Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

doi:10.1016/S1872-2067(14)60259-X

催化学报 ›› 2015, Vol. 36 ›› Issue (3): 308-313.DOI: 10.1016/S1872-2067(14)60259-X

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

Jalal Albadi^a, Amir Alihosseinzadeh^b, Mehdi Mardani^a

a Behbahan Khatam Alanbia University of Technology, Behbahan, Iran;
b School of Chemical Engineering, University of Tehran, Tehran, Iran

收稿日期:2014-10-19 修回日期:2014-12-10 出版日期:2015-02-14 发布日期:2015-02-14
通讯作者: Jalal Albadi

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

Jalal Albadi^a, Amir Alihosseinzadeh^b, Mehdi Mardani^a

a Behbahan Khatam Alanbia University of Technology, Behbahan, Iran;
b School of Chemical Engineering, University of Tehran, Tehran, Iran

Received:2014-10-19 Revised:2014-12-10 Online:2015-02-14 Published:2015-02-14

摘要/Abstract

摘要：

A new method has been developed for the chemoselective acetylation of alcohols with acetic anhydride in the presence of phenols using a novel, recyclable CuO-ZnO nanocatalyst. The catalyst was synthesized using the co-precipitation method and characterized by N₂ adsorption-desorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and energy dispersion scanning analyses. Furthermore, this catalyst could be recycled up to six times without significant loss in its activity.

关键词: CuO-ZnO nanocatalyst, Alcohol, Chemoselective acetylation, Acetic anhydride

Abstract:

Key words: CuO-ZnO nanocatalyst, Alcohol, Chemoselective acetylation, Acetic anhydride

Jalal Albadi, Amir Alihosseinzadeh, Mehdi Mardani. Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO[J]. 催化学报, 2015, 36(3): 308-313.

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参考文献

[1] Ghosh R, Maiti S, Chakraborty A. Tetrahedron Lett, 2005, 46: 147
[2] Humphrey J M, Chamberlin A R. Chem Rev, 1997, 97: 2243
[3] Shirini F, Zolfigol M A, Abedini M. Monatsh Chem, 2009, 140: 1495
[4] Leclercq L, Suisse I, Agbossou-Niedercorn F. Eur J Org Chem, 2010: 2696
[5] Singh S J, Kale S R, Gawande M B, Velhinho A, Jayaram R V. Catal Commun, 2014, 44: 24
[6] Tamaddon F, Amrollahi M A, Shrafat L. Tetrahedron Lett, 2005, 46: 7841
[7] Lopez I, Bravo J L, Caraballo M, Barneto J L, Silvero G. Tetrahe-dron Lett, 2011, 52: 3339
[8] Moghadam M, Tangestaninejad S, Mirkhani V, Mohammadpoor- Baltork I, Gharaati S. C R Chim, 2011, 14: 1080
[9] Osiglio L, Romanelli G, Blanco M. J Mol Catal A, 2010, 316: 52
[10] Khazaie A, Rostami A, Mantashlo F. Chin Chem Lett, 2010, 21: 1430
[11] Farhadi S, Panahandehjoo S. Appl Catal A, 2010, 382: 293
[12] Rajabi F, Luque R. Catal Commun, 2014, 45: 129
[13] Ghorbani-Choghamarani A, Pourbaharan N. Chin J Catal (催化学报), 2012, 33: 1470
[14] Shirini F, Khaligh N G. Chin J Catal (催化学报), 2013, 34: 695
[15] Hajjami M, Ghorbani-Choghamarani A, Norouzi M. Chin J Catal (催化学报), 2012, 33: 1661
[16] Javaherian M, Sabzi H E. Ind J Chem, 2014, 53B: 631
[17] Astruc D. Nanoparticles and Catalysis. Weinheim: Wiley-VCH, 2008
[18] Samantaray S, Pradhan D K, Hota G, Mishra B G. Chem Eng J, 2012, 193: 1
[19] Li S, Zhang W, So M H, Che H M, Wang C M, Chen R. J Mol Catal A, 2012, 359: 81
[20] Pinaka A, Vougioukalakis G C, Dimotikali D, Psyharis V, Papado-poulos K. Synthesis, 2012, 44: 1057
[21] Sarvari M H, Sharghi H. J Org Chem, 2004, 69: 6953
[22] Yin S F, Xu B Q, Wang S J, Ng C F, Au C T. Catal Lett, 2004, 96: 113
[23] Drexler M T, Amiridis M D. Catal Lett, 2002, 79: 175
[24] Albadi J, Razeghi A, Abbaszadeh H, Mansournezhad A. J Nanoparticles, 2013, 2013: 546194
[25] Albadi J, Mansournezhad A, Abbaszadeh H. J Chin Chem Soc, 2013, 60: 1193
[26] Albadi J, Mansournezhad A, Derakhshandeh Z. Chin Chem Lett, 2013, 24: 821
[27] Albadi J, Mansournezhad A, Azarian Z. Iran J Org Chem, 2013, 5: 693
[28] Albadi J, Razeghi A, Mansournezhad A, Azarian Z. J Nanostructure Chem, 2013, 3: 85
[29] Albadi J, Shiran J A, Mansournezhad A. J Chem Sci, 2014, 126: 147
[30] Albadi J, Razeghi A, Alihoseinzadeh A. Catal Commun, 2014, 49: 1
[31] Sheldon R A. Catal Today, 1987, 1: 351

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

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