“嵌入模型”在γ-Al2O3负载单组分和双组分金属氧化物催化剂中的应用

doi:10.1016/S1872-2067(12)60708-6

催化学报 ›› 2013, Vol. 34 ›› Issue (11): 1975-1985.DOI: 10.1016/S1872-2067(12)60708-6

“嵌入模型”在γ-Al₂O₃负载单组分和双组分金属氧化物催化剂中的应用

姚小江^a, 高飞^b, 董林^a,b

a 南京大学化学化工学院, 介观化学教育部重点实验室, 江苏南京210093;
b 南京大学现代分析中心, 江苏省机动车尾气污染控制重点实验室, 江苏南京210093

收稿日期:2013-08-31 修回日期:2013-09-10 出版日期:2013-10-18 发布日期:2013-10-18
通讯作者: Lin Dong
基金资助:
国家自然科学基金(20873060,20973091);国家重点基础研究发展计划(973计划, 2010CB732300);江苏省科技支撑计划工业项目(SBE201100389).

The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review

Xiaojiang Yao^a, Fei Gao^b, Lin Dong^a,b

a School of Chemistry and Chemical Engineering, Key Laboratory of Mesoscopic Chemistry of MOE, Nanjing University, Nanjing 210093, Jiangsu, China;
b Center of Modern Analysis, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing 210093, Jiangsu, China

Received:2013-08-31 Revised:2013-09-10 Online:2013-10-18 Published:2013-10-18
Contact: Lin Dong
Supported by:
This work was supported by the National Natural Science Foundation of China (20873060, 20973091), the National Basic Research Program of China (973 Program, 2010CB732300), and Jiangsu Science and Technology Support Program (SBE201100389).

摘要/Abstract

摘要：

探讨负载型金属氧化物催化剂的表面组分与载体之间的相互作用, 有助于理解相关催化剂的催化作用本质. 近年来, 我们对单组分CuO以及双组分CuO-Mn₂O₃, CuO-CoO等金属氧化物在γ-Al₂O₃载体表面的分散行为和存在状态, 及其物理化学性质和催化性能(CO+O₂和NO+CO模型反应)进行了研究. 结果表明, 这些金属氧化物在γ-Al₂O₃载体表面的分散行为和所得负载型催化剂样品的一些物理化学性质及其催化性能均可参照“嵌入模型”来解释. 在此基础上, 我们讨论了这些样品的“组成-结构-性质”间的关系, 并针对表面负载双组分金属氧化物样品提出了表面协同氧空位参与的NO+CO反应机理.

关键词: γ-氧化铝载体, 负载型金属氧化物催化剂, 表面相互作用, 嵌入模型, 表面协同氧空位

Abstract:

The investigation of the interaction between the surface dispersed components and the supports is the key to understand the nature of catalytic reactions. A single metal oxide (CuO) and dual metal oxides (CuO-Mn₂O₃, CuO-CoO, etc.) were supported on γ-Al₂O₃ to produce model catalysts. The dispersion behavior of these metal oxides on the surface of γ-Al₂O₃ and some physicochemical properties were explained using the Incorporation Model. These properties were considered together with their catalytic performances in CO+O₂ and NO+CO model reactions to explore "composition-structure-property" relationships. A possible reaction mechanism involving surface synergetic oxygen vacancy on the supported dual metal oxide catalysts was proposed to approach the nature of NO reduction by CO.

Key words: γ-Alumina support, Supported metal oxide catalyst, Surface interaction, Incorporation Model, Surface synergetic oxygen vacancy

姚小江, 高飞, 董林. “嵌入模型”在γ-Al₂O₃负载单组分和双组分金属氧化物催化剂中的应用[J]. 催化学报, 2013, 34(11): 1975-1985.

Xiaojiang Yao, Fei Gao, Lin Dong. The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review[J]. Chinese Journal of Catalysis, 2013, 34(11): 1975-1985.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(12)60708-6

https://www.cjcatal.com/CN/Y2013/V34/I11/1975

参考文献

[1] Zhang Y H, Xiong G X, Sheng S S, Yang W S. Catal Today, 2000, 63: 517
[2] Zhang Y H, Xiong G X, Yang W S, Sheng S S. J Nat Gas Chem (张玉红, 熊国兴, 杨维慎, 盛世善. 天然气化学), 2000, 9:175
[3] Ma D, Mei D J, Li X, Gong M C, Chen Y Q. J Chin Rare Earth Soc (马迪, 梅大江, 李璇, 龚茂初, 陈耀强. 中国稀土学报), 2006, 24: 293
[4] Zhao X Y, Xu B L, Fan Y N. Chin J Inorg Chem (赵小燕, 许波连, 范以宁. 无机化学学报), 2008, 24: 1489
[5] Capannelli G, Carosini E, Monticelli O, Cavani F, Trifirò F. Catal Lett, 1996, 39: 241
[6] Selwood P W. Adv Catal, 1951, 3: 27
[7] Schuman S C, Shalit H. Catal Rev, 1970, 4: 245
[8] Schuit G C A, Gates B C. AICHE J, 1973, 19: 471
[9] Grange P, Delmon B. J Gess-Common Metals, 1974, 36: 353
[10] Massoth F E. Adv Catal, 1978, 27: 265
[11] Lipsch J M J G, Schuit G C A. J Catal, 1969, 15: 179
[12] Sonnemans J, Mars P. J Catal, 1973, 31: 209
[13] Lo Jacono M, Cimino A, Schuit G C A. Gazz Chim Ital, 1973, 103: 1281
[14] de Beer V H J, Schuit G C A. Stud Surf Sci Catal, 1976, 1: 343
[15] Hagenbach G, Courty Ph, Delmon B. J Catal, 1971, 23: 295
[16] Hagenbach G, Menguy P, Delmon B. Bull Soc Chim Belg, 1974, 83: 1
[17] Xie Y C, Tang Y Q. Adv Catal, 1990, 37: 1
[18] Chen Y, Dong L, Jin Y S, Xu B, Ji W J. Stud Surf Sci Catal, 1996, 101: 1293
[19] Chen Y, Zhang L F. Catal Lett, 1992, 12: 51
[20] Gates B C, Katzer J R, Schuit G C A. Chemistry of Catalytic Processes. New York: McGraw-Hill, 1979
[21] Beaufils J P, Barbaux Y. J Chim Phys Phys-Chim Biol, 1981, 78: 347
[22] Jimenéz-Gonzaléz A, Schmeisser D. Surf Sci, 1991, 250: 59
[23] Chen Y, Zhang L F. Catal Lett, 1992, 12: 51
[24] Wang X Y, Zhao B Y, Jiang D E, Xie Y C. Appl Catal A, 1999, 188: 201
[25] Chen Y. J Fudan Univ (Nat Sci) (陈懿. 复旦大学学报(自然科学版)), 2002, 41: 251
[26] Dong L. Chin J Catal (董林. 催化学报), 2009, 30: 1150
[27] Dong L, Yao X J, Chen Y. Chin J Catal (董林, 姚小江, 陈懿. 催化学报), 2013, 34: 851
[28] Dong L, Chen Y. Chin J Inorg Chem, 2000, 16: 250
[29] Xia W S, Wan H L, Chen Y. J Mol Catal A, 1999, 138: 185
[30] Wan H Q, Wang Z, Zhu J, Li X W, Liu B, Gao F, Dong L, Chen Y. Appl Catal B, 2008, 79: 254
[31] Yang F, Graciani J, Evans J, Liu P, Hrbek J, Sanz J F, Rodriguez J A. J Am Chem Soc, 2011, 133: 3444
[32] Over H, Kim Y D, Seitsonen A P, Wendt S, Lundgren E, Schmid M, Varga P, Morgante A, Ertl G. Science, 2000, 287:1474
[33] Esch F, Fabris S, Zhou L,Montini T, Africh C, Fornasiero P, Comelli G, Rosei R. Science, 2005, 309: 752
[34] Sun C Z, Zhu J, Lv Y Y, Qi L, Liu B, Gao F, Sun K Q, Dong L, Chen Y. Appl Catal B, 2011, 103: 206
[35] Yao X J, Yu Q, Ji Z Y, Lv Y Y, Cao Y, Tang C J, Gao F, Dong L, Chen Y. Appl Catal B, 2013, 130-131: 293
[36] Yao X J, Gao F, Yu Q, Qi L, Tang C J, Dong L, Chen Y. Catal Sci Technol, 2013, 3: 1355
[37] Pan X M, Ren K W, Wang X L, Lin R, Kou S Y, Ma J X. Acta Energiae Solaris Sin (潘相敏, 任克威, 王晓蕾, 林瑞, 寇素原, 马建新. 太阳能学报), 2010, 31: 958
[38] Chmielarz L, Kuśtrowski P, Zbroja M, Gil-Knap B, Datka J, Dziembaj R. Appl Catal B, 2004, 53: 47
[39] Wan H Q, Li D, Dai Y, Hu Y H, Liu B, Dong L. J Mol Catal A, 2010, 332: 32
[40] Faungnawakij K, Shimoda N, Fukunaga T, Kikuchi R, Eguchi K. Appl Catal A, 2008, 341: 139
[41] Lv Y Y, Zhang H L, Cao Y, Dong L H, Zhang L L, Yao K A, Gao F, Dong L, Chen Y. J Colloid Interface Sci, 2012, 372: 63
[42] Arnoldy P, Moulijn J A. J Catal, 1985, 93: 38
[43] Li D, Yu Q, Li S S, Wan H Q, Liu L J, Qi L, Liu B, Gao F, Dong L, Chen Y. Chem Eur J, 2011, 17: 5668
[44] Lv Y Y, Liu L C, Zhang H L, Yao X J, Gao F, Yao K A, Dong L, Chen Y. J Colloid Interface Sci, 2013, 390: 158

“嵌入模型”在γ-Al₂O₃负载单组分和双组分金属氧化物催化剂中的应用

The application of incorporation model in γ-Al₂O₃-supported single and dual metal oxide catalysts：A review

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 6

编辑推荐

Metrics

[1]	董林, 姚小江, 陈懿. 负载型铜基催化剂组分间相互作用及其催化性能[J]. 催化学报, 2013, 34(5): 851-864.
[2]	石川, 徐力, 朱爱民, 张玉卓, 区泽棠. 氧化铈稳定的 CuO 簇在 CO, C₃H₆ 和 NO 消除中的催化性能[J]. 催化学报, 2012, 33(9): 1455-1462.
[3]	董林. 负载型催化剂的表面相互作用及其在大气分子污染物 NO 和 CO 消除中的应用基础研究[J]. 催化学报, 2009, 30(11): 1150-1169.
[4]	朱海洋;沈明敏;刘田东;韦书婷;胡玉海;董林;陈懿. 氧化铜与CeO2-γ-Al2O3混合氧化物载体之间的表面相互作用[J]. 催化学报, 2002, 23(4): 325-328.
[5]	胡玉海;刘东;董林;陈懿. MoO3在Ga2O3上的分散研究[J]. 催化学报, 1999, 20(6): 649-653.
[6]	徐斌;董林;陈懿. 一些金属氧化物在TiO2(锐钛)载体上的分散-嵌入模型的应用[J]. 催化学报, 1997, 18(3): 183-184.