一种嵌有双亚胺基吡啶配体的全共轭有机聚合物材料及其在C-C偶联反应中的应用

doi:10.1016/S1872-2067(14)60021-8

催化学报 ›› 2014, Vol. 35 ›› Issue (4): 540-545.DOI: 10.1016/S1872-2067(14)60021-8

一种嵌有双亚胺基吡啶配体的全共轭有机聚合物材料及其在C-C偶联反应中的应用

陈贵夫^a,b, 王峰^a, 王业红^a, 张晓辰^a, 秦洪强^a, 邹汉法^a, 徐杰^a

a 中国科学院大连化学物理研究所, 辽宁大连116023;
b 中国科学院大学, 北京100049

收稿日期:2013-11-01 修回日期:2014-01-06 出版日期:2014-03-20 发布日期:2014-03-21
通讯作者: 王峰，徐杰
基金资助:
国家自然科学基金（21073184，21273231）；中国科学院“百人计划”.

Imine-linked conjugated organic polymer bearing bis(imino)pyridine ligands and its catalytic application in C-C coupling reactions

Guifu Chen^a,b, Feng Wang^a, Yehong Wang^a, Xiaochen Zhang^a, Hongqiang Qin^a, Hanfa Zou^a, Jie Xu^a

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2013-11-01 Revised:2014-01-06 Online:2014-03-20 Published:2014-03-21
Supported by:
This work was supported by the National Natural Science Foundation of China (21073184, 21273231) and Hundred Talents Program of the Chinese Academy of Sciences.

摘要/Abstract

摘要：

报道了一种嵌有双亚胺基吡啶配体的全共轭有机聚合物材料. 该材料所具有的双亚胺基吡啶配体起到链接聚合物单元和络合金属中心的双重作用. 采用紫外可见光谱、红外光谱以及基质辅助激光解吸电离飞行时间质谱等对其结构进行了详细表征和确认. 由于具有全共轭结构，该材料的热稳定性达到440 ℃，并且在常规溶剂中较难溶解. 作为多相催化剂载体，可以络合Pd离子形成新的多相配位催化剂，在经典的Suzuki-Miyaura C-C偶联反应中转化率和选择性均达到99%.

关键词: 共轭有机聚合物, 双亚胺基吡啶配体, 催化, Suzuki-Miyaura反应

Abstract:

Covalent organic polymers are an emerging class of materials with potential applications in areas including molecular separation, gas sorption, and catalysis. A novel fully conjugated organic polymer bearing bis(imino)pyridine (COP-BIP) and its catalytic function are reported here. Unlike previous COP materials, the imine bonds of COP-BIP act as both linkages and complexation sites for the binding of metal ions. A clear structure is presented based on ultraviolet-visible, Fourier transform infrared, and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry characterization. The COP-BIP materials are thermally stable up to 440 ℃ and are insoluble in conventional solvents. In addition, COP-BIP complexes Pd ions on bis(imino)pyridine sites and forms a heterogeneous catalyst, which exhibits excellent catalytic activity in the Suzuki-Miyaura C-C coupling reaction.

Key words: Conjugated organic polymer material, Bis(imino)pyridine ligand, Catalysis, Suzuki-Miyaura C-C coupling

陈贵夫, 王峰, 王业红, 张晓辰, 秦洪强, 邹汉法, 徐杰. 一种嵌有双亚胺基吡啶配体的全共轭有机聚合物材料及其在C-C偶联反应中的应用[J]. 催化学报, 2014, 35(4): 540-545.

Guifu Chen, Feng Wang, Yehong Wang, Xiaochen Zhang, Hongqiang Qin, Hanfa Zou, Jie Xu. Imine-linked conjugated organic polymer bearing bis(imino)pyridine ligands and its catalytic application in C-C coupling reactions[J]. Chinese Journal of Catalysis, 2014, 35(4): 540-545.

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一种嵌有双亚胺基吡啶配体的全共轭有机聚合物材料及其在C-C偶联反应中的应用

Imine-linked conjugated organic polymer bearing bis(imino)pyridine ligands and its catalytic application in C-C coupling reactions

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