急冷非晶态镍合金催化剂的研究开发和工业应用

doi:10.1016/S1872-2067(11)60486-5

催化学报 ›› 2013, Vol. 34 ›› Issue (5): 828-837.DOI: 10.1016/S1872-2067(11)60486-5

急冷非晶态镍合金催化剂的研究开发和工业应用

宗保宁^a, 慕旭宏^a, 张晓昕^a, 孟祥堃^a, 乔明华^b

a 中国石油化工股份有限公司石油化工科学研究院, 催化材料和反应工程国家重点实验室, 北京 100083;
b 复旦大学化学系, 上海市分子催化和功能材料重点实验室, 上海 200433

收稿日期:2012-12-20 修回日期:2013-05-20 出版日期:2013-05-06 发布日期:2013-05-06
通讯作者: 宗保宁
基金资助:
国家重点基础研究发展计划(973计划,2012CB224806).

Research, development, and application of amorphous nickel alloy catalysts prepared by melt-quenching

ZONG Baoning^a, MU Xuhong^a, ZHANG Xiaoxin^a, MENG Xiangkun^a, QIAO Minghua^b

a State key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, Sinopec, Beijing 100083, China;
b Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China

Received:2012-12-20 Revised:2013-05-20 Online:2013-05-06 Published:2013-05-06
Supported by:
This work was supported by the National Basic Research Program of China (973 Program, 2012CB224806).

摘要/Abstract

摘要：

Raney Ni催化剂是石油化学工业用量最大的催化剂之一,通过急冷技术将其晶态结构转变为非晶态结构,能够提高加氢活性.但非晶态合金热稳定性差、比表面积小限制了这类催化材料的工业应用.通过加入少量稀土元素,使非晶态 Ni 晶化温度提高200 K以上; 通过加入Al再碱抽Al,使非晶态Ni比表面积增加100倍以上; 通过加入功能助剂调节非晶态Ni的加氢选择性、增加抗酸碱腐蚀性和磁性,从而形成了系列非晶态Ni加氢催化剂 (商品名为 SRNA).其中,SRNA-1 用于药物中间体加氢; SRNA-2用于葡萄糖加氢制山梨醇; SRNA-3用于汽、柴油吸附脱硫; SRNA-4用于己内酰胺加氢精制; SRNA-5 用于苯甲酸加氢中替代Pd/C催化剂,使后者的用量减少了50%.

关键词: 非晶态合金, 骨架镍, 加氢, 脱硫, 工业化

Abstract:

Raney Ni is one of the most widely used catalysts in the petrochemical industry. This material's intrinsic catalytic activity for hydrogenation may be enhanced by transforming the crystalline Ni-based alloy into an amorphous structure via melt-quenching. The meta-stability and low specific surface area of such amorphous alloys, however, can severely restrict their catalytic applications. Our work has demonstrated that the incorporation of rare earth (RE) elements increases the crystallization temperature of an amorphous Ni catalyst by 200 K. Related experimentation has determined that the specific surface area of such catalysts is dramatically increased by two orders of magnitude following alloying with Al and subsequent caustic leaching. In addition, by introducing a third metal as a promoter, the hydrogenation selectivity, corrosion resistance and magnetism of these materials may be precisely adjusted, giving rise to a family of skeletal amorphous Ni alloy catalysts, to which we apply the trade name SRNA. Among these catalysts, the SRNA-1 catalyst is used for the hydrogenation of pharmaceutical intermediates, SRNA-2 is employed for the hydrogenation of glucose into sorbitol, SRNA-3 is effective in the adsorptive desulfurization of gasoline and diesel and SRNA-4 is used for the purification of caprolactam. In addition, the SRNA-5 catalyst is useful in the hydrogenation of benzoic acid as a partial substitute for the costly Pd/C catalyst, reducing consumption of the latter during the hydrogenation process by almost 50%.

Key words: Amorphous alloy, Skeletal nickel, Hydrogenation, Desulfurization, Industrialization

宗保宁, 慕旭宏, 张晓昕, 孟祥堃, 乔明华. 急冷非晶态镍合金催化剂的研究开发和工业应用[J]. 催化学报, 2013, 34(5): 828-837.

ZONG Baoning, MU Xuhong, ZHANG Xiaoxin, MENG Xiangkun, QIAO Minghua. Research, development, and application of amorphous nickel alloy catalysts prepared by melt-quenching[J]. Chinese Journal of Catalysis, 2013, 34(5): 828-837.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(11)60486-5

https://www.cjcatal.com/CN/Y2013/V34/I5/828

参考文献

[1] Seymour R, Montgomery S. Murray Raney-Pioneer Catalyst Producer. In: Davis B H, Hettinger W P eds. Heterogeneous Catalysis-Selected American Histories, Vol 222. Washington: American Chemical Society, 1983. 491

[2] Yokoyama A, Komiyama H, Inoue H, Masumoto T, Kimura H M. J Catal, 1981, 68: 355

[3] Zong B N. [PhD Dissertation]. Beijing: Research Institute of Petroleum Processing, 1991

[4] Chen H S. Acta Metall, 1976, 24: 153

[5] Chen H S. Appl Phys Lett, 1976, 29: 12

[6] Mu X H, Zong B N, Min E Z, Wang X, Wang Y, Zhang X X, Shu X T. US Patent 6368996B1. 2002

[7] Xie F Z, Chu X W, Hu H R, Qiao M H, Yan S R, Zhu Y L, He H Y, Fan K N, Li H X, Zong B N, Zhang X X. J Catal, 2006, 241: 211

[8] Clarke S H, Dicks A L, Pointon K, Smith T A, Swann A. Catal Today, 1997, 38: 411

[9] Rath L K, Longanbach J R. Energy Sources, 1991, 13: 443

[10] Rostrup-Nielsen J R. Steam Reforming Catalysts. Copenhagen: Danish Technical Press, 1975

[11] Rostrup-Nielsen J R. Phys Chem Chem Phys, 2001, 3: 283

[12] Cortright R D, Davda R R, Dumesic J A. Nature, 2002, 418: 964

[13] Huber G W, Shabaker J W, Dumesic J A. Science, 2003, 300: 2075

[14] Shabaker J W, Huber G W, Dumesic J A. J Catal, 2004, 222: 180

[15] Lemons R A. J Power Sources, 1990, 29: 251

[16] Liu B, Qiao M H, Deng J F, Fan K N, Zhang X X, Zong B N. J Catal, 2001, 204: 512

[17] Kroschwitz J I, Howe-Grant M. Kirk-Othmer Encyclopedia of Chemical Technology. 4th Ed, Vol. 13. New York: John Wiley & Sons, 1995. 961

[18] Roberts J D, Caserio M C. Basic Principles of Organic Chemistry. California: W. A. Benjamin, 1964

[19] Stern A C, Boubel R W, Turner D B, Fox D L. Fundamentals of Air Pollution. 2nd Ed. New York: Academic Press, 1984

[20] Bartholomew C H, Agrawal P K, Katzer J R. Adv Catal, 1982, 31: 135

[21] Oudar J. Catal Rev-Sci Eng, 1980, 22: 171

[22] Plantenga F L, Leliveld R G. Appl Catal A, 2003, 248: 1

[23] Rossini S. Catal Today, 2003, 77: 467

[24] Babich I V, Moulijin J A. Fuel, 2003, 82: 607

[25] Hernández-Maldonado A J, Yang R T. Ind Eng Chem Res, 2004, 43: 1081

[26] Yang R T. Adsorbents: Fundamentals and Applications. New York: Wiley, 2003

[27] Yang R T, Hernández-Maldonado A J, Yang F H. Science, 2003, 301: 79

[28] Hurd C D, Runder B. J Am Chem Soc, 1951, 73: 5157

[29] Pizey J S. Synthetic Reagents, Vol 2. New York: Wiley, 1974

[30] Spera M L, Harman W D. J Am Chem Soc, 1997, 119: 8843

[31] Hu H R, Qiao M H, Xie F Z, Fan K N, Lei H, Tan D L, Bao X H, Lin H L, Zong B N, Zhang X X. J Phys Chem B, 2005, 109: 5186

[32] Jirsak T, Dvorak J, Rodriguez J A. J Phys Chem B, 1999, 103: 5550

[33] Handbook of X-ray Photoelectron Spectroscopy. Perkin Elmer Corporation, 1992

[34] Barrio V L, Arias P L, Cambra J F, Güemez M B, Campos-Martin J M, Pawelec B, Fierro J L G. Appl Catal A, 2003, 248: 211

[35] Schoofs G R, Preston R E, Benziger J B. Langmuir, 1985, 1: 313

[36] Hu H R, Qiao M H, Wang S, Fan K N, Li H X, Zong B N, Zhang X X. J Catal, 2004, 221: 612

[37] Balandin A A. Z Phys Chem, 1929, 132: 289

[38] Vradman L, Herskowitz M, Korin E, Wisniak J. Ind Eng Chem Res, 2001, 40: 1589

[39] Zong B N, Meng X K, Lin H L, Zhang X X, Mu X H, Min E Z. US Patent 6875340B2. 2005

[40] Zhang X X, Zong B N, Meng X K, Wang X, Mu X H, Min E Z. CN Patent 1179021C. 2004

[41] Meng X K, Mu X H, Zong B N, Min E Z, Zhu Z H, Fu S B, Luo Y B. Catal Today, 2003, 79-80: 21

[42] Zong B N, Zhang X X, Qiao M H. AIChE J, 2009, 55: 192

急冷非晶态镍合金催化剂的研究开发和工业应用

Research, development, and application of amorphous nickel alloy catalysts prepared by melt-quenching

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘诗瑶, 巩玉同, 杨晓, 张楠楠, 刘会斌, 梁长海, 陈霄. 具有富电子镍位点的耐酸金属间化合物CaNi₂Si₂催化剂用于不饱和有机酸酐/酸的水相加氢[J]. 催化学报, 2023, 50(7): 260-272.
[2]	夏思源, 李奇远, 张仕楠, 许冬, 林秀, 孙露菡, 许景三, 陈接胜, 李国栋, 李新昊. Pd纳米立方体异质结尺寸依赖的电子界面效应对苯酚加氢反应的促进作用[J]. 催化学报, 2023, 49(6): 180-187.
[3]	张锋伟, 郭河芳, 刘萌萌, 赵阳, 洪峰, 李静静, 董正平, 乔波涛. 表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢[J]. 催化学报, 2023, 48(5): 195-204.
[4]	曾严, 王慧, 杨惠茹, 隽超, 李丹, 温晓东, 张帆, 邹吉军, 彭冲, 胡常伟. 镍纳米粒子耦合氧空位高效催化转化棕榈酸制备烷烃[J]. 催化学报, 2023, 47(4): 229-242.
[5]	Eun Hyup Kim, Min Hee Lee, Jeehye Kim, Eun Cheol Ra, Ju Hyeong Lee, Jae Sung Lee. 无碱CO₂加氢高效制甲酸Pd/g-C₃N₄催化剂的单原子和纳米簇的协同作用[J]. 催化学报, 2023, 47(4): 214-221.
[6]	杨成功, 王冬娥, 黄蓉, 韩健强, 塔娜, 马怀军, 曲炜, 潘振栋, 王从新, 田志坚. 高效稳定的MoS₂-TiO₂纳米复合催化剂用于浆态床菲催化加氢[J]. 催化学报, 2023, 46(3): 125-136.
[7]	刘玥, 章伟, 刘海超. 三氧化钨基催化剂在纤维素选择性转化合成二元醇反应中的活性相态[J]. 催化学报, 2023, 46(3): 56-63.
[8]	聂超, 龙向东, 刘琪, 王嘉, 展飞, 赵泽伦, 李炯, 席永杰, 李福伟. 原子分散Ru-P-Ru催化剂的制备及其在多类加氢中的高效应用[J]. 催化学报, 2023, 45(2): 107-119.
[9]	沙峰, 唐珊, 汤驰洲, 冯振东, 王集杰, 李灿. ZnZrO_x固溶体催化剂表面羟基在CO₂加氢制甲醇中的作用[J]. 催化学报, 2023, 45(2): 162-173.
[10]	李航杰, 肖月华, 肖佳乐, 范凯, 李炳宽, 李晓龙, 王亮, 肖丰收. 镓改性的铜基疏水催化剂用于CO₂选择性加氢制二甲醚的研究[J]. 催化学报, 2023, 54(11): 178-187.
[11]	吴沛文, 邓畅, 刘锋, 朱昊男, 陈琳琳, 刘若禹, 朱文帅, 徐春明. 磁性可循环高熵金属氧化物催化剂用于活化氧气催化氧化脱硫[J]. 催化学报, 2023, 54(11): 238-249.
[12]	顾宇, 王磊, 徐柏庆, 施慧. 金属-水界面催化的分子机制: 加氢与氧化反应[J]. 催化学报, 2023, 54(11): 1-55.
[13]	高广, 赵泽伦, 王嘉, 席永杰, 孙鹏, 李福伟. PtReO_x/TiO₂金属-氧化物-载体相互作用增强手性羧酸选择性加氢[J]. 催化学报, 2022, 43(8): 2034-2044.
[14]	周紫璇, 高鹏. 多相催化CO₂加氢直接合成大宗化学品与液体燃料[J]. 催化学报, 2022, 43(8): 2045-2056.
[15]	王梦茹, 王奕, 牟效玲, 林荣和, 丁云杰. 1,3-丁二烯选择性加氢催化剂的设计策略以及构效关系[J]. 催化学报, 2022, 43(4): 1017-1041.