焙烧与预处理条件对 Co3O4 催化氧化 CO 性能的影响

doi:10.1016/S1872-2067(11)60484-1

催化学报 ›› 2013, Vol. 34 ›› Issue (2): 283-293.DOI: 10.1016/S1872-2067(11)60484-1

焙烧与预处理条件对 Co₃O₄ 催化氧化 CO 性能的影响

余运波a,*, 赵娇娇a, 韩雪a, 张燕a, 秦秀波b, 王宝义b

a中国科学院生态环境研究中心, 北京 100085; b中国科学院高能物理研究所, 核分析技术重点实验室, 北京 100049

收稿日期:2012-09-20 修回日期:2012-11-10 出版日期:2013-02-05 发布日期:2013-02-05

Influence of calcination and pretreatment conditions on the activity of Co₃O₄ for CO oxidation

YU Yunbo a,*, ZHAO Jiaojiao a, HAN Xue a, ZHANG Yan a, QIN Xiubo b, WANG Baoyi b

a Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; b Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

Received:2012-09-20 Revised:2012-11-10 Online:2013-02-05 Published:2013-02-05

摘要/Abstract

摘要： 采用沉淀法制备了 Co₃O₄, 考察了焙烧和预处理条件对其结构、低温催化氧化 CO 性能的影响. 热重分析表明, 未经焙烧的样品以 Co(OH)₂CO₃ 的形式存在, 150~400 ^oC 空气气氛中焙烧后, 样品以立方相 Co₃O₄ 的形式存在. N2 吸附-脱附法、X 射线衍射、透射电镜及活性测试结果表明, 以纳米颗粒物存在的 Co₃O₄ 的比表面积、颗粒尺寸、催化氧化 CO 活性与焙烧温度密切相关. 正电子湮没寿命谱、O₂-程序升温脱附与定温条件下 CO 氧化测试结果表明, 合适温度 (150~250 ^oC) 下 N₂ 预处理有利于 Co₃O₄ 表面氧空穴团的形成, 它在吸附活化分子氧以及 CO 催化氧化反应中起到关键作用. 同时讨论了预处理作用下Co₃O₄表面氧空穴的再构机制.

关键词: 四氧化三钴, 焙烧, 预处理, 氧空穴, 一氧化碳氧化

Abstract: The influence of calcination and pretreatment conditions on the structure of Co₃O₄ and its activity for CO oxidation were studied. TG analysis indicated that the precursor of Co₃O₄ prepared by a precipitation method was present in the form of cobalt hydroxide carbonate, calcination of which within the temperature range of 150–400 ^oC in air resulted in the formation of cubic phase Co₃O₄. N₂ adsorption-desorption, powder X-ray diffraction, transmission electron microscopy, and activity test results showed that the prepared Co₃O₄ samples were comprised of nanoparticles, with the specific surface area and size distribution closely related to the calcination temperature. Over these samples, a size dependence of the catalytic activity for CO oxidation was clearly observed. As identified by positron annihilation lifetime spectrum, low temperature oxygen temperature-programmed desorption, and durability testing for CO oxidation, pretreatment of Co₃O₄ in N₂ within the temperature range 150–250 ^oC favors the formation of surface oxygen vacancy clusters, the occurrence of which would be beneficial for the adsorption and activation of O₂, and also for the catalytic oxidation of CO. Meanwhile, the reconstruction of oxygen vacancies on the surface of Co₃O₄, induced by the pretreatment process, was also discussed.

Key words: Tricobalt tetraoxide, Calcination, Pretreatment, Oxygen vacancy, Carbon monoxide oxidation

余运波, 赵娇娇, 韩雪, 张燕, 秦秀波, 王宝义. 焙烧与预处理条件对 Co₃O₄ 催化氧化 CO 性能的影响[J]. 催化学报, 2013, 34(2): 283-293.

YU Yun-Bo, ZHAO Jiao-Jiao, HAN Xue, ZHANG Yan, QIN Xiu-Bo, WANG Bao-Yi. Influence of calcination and pretreatment conditions on the activity of Co₃O₄ for CO oxidation[J]. Chinese Journal of Catalysis, 2013, 34(2): 283-293.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(11)60484-1

https://www.cjcatal.com/CN/Y2013/V34/I2/283

参考文献

[1] Royer S, Duprez D. ChemCatChem, 2011, 3: 24
[2] Zhou K B, Li Y D. Angew Chem, Int Ed, 2012, 51: 602
[3] Jansson J, Palmqvist A E C, Fridell E, Skoglundh M, Österlund L, Thormählen P, Langer V. J Catal, 2002, 211: 387
[4] Broqvist P, Panas I, Persson H. J Catal, 2002, 210: 198
[5] Xie X W, Li Y, Liu Zh Q, Haruta M, Shen W J. Nature, 2009, 458: 746
[6] Hu L H, Sun K Q, Peng Q, Xu B Q, Li Y D. Nano Res, 2010, 3: 363
[7] Ren Y, Ma Zh, Qian L P, Dai Sh, He H Y, Bruce P G. Catal Lett, 2009, 131: 146
[8] Razdobarov V A, Sadykov V A, Veniaminov S A, Bulgakov N N, Kovalenko O N, Pankratiev Yu D, Popovskii V V, Kryukova G N, Tikhov S F. React Kinet Catal Lett, 1988, 37: 109
[9] Sadykov V A, Tikhov S F, Tsybulya S V, Kryukova G N, Veniaminov S A, Kolomiichuk V N, Bulgakov N N, Paukshtis E A, Ivanov V P, Koshcheev S V, Zaikovskii V I, Isupova L A, Burgina L B. J Mol Catal A, 2000, 158: 361
[10] Luo J Y, Meng M, Li X, Li X G, Zha Y Q, Hu T D, Xie Y N, Zhang J. J Catal, 2008, 254: 310
[11] Lou Y, Wang L, Zhang Y H, Zhao Zh Y, Zhang Zh G, Lu G Zh, Guo Y. Catal Today, 2011, 175: 610
[12] Wang Y Zh , Zhao Y X , Gao Ch G, Liu D Sh. Catal Lett, 2008, 125: 134
[13] Yu Y B, Takei T, Ohashi H, He H, Zhang X L, Haruta M. J Catal, 2009, 267: 121
[14] Cunningham D A H, Kobayashi T, Kamijo N, Haruta M. Catal Lett, 1994, 25: 257
[15] 李亚栋, 贺蕴普, 李龙泉, 钱逸泰. 高等化学学报 (Li Y D, He Y P, Li L Q, Qian Y T. Chem J Chin Univ), 1999, 20: 519
[16] Li B X, Xie Y, Wu Ch Zh, Li Zh Q, Zhang J. Mater Chem Phys, 2006, 99: 479
[17] Wang Y Zh, Zhao Y X , Gao Ch G , Liu D Sh. Catal Lett, 2007, 116: 136
[18] Kuriplach J, Morales A L, Dauwe C, Segers D, Šob M. Phys Rev B, 1998, 58: 10475
[19] 曹兴忠, 王宝义, 王平, 马雁云, 秦秀波, 魏龙. 高能物理与核物理 (Cao X Zh, Wang B Y, Wang P, Ma Y Y, Qin X B, Wei L. High Energy Phys Nuc Phys), 2006, 30: 1196
[20] 戚盛勇, 刘复汉. 催化学报 (Qi Sh Y, Liu F H. Chin J Catal), 1987, 8: 418
[21] Liu X W, Zhou K B, Wang L, Wang B Y, Li Y D. J Am Chem Soc, 2009, 131: 3140
[22] Idriss H, Scott M, Llorca J, Chan S C, Chiu W, Sheng P Y, Yee A, Blackford M A, Pas S J, Hill A J, Alamgir F M, Rettew R, Petersburg C, Senanayake S D, Barteau M A. ChemSusChem, 2008, 1: 905
[23] Jiang D E, Dai Sh. Phys Chem Chem Phys, 2011, 13: 978
[24] Zhang Ch J, Michaelides A, King D A., Jenkins S J. Phys Rev B, 2009, 79: 075433
[25] Mitsui T, Rose M K, Fomin E, Ogletree D F, Salmeron M. Nature, 2003, 422: 705
[26] Golodets G I, Ross J R H. Stud Surf Sci Catal, 1983, 15: 280

焙烧与预处理条件对 Co₃O₄ 催化氧化 CO 性能的影响

Influence of calcination and pretreatment conditions on the activity of Co₃O₄ for CO oxidation

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘海峰, 黄祥, 陈加藏. 电子态调控促进氢气无损耗纯化中CO的光致富集和氧化[J]. 催化学报, 2023, 51(8): 49-54.
[2]	王宇, Jaime Gallego, 汪炜, Phillip Timmer, 丁敏, Alexander Spriewald Luciano, Tim Weber, Lorena Glatthaar, 郭杨龙, Bernd M. Smarsly, Herbert Over. 析出型LaFe_0.9Ru_0.1O₃钙钛矿催化剂在丙烷催化氧化反应中的自活化现象[J]. 催化学报, 2023, 54(11): 250-264.
[3]	陈宏彬, 叶雅倩, 陈鑫智, 张利利, 刘国学, 王素清, 丁良鑫. 中空四氧化三钴纳米球镶嵌的氮掺杂多孔碳纳米纤维: 锂-氧电池氧电极双功能催化剂[J]. 催化学报, 2022, 43(6): 1511-1519.
[4]	贾雪梅, 沈紫晨, 韩巧凤, 毕慧平. 相转移有机前驱体BiOAc_0.6Br_0.2I_0.2固溶体合成表面富有氧空位的棒状S型Bi₄O₅I₂/Bi₄O₅Br₂异质结[J]. 催化学报, 2022, 43(2): 288-302.
[5]	武慧中, 王佳栋, 陈瑞敏, 袁潮苇, 张锦, 张育新, 盛剑平, 董帆. 具有独特电子结构的锌掺杂SnO₂介导形成氧空位实现高效稳定的光催化降解甲苯[J]. 催化学报, 2021, 42(7): 1195-1204.
[6]	Yanan Gao, Fu-Kuo Chiang, Shaojie Li, Long Zhang, Peng Wang, Emiel J. M. Hensen. α-Fe₂O₃形貌对Au/α-Fe₂O₃催化一氧化碳氧化反应性能的影响[J]. 催化学报, 2021, 42(4): 658-665.
[7]	吴凡, 贺雷, 李文翠, 路饶, 王阳, 陆安慧. 氮化硼负载的高分散Au-CuO_x纳米颗粒用于低温CO氧化[J]. 催化学报, 2021, 42(3): 388-395.
[8]	Ya-Qiong Su, Long Zhang, Valery Muravev, Emiel J. M. Hensen. 过渡金属掺杂铈中晶格氧的活化[J]. 催化学报, 2020, 41(6): 977-984.
[9]	Valentín Briega-Martos, Enrique Herrero, Juan M. Feliu. Pt单晶电极上氧和过氧化氢还原反应研究进展[J]. 催化学报, 2020, 41(5): 732-738.
[10]	宋三召, 周靖, 孙健, 张诗雨, 林逍, Zhiwei Hu, 胡钧, 张林娟, 王建强. Sr掺杂钙钛矿体系中高活性氧析出反应机制[J]. 催化学报, 2020, 41(4): 592-597.
[11]	路饶, 贺雷, 王阳, 高新芊, 李文翠. 镍掺杂对氧化铝纳米片负载金催化剂在CO氧化反应中的促进作用[J]. 催化学报, 2020, 41(2): 350-356.
[12]	赵佳华, 束远, 张鹏飞. CTAB辅助的机械化学法合成介孔Fe₃O₄和Au@Fe₃O₄催化剂[J]. 催化学报, 2019, 40(7): 1078-1084.
[13]	杨军, 刘雨溪, 邓积光, 赵星天, 张昆锋, 韩卓, 戴洪兴. AgAuPd/meso-Co₃O₄高效甲醇氧化催化剂[J]. 催化学报, 2019, 40(6): 837-848.
[14]	郇伟伟, 李洁, 嵇家辉, 邢明阳. 二氧化铈促进钴氧化物表面氧化一氧化碳的原位表征研究[J]. 催化学报, 2019, 40(5): 656-663.
[15]	高新芊, 陆文多, 户守昭, 李文翠, 陆安慧. 棒状多孔氧化铝负载氧化铬催化丙烷脱氢反应性能[J]. 催化学报, 2019, 40(2): 184-191.