CO2 mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

doi:10.1016/S1872-2067(14)60018-8

催化学报 ›› 2014, Vol. 35 ›› Issue (4): 514-523.DOI: 10.1016/S1872-2067(14)60018-8

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

Tiago P. Braga^a, Regina C. R. Santos^a, Barbara M. C. Sales^a, Bruno R. da Silva^a, Antônio N. Pinheiro^b, Edson R. Leite^b, Antoninho Valentini^a

a Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Fortaleza, CE, CEP:60440-554, Brazil;
b Department of Chemistry, Federal University of São Carlos, São Carlos, SP, CEP:13560-905, Brazil

收稿日期:2013-09-19 修回日期:2013-12-30 出版日期:2014-03-20 发布日期:2014-03-21
通讯作者: Antoninho Valentini

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

Tiago P. Braga^a, Regina C. R. Santos^a, Barbara M. C. Sales^a, Bruno R. da Silva^a, Antônio N. Pinheiro^b, Edson R. Leite^b, Antoninho Valentini^a

a Department of Analytical Chemistry and Physical Chemistry, Federal University of Ceara, Fortaleza, CE, CEP:60440-554, Brazil;
b Department of Chemistry, Federal University of São Carlos, São Carlos, SP, CEP:13560-905, Brazil

Received:2013-09-19 Revised:2013-12-30 Online:2014-03-20 Published:2014-03-21
Contact: Antoninho Valentini

摘要/Abstract

摘要：

A factorial experimental design was combined with response surface methodology (RSM) to optimize the catalyzed CO₂ consumption by coke deposition and syngas production during the dry reforming of CH₄. The CH₄/CO₂ feed ratio and the reaction temperature were chosen as the variables, and the selected responses were CH₄ and CO₂conversion, the H₂/CO ratio, and coke deposition. The optimal reaction conditions were found to be a CH₄/CO₂ feed ratio of approximately 3 at 700 ℃, producing a large quantity of coke and realizing high CO₂ conversion. Furthermore, Raman results showed that the CH₄/CO₂ ratio and reaction temperature affect the system's response, particularly the characteristics of the coke produced, which indicates the formation of carbon nanotubes and amorphous carbon.

关键词: Factorial design, Carbon dioxide, Reforming, Methane, Carbon nanotube

Abstract:

Key words: Factorial design, Carbon dioxide, Reforming, Methane, Carbon nanotube

Tiago P. Braga, Regina C. R. Santos, Barbara M. C. Sales, Bruno R. da Silva, Antônio N. Pinheiro, Edson R. Leite, Antoninho Valentini. CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology[J]. 催化学报, 2014, 35(4): 514-523.

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CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

CO₂ mitigation by carbon nanotube formation during dry reforming of methane analyzed by factorial design combined with response surface methodology

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