Carbon Paste Electrode Prepared from Chemically Modified Multiwall Carbon Nanotubes for the Voltammetric Determination of Isoprenaline in Pharmaceutical and Urine Samples

doi:10.1016/S1872-2067(11)60465-8

摘要/Abstract

摘要： A carbon paste electrode with added multiwall carbon nanotubes chemically modified with N-(3,4-dihydroxyphenethyl)- 3,5-dinitrobenzamide was used as the electrochemical sensor for the determination of trace amounts of isoprenaline. The modified electrode showed good electrocatalytic activity for the anodic oxidation of isoprenaline, which was due to a substantial decrease in the anodic overpotential. Under the optimum conditions, measurements using square wave voltammetry had a linear range in the range of 0.3 to 125.0 µmol/L of isoprenaline and a detection limit of 0.1 µmol/L. The diffusion coefficient and kinetic parameters were determined using electrochemical methods. The relative standard deviation for seven successive assays of 1.0 and 20.0 µmol/L isoprenaline were 1.9% and 2.4%, respectively. This electrochemical sensor was successfully applied for the determination of isoprenaline in human urine and injection solution samples.

关键词: isoprenaline, carbon nanotube, electrode, electrocatalytic effect, voltammetry

Abstract: A carbon paste electrode with added multiwall carbon nanotubes chemically modified with N-(3,4-dihydroxyphenethyl)- 3,5-dinitrobenzamide was used as the electrochemical sensor for the determination of trace amounts of isoprenaline. The modified electrode showed good electrocatalytic activity for the anodic oxidation of isoprenaline, which was due to a substantial decrease in the anodic overpotential. Under the optimum conditions, measurements using square wave voltammetry had a linear range in the range of 0.3 to 125.0 µmol/L of isoprenaline and a detection limit of 0.1 µmol/L. The diffusion coefficient and kinetic parameters were determined using electrochemical methods. The relative standard deviation for seven successive assays of 1.0 and 20.0 µmol/L isoprenaline were 1.9% and 2.4%, respectively. This electrochemical sensor was successfully applied for the determination of isoprenaline in human urine and injection solution samples.

Key words: isoprenaline, carbon nanotube, electrode, electrocatalytic effect, voltammetry

Ali A. ENSAFI, Hajar BAHRAMI, Hassan KARIMI-MALEH, Shadpour MALLAKPOUR. Carbon Paste Electrode Prepared from Chemically Modified Multiwall Carbon Nanotubes for the Voltammetric Determination of Isoprenaline in Pharmaceutical and Urine Samples[J]. 催化学报, 2012, 33(12): 1919-1926.

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参考文献

1 Stryer L. Biochemistry. 3rd Ed. New York: Freeman, 1988
2 Voet D, Voet J G. Biochemistry. New York: Wiley, 1995. 1268
3 Lupetti K O, Vieira I C, Fatibello-Filho O. Talanta, 2001, 57: 135
4 Solich P, Polydorou C K, Koupparis M A, Efstathiou C E. J Pharm Biomed Anal, 2000, 22: 781
5 Nevado J J B, Gallego J M L, Laguna P B. Anal Chim Acta, 1995, 300: 293
6 Jeon H K, Nohta H, Nagaoka H, Ohkura Y. Anal Sci, 1991, 7: 257
7 Nohta H, Yukizawa T, Ohkura Y, Yoshimura M, Ishida V, Ya-maguchi M. Anal Chim Acta, 1997, 344: 233
8 Alberts G, Lameris T, van den Meiracker A H, Veld A J M I, Boomsma F. J Chromatogr B, 1999, 730: 213
9 Villanueva Camanas R M, Sanchis Mallols J M, Torres Lapasio J R, Ramis-Ramos V. Analyst, 1995, 120: 1767
10 El-Obeid H A. Anal Lett, 1984, 17: 771
11 Watson J R, Lawrence R C. J Pharm Sci, 1977, 66: 560
12 Yamaguchi M, Ishida J, Yoshimura M. Analyst, 1998, 123: 307
13 Qu Y, Moons L, Vandesande F. J Chromatogr Biomed Appl, 1997, 704: 351
14 Mashige F, Matsushima Y, Miyata C, Yamada R, Kanazawa H, Sakuma I, Takai N, Shinozuka N, Ohkubo A, Nakahara K. Biomed Chromatogr BMC, 1995, 9: 221
15 Elrod Jr L, Schmit J L, Morley J A. J Chromatogr A, 1996, 723: 235
16 Zhou G J, Zhang G F, Chem H Y. Anal Chim Acta, 2002, 463: 257
17 Zhang C, Huang J, Zhang Z, Aizawa M. Anal Chim Acta, 1998, 374: 105
18 Al Warthan A A, Al-Tamrah S A, Al-Akel A A. Anal Sci, 1994, 10: 449
19 Ensafi A A, Dadkhah M, Karimi-Maleh H. Colloids Surf B, 2011, 84: 148
20 Ensafi A A, Karimi-Maleh H. Drug Test Anal, 2011, 3: 325
21 Ensafi A A, Khoddami E, Karimi-Maleh H. Int J Electrochem Sci, 2011, 6: 2596
22 Ahmed M U, Hossain M M, Tamiyaa E. Electroanalysis, 2008, 20: 616
23 De Marco R, Clarke G, Pejcicb B. Electroanalysis, 2007, 19: 1987
24 Santana M H P, Silva L M D, Freitas A C, Boodts J F C, Fernandes K C, De Faria L A. J Hazard Mater, 2009, 164: 10
25 Pihel K, Schroeder T J, Mark Wightman R. Anal Chem, 1994, 66: 4532
26 Shahrokhian S, Amiri M. Microchim Acta, 2007, 157: 149
27 Beitollahi H, Karimi-Maleh H, Khabazzadeh H. Anal Chem, 2008, 80: 9848
28 Ensafi A A, Karimi-Maleh H. J Electroanal Chem, 2010, 640: 75
29 El-Mhammedi M A, Achak M, Hbid M, Bakasse M, Hbid T, Chtaini A. J Hazard Mater, 2009, 170: 590
30 Sun W, Li X, Wang Y, Li X, Zhao C, Jiao K. Bioelectrochem-istry, 2009, 75: 170
31 Jin G P, Chen Q Z, Ding Y F, He J B. Electrochim Acta, 2007, 52: 2535
32 El-Mhammedi M A, Bakasse M, Chtaini A. J Hazard Mater, 2007, 145: 1
33 Sun Y X, Wang S F, Zhang X H, Huang Y F, Sens Actuators B, 2006, 113: 156
34 Lev O, Wu Z, Bharathi S, Glezer V, Modestov A, Gun J, Rabinovich L, Sampath S. Chem Mater, 1997, 9: 2354
35 Ensafi A A, Karimi-Maleh H, Mallakpour S, Hatami M. Sens Actuators B, 2011, 155: 464
36 Ensafi A A, Karimi-Maleh H. Drug Test Analysis, 2011, DOI 10.1002/dta.286
37 Ensafi A A, Dadkhah-Tehrani S, Karimi-Maleh H. Anal Sci, 2011, 27: 409
38 Karimi-Maleh H, Ensafi A A, Allafchian A R. J Solid State Electrochem, 2010, 14: 9
39 Ensafi A A, Karimi-Maleh H. Int J Electrochem Sci, 2010, 5: 1484
40 Ensafi A A, KarimiMaleh H. Electroanalysis, 2010, 22: 2558
41 Mirmomtaz E, Ensafi A A, Karimi-Maleh H. Electroanalysis, 2008, 20: 1973
42 Ensafi A A, Karimi-Maleh H, Mallakpour S. Electroanalysis, 2011, 23: 1478
43 Bard A J, Faulkner L R. Electrochemical Methods, Funda-mentals and Applications. New York: Wiley, 2001
44 Galus Z. Fundamentals of Electrochemical Analysis. New York: Ellis Horwood, 1976
45 Raoof J B, Ojani R, Karimi-Maleh H. Electroanalysis, 2009, 20: 1259
46 Beitollahi H, Raoof J B, Karimi-Maleh H, Hosseinzadeh R. J Solid State Electrochem, 2012, 16: 1701

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