催化学报

催化学报 ›› 2014, Vol. 35 ›› Issue (12): 1921-1926.DOI: 10.1016/S1872-2067(14)60224-2

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绿色离子液体中纳米钯催化剂的制备及其催化Heck-Mizoroki反应性能

王芙蓉, 唐思思, 于英豪, 王乐夫, 尹标林, 李雪辉   

  1. 华南理工大学化学与化工学院, 制浆造纸工程国家重点实验室, 广东广州510640
  • 收稿日期:2014-07-04 修回日期:2014-09-03 出版日期:2014-11-29 发布日期:2014-11-29
  • 通讯作者: 李雪辉
  • 基金资助:

    国家自然科学基金(21336002和21276094);高等学校博士学科点专项科研基金(20130172110043).

Preparation of palladium nanoparticle catalyst in ionic liquid and its catalytic properties for Heck-Mizoroki reaction

Furong Wang, Sisi Tang, Yinghao Yu, Lefu Wang, Biaolin Yin, Xuehui Li   

  1. School of Chemistry and Chemical Engineering, State Key Laboratory of Pulp and Paper Engineering of China, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2014-07-04 Revised:2014-09-03 Online:2014-11-29 Published:2014-11-29
  • Supported by:

    This work was supported by the National Natural Science Foundation of China (21336002, 21276094) and the Specialized Research Fund for the Doctoral Program of Higher Education (20130172110043).

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被引次数

5

摘要：

发展了在非卤素绿色离子液体1-丁基-3-甲基咪唑离子液体乳酸盐中制备纳米Pd催化剂的简便化学方法.透射电镜结果表明, Pd纳米粒子高度分散在[Bmim]Lac离子液体中, 平均粒径为2.2-3.1 nm.Pd纳米粒子的大小随着体系中[Bmim]Lac与Pd(OAc)2摩尔比减小和温度升高而增大.考察了离子液体稳定纳米Pd催化剂(PdNPs@[Bmim]Lac)催化Heck-Mizoroki反应性能, 并对反应条件进行了优化.结果表明, 所制备的离子液体稳定的纳米Pd催化剂在优化条件下可高效催化系列卤代芳烃与烯烃的Heck-Mizoroki反应, 且可循环使用6次.

关键词: 钯纳米粒子, Heck-Mizoroki反应, 1-丁基-3-甲基咪唑离子液体乳酸盐, 绿色离子液体

Abstract:

A palladium nanoparticle (PdNPs) catalyst was synthesized in halogen-free anion ionic liquid (1-buthyl-3-methylimidazolium lactate, [Bmim]Lac) by a simple chemical approach. The transmission electron microscopy analysis confirmed the presence of highly dispersed PdNPs in [Bmim]Lac with small average particle size distribution from 2.2 to 3.1 nm. The size of the PdNPs increases with decreasing molar ratio of [Bmim]Lac to Pd(OAc)2 and increasing temperature. The activity of PdNPs@[Bmim]Lac catalyst was tested by the Heck-Mizoroki reaction, and the conditions were optimized. The catalyst can efficiently catalyze couplings of various aryl bromides and iodides with different olefins, giving good yields of products under the optimal conditions and be recycled up to six consecutive times.

Key words: Palladium nanoparticles, Heck-Mizoroki reaction, 1-Buthyl-3-methylimidazolium lactate, Green ionic liquid