铜基催化剂用于一氧化碳催化消除研究进展

doi:10.3724/SP.J.1088.2012.20401

摘要/Abstract

摘要： 催化消除 CO 主要包括 CO 的完全氧化 (CO-COOX) 和优先氧化 (CO-PROX). 首先, 结合本课题组的相关研究, 按照催化剂体系介绍了 Cu 基催化剂在 CO-COOX 中的活性物种和组分之间的相互作用. 其次, 对用于富氢气氛下 CO-PROX 的 Cu 基催化剂进行了系统的分类总结, 重点阐述了 CuO-CeO₂ 催化剂的制备方法、助剂改性、载体调变以及过渡金属离子掺杂 (CuO/Ce_1-xM_xO₂)、反相结构 (CeO₂/CuO) 等方面对 CO-PROX 催化性能的影响. 最后, 总结了 Cu 基催化剂在 CO-PROX 中存在的问题, 并展望了未来的研究趋势.

关键词: 一氧化碳, 完全氧化, 优先氧化, 铜基催化剂

Abstract: Catalytic elimination of CO mainly includes complete oxidation (CO-COOX) and preferential oxidation of CO (CO-PROX). First, combined with our group’s research, a brief introduction to the active species and the interaction between components in Cu-based catalysts for CO-COOX was presented from the perspective of the catalyst system. Then recent progress in CO-PROX under H₂-rich over Cu-based catalysts was systematically summarized. Influence of the preparation method, promoter, and support of CuO-CeO₂ catalyst as well as transition metal ions doped support (CuO/Ce_1-xM_xO₂), and inverse structure (CeO₂/CuO) on the catalytic performance in CO-PROX was elaborated. Finally, the application problems and future research trend of Cu-based catalysts for catalytic removal of CO were discussed and summarized.

Key words: carbon monoxide, complete oxidation, preferential oxidation, Cu-based catalyst

余强, 高飞, 董林. 铜基催化剂用于一氧化碳催化消除研究进展[J]. 催化学报, 2012, 33(8): 1245-1256.

YU Qiang, GAO Fei, DONG Lin. Recent Progress of Cu-Based Catalysts for Catalytic Elimination of CO[J]. Chinese Journal of Catalysis, 2012, 33(8): 1245-1256.

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链接本文: https://www.cjcatal.com/CN/10.3724/SP.J.1088.2012.20401

https://www.cjcatal.com/CN/Y2012/V33/I8/1245

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