用于Suzuki-Miyaura反应的阴离子交换树脂负载钯催化剂

doi:10.1016/S1872-2067(12)60698-6

催化学报 ›› 2013, Vol. 34 ›› Issue (12): 2161-2166.DOI: 10.1016/S1872-2067(12)60698-6

用于Suzuki-Miyaura反应的阴离子交换树脂负载钯催化剂

张明明, 江曼曼, 梁长海

大连理工大学化工学院先进材料和催化工程实验室, 辽宁大连116024

收稿日期:2013-07-14 修回日期:2013-09-02 出版日期:2013-11-25 发布日期:2013-11-25
通讯作者: 梁长海
基金资助:
国家自然科学基金(21073023, 20906008);中央高校基本科研业务费专项资金(DUT12YQ03).

Palladium supported on an ion exchange resin for the Suzuki-Miyaura reaction

Mingming Zhang, Manman Jiang, Changhai Liang

Laboratory of Advanced Materials and Catalytic Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2013-07-14 Revised:2013-09-02 Online:2013-11-25 Published:2013-11-25
Contact: Changhai Liang
Supported by:
This work was supported by the National Natural Science Foundation of China (21073023, 20906008) and the Fundamental Research Funds for the Central Universities (DUT12YQ03).

摘要/Abstract

摘要：

以碱性阴离子交换树脂Amberlite IRA-900为载体，Pd(C₃H₅)(C₅H₅)为金属有机前体，采用金属有机气相沉积法在室温下制备了Pd@IRA-900多相催化材料. 紫外-可见光谱分析证明前体和树脂骨架之间的化学作用以及树脂本身的孔道结构使得Pd纳米粒子均匀分散在载体上. 透射电镜结果显示钯纳米粒子的平均尺寸为2.6 nm. 在较温和的条件下Pd@IRA-900对多种卤代芳烃和苯硼酸的Suzuki偶联都具有良好的催化活性, 并且催化剂重复使用5次之后依然具有很好的活性. 此外，对树脂载体进行碱性交换处理后可得到一种双功能催化材料Pd@IRA-900(OH)，该催化剂在不加入碱的条件下也可以催化碘苯和苯硼酸的Suzuki偶联反应.

关键词: 钯, 阴离子交换树脂, 金属有机气相沉积, Suzuki偶联, 双功能催化剂

Abstract:

A basic anion exchange resin, Amberlite IRA-900, was loaded with Pd(C₃H₅)(C₅H₅) by an easy metal-organic chemical vapor deposition (MOCVD) approach to give Pd@IRA-900 catalyst after reduction at room temperature. Ultraviolet-Visible spectroscopy results showed a red shift of the absorption peak of Pd²⁺ after the Pd precursor was loaded on the resin, indicating that a chemical reaction occurred between the precursor and the support. Pd nanoparticles with 2.6 nm of average size were well dispersed on the support. The Pd@IRA-900 catalyst showed high activity for different kinds of aryl halides in Suzuki-Miyaura coupling reactions under mild and aerobic conditions. Excellent recyclability of Pd@IRA-900 catalyst was also observed in the Suzuki-Miyaura coupling reaction of iodobenzene and phenylboronic acid. A bifunctional catalyst Pd@IRA-900(OH) was synthesized by pretreating the ion exchange resin support with NaOH before Pd loading, which successfully catalyzed the Suzuki-Miyaura reaction of iodobenzene and phenylboronic acid without base under aerobic conditions.

Key words: Palladium, Anion exchange resin, Metal-organic chemical vapor deposition, Suzuki-Miyaura coupling reaction, Bifunctional catalyst

张明明, 江曼曼, 梁长海. 用于Suzuki-Miyaura反应的阴离子交换树脂负载钯催化剂[J]. 催化学报, 2013, 34(12): 2161-2166.

Mingming Zhang, Manman Jiang, Changhai Liang. Palladium supported on an ion exchange resin for the Suzuki-Miyaura reaction[J]. Chinese Journal of Catalysis, 2013, 34(12): 2161-2166.

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用于Suzuki-Miyaura反应的阴离子交换树脂负载钯催化剂

Palladium supported on an ion exchange resin for the Suzuki-Miyaura reaction

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