学报, 2019, 40(7): 1093-1099.
[6]	章凌, 彭悦欣, 张娟, 陈龙, 孟祥举, 肖丰收. 沸石分子筛材料在消除挥发性有机化合物反应中的吸附与催化性能[J]. 催化学报, 2016, 37(6): 800-809.
[7]	龙雨, 袁冰, 马建泰 . 埃洛石表面修饰并负载salen钼高效催化烯烃环氧化反应[J]. 催化学报, 2015, 36(3): 348-354.
[8]	周晓兆, 刘艳, 孟祥举, 申宝剑, 肖丰收. 以天然凹凸棒石为原料合成Fe/Ti-ZSM-5沸石分子筛及其催化裂化性能[J]. 催化学报, 2013, 34(8): 1504-1512.
[9]	谢在库. 从催化导向性基础研究到工业应用的若干创新思路与实践 ——庆祝闵恩泽先生 90 华诞[J]. 催化学报, 2013, 34(1): 209-216.
[10]	任秀秀, 杨建华, 陈赞, 杨兴宝, 鲁金明, 张艳, 王金渠. 含氟体系下高性能丝光沸石分子筛膜的制备及其性能[J]. 催化学报, 2012, 33(9): 1558-1564.
[11]	滕波涛;常杰;刘颖;张成华;杨骏;郑洪岩;张荣乐;白亮;相宏伟;李永旺. 工业Fe-Mn催化剂上基于详细反应机理的F-T合成动力学模型Ⅰ. 烯烃再吸附动力学研究[J]. 催化学报, 2005, 26(8): 693-700.
[12]	滕波涛;常杰;王刚;张成华;刘颖;郑洪岩;杨骏;张荣乐;白亮;相宏伟;李永旺. 工业Fe-Mn催化剂上基于详细反应机理的F-T合成动力学模型 Ⅱ. 不同校正方法的动力学模型分析[J]. 催化学报, 2005, 26(8): 701-706.
[13]	徐仁顺;郭新闻*;王桂茹;刘靖;张竹霞. 柠檬酸改性的H-Beta上2-(4′-乙基苯甲酰基)苯甲酸的脱水反应[J]. 催化学报, 2005, 26(11): 933-934.
[14]	左伯军;王琪珑;王远;马玉道. 酸性沸石分子筛催化Knoevenagel缩合反应[J]. 催化学报, 2002, 23(6): 555-558.
[15]	许名灿;程谟杰;谭大力;刘秀梅;包信和;宗保宁;闵恩泽. 沸石分子筛在高岭土微球上的生长[J]. 催化学报, 2001, 22(1): 31-34.