三价铑催化苯甲酰胺与醌的C-H活化偶联

doi:10.1016/S1872-2067(14)60245-X

催化学报 ›› 2015, Vol. 36 ›› Issue (1): 48-56.DOI: 10.1016/S1872-2067(14)60245-X

三价铑催化苯甲酰胺与醌的C-H活化偶联

戚自松, 李兴伟

中国科学院大连化学物理研究所, 辽宁大连116023

收稿日期:2014-09-25 修回日期:2014-11-10 出版日期:2014-12-31 发布日期:2014-12-31
通讯作者: 李兴伟
基金资助:
中国科学院大连化学物理研究所; 国家自然科学基金(21272231).

Rh(III)-catalyzed C-H activation of benzamides: Coupling with quinones

Zisong Qi, Xingwei Li

Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2014-09-25 Revised:2014-11-10 Online:2014-12-31 Published:2014-12-31
Supported by:
This work was supported by the Dalian Institute of Chemical Physics, Chinese Academy of Sciences and the National Natural Science Foundation of China (21272231).

摘要/Abstract

摘要：

三价铑在氧化条件下催化N-烷基苯甲酰胺与醌反应生成芳基醌. 在氧化还原中性条件下, 经过偶联和内酯化反应可以得到2-羟基-6H-苯并[c]吡喃-6-酮.

关键词: 三价铑, 碳氢活化, 苯甲酰胺, 芳基醌

Abstract:

Rh(III)-catalyzed C-H activation of N-(alkyl)benzamides in the oxidative coupling with various quinones. In addition, under redox-neutral conditions, 2-hydroxy-6H-benzo[c]chromen-6-ones were also obtained via a cascade of cross-coupling followed by lactonization.

Key words: Rhodium(III), C-H activation, Benzamides, Arylquinones

戚自松, 李兴伟. 三价铑催化苯甲酰胺与醌的C-H活化偶联[J]. 催化学报, 2015, 36(1): 48-56.

Zisong Qi, Xingwei Li. Rh(III)-catalyzed C-H activation of benzamides: Coupling with quinones[J]. Chinese Journal of Catalysis, 2015, 36(1): 48-56.

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三价铑催化苯甲酰胺与醌的C-H活化偶联

Rh(III)-catalyzed C-H activation of benzamides: Coupling with quinones

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