An electrode with Ni(Ⅱ) loaded analcime zeolite catalyst for the electrooxidation of methanol

doi:10.1016/S1872-2067(14)60002-4

摘要/Abstract

摘要：

There is a high overvoltage in the oxidation of methanol in fuel cells, and so modified electrodes are used to decrease it. A modified electrode that used Ni(Ⅱ) loaded analcime zeolite to catalyze the electrooxidation of methanol in alkaline solution was proposed. Analcime zeolite was synthesized by hydrothermal synthesis, and Ni(Ⅱ) ions were incorporated into the analcime structure, which was then mixed with carbon paste to prepare modified electrode. The electrocatalytic oxidation of methanol on the surface of the modified electrode in alkaline solution was investigated by cyclic voltammetry and chronoamperometry. The effects of the scan rate of the potential, concentration of methanol, and amount of zeolite were investigated. The rate constant for the catalytic reaction of methanol was 6×10³ cm³ mol^-1 s^-1 from measurements using chronoamperometry. The proposed electrode significantly improved the electron transfer rate and decreased the overpotential for methanol oxidation.

关键词: Analcime zeolite, Modified electrode, Methanol, Cyclic voltammetry, Electrocatalytic oxidation

Abstract:

Key words: Analcime zeolite, Modified electrode, Methanol, Cyclic voltammetry, Electrocatalytic oxidation

Seyed Naser Azizi, Shahram Ghasemi, Neda Salek Gilani. An electrode with Ni(Ⅱ) loaded analcime zeolite catalyst for the electrooxidation of methanol[J]. 催化学报, 2014, 35(3): 383-390.

Seyed Naser Azizi, Shahram Ghasemi, Neda Salek Gilani. An electrode with Ni(Ⅱ) loaded analcime zeolite catalyst for the electrooxidation of methanol[J]. Chinese Journal of Catalysis, 2014, 35(3): 383-390.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(14)60002-4

https://www.cjcatal.com/CN/Y2014/V35/I3/383

参考文献

[1] Bindler F, Vages E, Laugel P. Food Addit Contam, 1988, 5: 343
[2] Baratz B, Quellette R, Park W, Stokes B. Mechanical, Thermal and Chemical Storage of Energy. Pennsylvania: Hutchinson Ross, 1981
[3] Lima A, Coutanceau C, Leger J M, Lamy C. J Appl Electrochem, 2001, 31: 379
[4] Abdel Rahim M A, Abdel Hameed R M, Khalil M W. J Power Sources, 2004, 134: 160
[5] Parsons R, Vander Noot T. J Electroanal Chem Interfacial Electrochem, 1988, 257: 9
[6] Morallón E, Cases F J, Vázquez J L, Aldaz A. Electrochim Acta, 1992, 37: 1883
[7] Biswas P C, Nodasaka Y, Enyo M. J Appl Electrochem, 1996, 26: 30
[8] Jiang Y X, Zou M Z, Yuan K, Xu H D. Electroanalysis, 1999, 11: 254
[9] Pushparaj H, Mani G, Muthiahpillai P, Velayutham M, Park Y K, Choi W C, Jang H T. Chin J Catal (催化学报), 2013, 34: 294
[10] Pepe F, De Gennaro B, Aprea P, Caputo D. Chem Eng J, 2013, 219: 37
[11] Mu X H, Wang D Z, Wang Y R, Lin M, Cheng S B, Shu X T. Chin J Catal (催化学报), 2013, 34: 69
[12] Zhou X Z, Liu Y, Meng X J, Shen B J, Xiao F S. Chin J Catal (催化学报), 2013, 34: 1504
[13] Deer W A, Howie R A, Zussman J. An Introduction to the Rock-Forming Minerals. Longman Scientic & Technical, Harlow, Essex, UK, 1992
[14] Taher M A, Mostafavi A, Mohammadi Mobarakeh S Z. J Anal Chem, 2007, 62: 1022
[15] Afzali D, Mostafavi A, Taher M A, Moradian A. Talanta, 2007, 71: 971
[16] Afzali D, Taher M A, Mostafavi Ali, Khayatzadeh Mahani M. J AOAC Int, 2005, 88: 842
[17] Shaw B R, Creasy K E, Lanczycki C J, Sargeant J A, Tirhado M. J Electrochem Soc, 1988, 135: 869
[18] Senaratne C, Zhang J, Baker M D, Bessel C A, Rolison D R. J Phys Chem, 1996, 100: 5849
[19] Bessel C A, Rolison D R. J Am Chem Soc, 1997, 119: 12673
[20] He Y P, Liu M, Dai C Y, Xu S T, Wei Y X, Liu Z M, Guo X W. Chin J Catal (催化学报), 2013, 34: 1148
[21] Petrucelli G C, Kawachi E Y, Kubota L T, Bertran C A. Anal Commun, 1996, 33: 227
[22] Afzali D, Mostafavi A, Taher M A, Rezaeipour E, Khayatzadeh Mahani M. Anal Sci, 2005, 21: 383
[23] Shi X Y, Liu F D, Shan W P, He H. Chin J Catal (催化学报), 2012, 33: 454
[24] Wang J Y, Xia H A, Ju X H, Fan F T, Feng Z C, Li C. Chin J Catal (催化学报), 2013, 34: 876
[25] Zhang X Y, Shen Q, He C, Ma C Y, Cheng J, Hao Z P. Catal Commun, 2012, 18: 151
[26] Raoof J B, Azizi N, Ojani R, Ghodrati S, Abrishamkar M, Chekin F. Int J Hydrogen Energy, 2011, 36: 13295
[27] Azizi S N, Ghasemi S, Chiani E. Electochim Acta, 2013, 88: 463
[28] Fakeeha A H, Khan W U, AL-Fatesh A S, Abasaeed A E. Chin J Catal (催化学报), 2013, 34: 764
[29] Ren L M, Zhang Y B, Zeng S J, Zhu L F, Sun Q, Zhang H Y, Yang C G, Meng X J, Yang X G, Xiao F S. Chin J Catal (催化学报), 2012, 33: 92
[30] Guzmán-Vargas A, Oliver-Tolentino M A, Lima E, Flores-Moreno J. Electrochim Acta, 2013, 108: 583
[31] Taran O P, Yashnik S A, Ayusheev A B, Piskun A S, Prihod'ko R V, Ismagilov Z R, Goncharuk V V, Parmon V N. Appl Catal B, 2013, 140-141: 506
[32] Azizi S N, Ehsani Tilami S. Microporous Mesoporous Mater, 2013, 167: 89
[33] Vertes G, Horanyi G, Nagi F. Acta Chim Acad Sci Hung, 1971, 67: 145
[34] Fleischmann M, Korinek K, Pletcher D. J Electroanal Chem Interfacial Electrochem, 1971, 31: 39
[35] Azizi S N, Ehsani Tilami S. Z Anorg Allg Chem, 2009, 635: 2660
[36] Harada K, Tanaka K, Nagashima K. Am Mineral, 1972, 57: 924
[37] Pechar F, Rykl D. Chem Pap, 1983, 37: 757
[38] Bessel C A, Rolison D R. J Phys Chem B, 1997, 101: 1148
[39] Laviron E. J Electroanal Chem Interfacial Electrochem, 1979, 101: 19
[40] Luo H X, Shi Z J, Li N Q, Gu Z N, Zhuang Q K. Anal Chem, 2001, 73: 915
[41] Bard A J, Faulkner L R. Bard A J. Electrochemical Methods, Fundamentals and Applications. New York: Wiley, 2001
[42] Taraszewska J, Roslonek G. J Electroanal Chem, 1994, 364: 209
[43] Zheng L, Song J F. J Solid State Electrochem, 2010, 14: 43
[44] Yi Q F, Zhang J J, Huang W, Liu X P. Catal Commun, 2007, 8: 1017
[45] Robertson P M. J Electroanal Chem, 1980, 111: 97
[46] Liu B, Zhang Y S, Yuan H T, Yang H B, Yang E D. Int J Hydrogen Energy, 2000, 25: 333
[47] Danaee I, Jafarian M, Forouzandeh F, Gobal F, Mahjani M G. Int J Hydrogen Energy, 2009, 34: 859
[48] Subbaiah T, Mallick S C, Mishra K G, Sanjay K, Das R P. J Power Sources, 2002, 112: 562
[49] Nozad Golikand A, Shahrokhian S, Asgari M, Ghannadi Maragheh M, Irannejad L, Khanchi A. J Power Sources, 2005, 144: 21
[50] Spinner N, Mustain W E. Electrochim Acta, 2011, 56: 5656
[51] Singh R N, Sharma T, Singh A, Anindita, Mishra D, Tiwari S K. Electrochim Acta, 2008, 53: 2322
[52] Raoof J B, Ojani R, Hosseini S R. J Power Sources, 2011, 196: 1855
[53] Galus Z. Fundamentals of Electrochemical Analysis. New York: Ellis Horwood, 1976
[54] Jafarian M, Haghighatbin M A, Gobal F, Mahjani M G, Rayati S. J Electroanal Chem, 2011, 663: 14
[55] Ojani R, Raoof J B, Fathi S. J Solid State Electrochem, 2009, 13: 927
[56] Ojani R, Raoof J B, Hosseini Zavvarmahalleh S R. Electrochim Acta, 2008, 53: 2402
[57] Danaee I, Jafarian M, Mirzapoor A, Gobal F, Mahjani M G. Electrochim Acta, 2010, 55: 209