清液体系中T型分子筛膜的高重复性合成与渗透汽化性能

doi:10.1016/S1872-2067(11)60478-6

催化学报 ›› 2013, Vol. 34 ›› Issue (3): 542-547.DOI: 10.1016/S1872-2067(11)60478-6

清液体系中T型分子筛膜的高重复性合成与渗透汽化性能

张小亮, 宋鑫, 邱灵芳, 丁民正, 胡娜, 周荣飞, 陈祥树

江西师范大学化学化工学院, 江西省无机膜材料工程技术研究中心, 江西南昌 330022

收稿日期:2012-09-05 修回日期:2012-10-12 出版日期:2013-04-02 发布日期:2013-04-03
通讯作者: 陈祥树
基金资助:
国家自然科学基金(20966003,21106059);国家高技术研究发展计划(863计划,2012AA03A609);江西省科技支撑计划重点项目和自然科学基金(2010BGA01200,2010GQH0068,20122BAB203018);江西省教育厅科技项目(GJJ11377).

Synthesis and pervaporation performance of highly reproducible zeolite T membranes from clear solutions

ZHANG Xiaoliang, SONG Xin, QIU Lingfang, DING Minzheng, HU Na, ZHOU Rongfei,CHEN Xiangshu

Jiangxi Inorganic Membrane Materials Engineering Research Centre, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, Jiangxi, China

Received:2012-09-05 Revised:2012-10-12 Online:2013-04-02 Published:2013-04-03
Supported by:
This work was supported by the National Natural Science Foundation of China (20966003, 21106059), the National High Technology Research and Development Program of China (863 Program, 2012AA03A609), Jiangxi Provincial Department of Science and Technology (2010BGA01200, 2010GQH0068, 20122BAB203018), and Jiangxi Provincial Department of Education (GJJ11377).

摘要/Abstract

摘要：

以自制微米级分子筛为晶种,在清液体系中成功合成出高性能的T型分子筛膜,考察了硅铝比、水硅比、碱度及合成温度与时间等条件对膜的生长和渗透汽化性能的影响.结果表明,在摩尔组成为1SiO₂:0.015Al₂O₃:0.41(Na₂O+K₂O):30H₂O的清液体系中,于423K晶化6h的条件下可较快地形成一层厚度为5μm的连续致密纯相T型分子筛膜,较大缩短了膜合成时间且提高了膜致密性.在优化条件下所合成的膜具有优良的分离性能和高重复性.348K时,在10wt%水-90wt%异丙醇混合物体系中膜的渗透通量和分离因子分别高达4.20kg/(m²·h)和7800.

关键词: T型分子筛膜, 重复性, 清液, 二次生长法, 渗透汽化

Abstract:

Zeolite T membranes with very good permeation performance were successfully synthesized on porous mullite supports by the secondary growth method with homemade microsized seeds from clear solutions. The influence of synthesis parameters such as the molar ratios of SiO₂/Al₂O₃ and H₂O/SiO₂, alkalinity, synthesis temperature, and crystallization time on membrane growth and permeation performance was investigated systematically. It is found that these parameters strongly affect the zeolite T growth and pervaporation performance of the membranes. Under the optimized synthesis conditions of 1SiO₂:0.015Al₂O₃:0.41(Na₂O+K₂O):30H₂O, the crystallization time was shortened to 6 h at 423 K and a continuous and dense T-type zeolite layer as thin as 5 μm formed on the surface of the support. It significantly improved the membrane density and permselective properties. A permeation flux and separation factor of 4.20 kg/(m²·h) and 7800, respectively, were obtained with the as-synthesized membrane for 10 wt% water-90 wt% #em/em#-propanol mixtures at 348 K. It also exhibited a very good pervaporation performance for water/ethanol mixtures separation. This high quality zeolite T membrane could be reproducibly prepared.

Key words: Zeolite T membrane, Reproducibility, Clear solution, Secondary growth, Pervaporation

张小亮, 宋鑫, 邱灵芳, 丁民正, 胡娜, 周荣飞, 陈祥树. 清液体系中T型分子筛膜的高重复性合成与渗透汽化性能[J]. 催化学报, 2013, 34(3): 542-547.

ZHANG Xiaoliang, SONG Xin, QIU Lingfang, DING Minzheng, HU Na, ZHOU Rongfei,CHEN Xiangshu. Synthesis and pervaporation performance of highly reproducible zeolite T membranes from clear solutions[J]. Chinese Journal of Catalysis, 2013, 34(3): 542-547.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(11)60478-6

https://www.cjcatal.com/CN/Y2013/V34/I3/542

参考文献

[1] Drioli E, Fontananova E, Bonchio M, Carraro M, Gardan M, Scorrano G. Chin J Catal (催化学报), 2008, 29: 1152

[2] Zhang X L, Wang W P, Xiong G X, Yang W Sh. Chin J Catal (张小亮, 王卫平, 熊国兴, 杨维慎. 催化学报), 2010, 31: 1049

[3] Li X M, Wang Zh B, Zheng J, Shao Sh Q, Wang Y Ch, Yan Y Sh. Chin J Catal (李显明, 王正宝, 郑洁, 邵世群, 王胤超, 严玉山. 催化学报), 2011, 32: 217

[4] Cui Y, Kita H, Okamoto K I. Chem Commun, 2003: 2154

[5] Cui Y, Kita H, Okamoto K I. J Mater Chem, 2004, 14: 924

[6] Cui Y, Kita H, Okamoto K I. J Membr Sci, 2004, 236: 17

[7] Kondo M, Kita H. J Membr Sci, 2010, 361: 223

[8] Mirfendereski M, Sadrzadeh M, Mohammadi T. Int J Greenhouse Gas Control, 2008, 2: 531

[9] Mirfendereski S M, Mazaheri T, Sadrzadeh M, Mohammadi T. Sep Purif Technol, 2008, 61: 317

[10] Zhou H, Li Y Sh, Zhu G Q, Liu J, Lin L W, Yang W Sh. Chin J Catal (周汉, 李砚硕, 朱广奇, 刘杰, 林励吾, 杨维慎. 催化学报), 2008, 29: 592

[11] Zhou H, Li Y S, Zhu G Q, Liu J, Yang W S. Sep Purif Technol, 2009, 65: 164

[12] Zhou R F, Chen X Sh, Liu D, Qi H, Lin X, Xu N P. J Chin Ceram Soc (周荣飞, 陈祥树, 刘丹, 漆虹, 林晓, 徐南平. 硅酸盐学报), 2007, 35: 1270

[13] Zhou R F, Hu N, Yuan H, Zhu M H, Wang Zh Zh, Chen X Sh. J Chin Inorg Chem (周荣飞, 胡娜, 袁慧, 朱美华, 王振卓, 陈祥树. 无机化学学报), 2009, 25: 1439

[14] Zhou R F, Zhang F, Hu N, Chen X S, Kita H. Chem Lett, 2011, 40: 1383

[15] Zhang X L, Song X, Qiu L F, Zhou R F, Chen X Sh. Chin J Inorg Chem (张小亮, 宋鑫, 邱灵芳, 周荣飞, 陈祥树. 无机化学学报), 2012, 28: 1914

[16] Breck D W, Acara N A. US Patent 2 950 952. 1960

[17] Wang X Q, Chen Zh C, He Sh H, Mao Y G, Li Sh, Song T Y, Xu R R. Chem J Chin Univ (王杏乔, 陈忠财, 何淑华, 毛友刚, 李舒, 宋天佑, 徐如人. 高等学校化学学报), 1984, 5: 83

[18] Occelli M L, Innes R A, Pollack S S, Sanders J V. Zeolites, 1987, 7: 265

[19] Cichocki A. Zeolites, 1991, 11: 758

[20] Ueda S, Nishimura M, Koizumi M. Stud Surf Sci Catal, 1985, 24: 105

[21] Matin K T, Bastani D, Kazemian H. Chem Eng Technol, 2009, 32: 1042

[22] Mirfendereski M, Mohammadi T. Powder Technol, 2011, 206: 345

[23] Yu J H. Stud Surf Sci Catal, 2007, 168: 39

清液体系中T型分子筛膜的高重复性合成与渗透汽化性能

Synthesis and pervaporation performance of highly reproducible zeolite T membranes from clear solutions

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 5

编辑推荐

Metrics

[1]	任秀秀, 杨建华, 陈赞, 杨兴宝, 鲁金明, 张艳, 王金渠. 含氟体系下高性能丝光沸石分子筛膜的制备及其性能[J]. 催化学报, 2012, 33(9): 1558-1564.
[2]	邹昀, 童张法, 刘琨, 冯献社. 间歇反应器内醋酸丁酯酯化反应与渗透汽化集成过程的模型计算[J]. 催化学报, 2010, 31(8): 999-1005.
[3]	周汉;李砚硕;朱广奇;刘杰;林励吾;杨维慎; 中国科学院研究生院;北京 000. 微波合成a&b取向的T型分子筛膜及其在渗透汽化耦合酯化反应中的应用[J]. 催化学报, 2008, 29(7): 592-594.
[4]	李砚硕;刘杰;陈红亮;杨维慎;林励吾. 微波加热合成含有极少量非分子筛缺陷孔的LTA型分子筛膜[J]. 催化学报, 2006, 27(7): 544-546.
[5]	陈红亮;李砚硕;刘杰;杨维慎*;林励吾. 利用原位水热合成在二氧化硅陶瓷管上制备高性能的Silicalite-1分子筛膜[J]. 催化学报, 2005, 26(12): 1039-1041.