催化学报

催化学报 ›› 2012, Vol. 33 ›› Issue (1): 152-163.DOI: 10.1016/S1872-2067(10)60290-2

• 研究论文 • 上一篇    下一篇

碱处理脱硅与提高 Y 型分子筛硅铝比——矛盾的对立与统一

申宝剑 1,*, 覃正兴 1, 高雄厚 1,2, 林枫 1, 周淑歌 1, 沈文 1, 王宝杰 2, 赵红娟 2, 刘宏海 2   

  1. 1中国石油大学 (北京) 化学工程学院, 重质油国家重点实验室, CNPC 催化重点实验室,北京 102249; 2中国石油天然气股份有限公司石油化工研究院兰州化工研究中心, 甘肃兰州 730060
  • 收稿日期:2011-08-10 修回日期:2011-09-13 出版日期:2012-01-16 发布日期:2015-05-26

Desilication by Alkaline Treatment and Increasing the Silica to Alumina Ratio of Zeolite Y

SHEN Baojian1,*, QIN Zhengxing1, GAO Xionghou1,2, LIN Feng1, ZHOU Shuge1, SHEN Wen1, WANG Baojie2, ZHAO Hongjuan2, LIU Honghai2   

  1. 1State Key Laboratory of Heavy Oil Processing, the Key Laboratory of Catalysis of CNPC, Faculty of Chemical Engineering, China University of Petroleum, Beijing 102249, China; 2Lanzhou Petrochemical Research Center, Petrochemical Research Institute, PetroChina Company Limited, Lanzhou 730060, Gansu, China
  • Received:2011-08-10 Revised:2011-09-13 Online:2012-01-16 Published:2015-05-26

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摘要： 考察了 “水热处理”以及“碱处理+水热处理”两种方法所制得的超稳 Y 分子筛的骨架硅铝比、孔结构特征以及酸量, 并探讨了“碱处理+水热处理”方法对起始 NaY 分子筛的适应性. 结果表明, 在水热处理前, 对 NaY 分子筛进行碱处理脱硅可在不改变最终样品的骨架超稳化水平和酸量的同时, 样品的介孔体积显著增加. 直接水热处理 NaY 分子筛所得样品介孔体积不超过 0.14 cm3/g, 而先碱处理后水热处理, 所得样品介孔体积可达 0.22 cm3/g. 该法适用于制备骨架硅铝比高的 NaY 分子筛. 起始原料的骨架硅铝比较低时, 所得样品的介孔体积增幅小, 而且微孔受损严重.

关键词: Y 分子筛, 碱处理脱硅, 水热脱铝, 硅铝比, 超稳化处理, 介孔

Abstract: The framework silica to alumina ratio, the porosity, and the acidity properties of ultrastable Y zeolites prepared by ‘steaming’ and by the ‘sequential alkaline treatment and steaming’ of NaY zeolites are compared. The adaptability of the combined alkaline treatment method and steaming toward the type of starting NaY zeolites was studied. By comparison with single steaming treatment the combination of sequential alkaline treatment and steaming affords products with an obviously increased mesopore volume. The level of framework ultrastabilization and acidity of the final products were not affected. The mesopore volume of the ultrastable Y zeolite prepared by steaming dealumination only was no more than 0.14 cm3/g. The mesopore volume of the final product prepared by sequential desilication and dealumination was 0.22 cm3/g. The sequential desilication and dealumination method is suitable for the NaY zeolite with a high framework silica to alumina ratio. A small increase in the mesopore volume and severe micropore damage were evident when the NaY zeolite with a relatively low silica to alumina ratio (SiO2/Al2O3 = 4.8, determined by nuclear magnetic resonance) was used as the starting material for the combined desilication and dealumination treatment.

Key words: zeolite Y, desilication by alkaline treatment, dealumination by steaming, silica to alumina ratio, ultrastabilization treatment, mesopore