Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water

doi:10.1016/S1872-2067(12)60645-7

催化学报 ›› 2013, Vol. 34 ›› Issue (8): 1513-1518.DOI: 10.1016/S1872-2067(12)60645-7

Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water

Ezzat Rafiee, Sara Eavani, Maryam Khodayari

Faculty of Chemistry, Razi University, Kermanshah, 67149, Iran

收稿日期:2012-12-20 修回日期:2013-03-25 出版日期:2013-08-16 发布日期:2013-07-30
通讯作者: Ezzat Rafiee
基金资助:
This work was supported by Razi University Research Council and Iran National Science Foundation.

Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water

Ezzat Rafiee, Sara Eavani, Maryam Khodayari

Faculty of Chemistry, Razi University, Kermanshah, 67149, Iran

Received:2012-12-20 Revised:2013-03-25 Online:2013-08-16 Published:2013-07-30
Supported by:
This work was supported by Razi University Research Council and Iran National Science Foundation.

摘要/Abstract

摘要： 12-Tungstophosphoric acid supported on aerosil silica and silica-coated γ-Fe₂O₃ nanoparticles was prepared and characterized using transmission electron microscopy, scanning electron microscopy, and inductively coupled plasma atomic emission spectroscopy. The catalytic activity of the two prepared catalysts was compared in the synthesis of 1,8-dioxo-9,10- diaryldecahydroacridines in water. 12-Tungstophosphoric acid was highly dispersed on the silica-coated γ-Fe₂O₃ nanoparticles and showed higher activity and a higher reuse number compared with the acid supported on aerosil silica. The catalyst could be recovered simply by using an external magnetic field and could be reused several times without appreciable loss of its catalytic activity.

关键词: Core-shell particle, Magnetically recoverable catalyst, Heteropoly acid, Xanthene, Hydroacridine

Abstract: 12-Tungstophosphoric acid supported on aerosil silica and silica-coated γ-Fe₂O₃ nanoparticles was prepared and characterized using transmission electron microscopy, scanning electron microscopy, and inductively coupled plasma atomic emission spectroscopy. The catalytic activity of the two prepared catalysts was compared in the synthesis of 1,8-dioxo-9,10- diaryldecahydroacridines in water. 12-Tungstophosphoric acid was highly dispersed on the silica-coated γ-Fe₂O₃ nanoparticles and showed higher activity and a higher reuse number compared with the acid supported on aerosil silica. The catalyst could be recovered simply by using an external magnetic field and could be reused several times without appreciable loss of its catalytic activity.

Key words: Core-shell particle, Magnetically recoverable catalyst, Heteropoly acid, Xanthene, Hydroacridine

Ezzat Rafiee, Sara Eavani, Maryam Khodayari. Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water[J]. 催化学报, 2013, 34(8): 1513-1518.

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Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water

Magnetically recoverable, nanoscale-supported heteropoly acid catalyst for green synthesis of biologically active compounds in water

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