双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛

doi:10.1016/S1872-2067(14)60287-4

催化学报 ›› 2015, Vol. 36 ›› Issue (6): 820-828.DOI: 10.1016/S1872-2067(14)60287-4

双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛

李良, 丁姜宏, 蒋金刚, 朱治国, 吴鹏

华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室, 上海200062

收稿日期:2014-11-28 修回日期:2015-01-13 出版日期:2015-05-21 发布日期:2015-05-21
通讯作者: 吴鹏,电话/传真: (021)62232292; 电子信箱: pwu@chem.ecnu.edu.cn
基金资助:
国家自然科学基金(21373089, U1162102); 教育部博士学科点专项科研基金(2012007613000); 国家科技支撑计划(2012BAE05B02); 上海市重点学科建设项目资助(B409).

One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

Liang Li, Jianghong Ding, Jin-Gang Jiang, Zhiguo Zhu, Peng Wu

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China

Received:2014-11-28 Revised:2015-01-13 Online:2015-05-21 Published:2015-05-21
Supported by:
This work was supported by the National Natural Science Foundation of China (21373089, U1162102), Ph.D. Programs Foundation of Ministry of Education (2012007613000), the National Key Technology R&D Program (2012BAE05B02), and the Shanghai Leading Academic Discipline Project (B409).

摘要/Abstract

摘要：

以部分脱铝的Beta分子筛为母体, 采用同晶置换法将Sn植入骨架制备双功能[Sn,Al]-Beta分子筛, 并应用于葡萄糖一步催化生成5-羟甲基糠醛(5-HMF)反应中. 样品中Sn与Al的含量通过酸洗的浓度和酸洗的时间以及SnCl₄处理的时间来控制. 由于骨架中有与Al相关为B酸位, 和Sn相关的L酸位, [Sn,Al]-Beta可作为一种双功能的固体酸催化剂. 优化了[Sn,Al]-Beta催化葡萄糖一步催化生成5-HMF的反应参数, 在最优Sn/Al比条件下, 葡萄糖转化率为60.0%, 5-HMF选择性为62.1%.

关键词: [锡,铝]-Beta, 醛糖酮糖异构, 双功能催化, 羟甲基糠醛, 生物质, 同晶置换

Abstract:

The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl₄ vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.

Key words: [Sn,Al]-Beta, Aldose-Ketose Isomerization, Bifunctional Catalysis, Hydroxymethyl furfural, Biomass, Isomorphous substitution

李良, 丁姜宏, 蒋金刚, 朱治国, 吴鹏. 双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛[J]. 催化学报, 2015, 36(6): 820-828.

Liang Li, Jianghong Ding, Jin-Gang Jiang, Zhiguo Zhu, Peng Wu. One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts[J]. Chinese Journal of Catalysis, 2015, 36(6): 820-828.

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参考文献

[1] Huber G W, Iborra S, Corma A. Chem Rev, 2006, 106: 4044
[2] Kunkes E L, Simonetti D A, West R M, Serrano-Ruiz J C, Gärtner C A, Dumesic J A. Science, 2008, 322: 417
[3] Bond J Q, Alonso D M, Wang D, West R M, Dumesic J A. Science, 2010, 327: 1110
[4] Vispute T P, Zhang H Y, Sanna A, Xiao R, Huber G W. Science, 2010, 330: 1222
[5] Savage N. Nature, 2011, 474: S9
[6] Chheda J N, Huber G W, Dumesic J A. Angew Chem Int Ed, 2007, 46: 7164
[7] Climent M J, Corma A, Iborra S. Green Chem, 2011, 13: 520
[8] Liu M, Jia S Y, Li C Z, Zhang A F, Song C S, Guo X W. Chin J catal (刘民, 贾松岩, 李常增, 张安峰, 宋春山, 郭新闻), 2014, 35: 723
[9] Roman-Leshkov Y, Chheda J N, Dumesic J A. Science, 2006, 312: 1933
[10] Lin Y C, Huber G W. Energy Environ Sci, 2009, 2: 68
[11] Perego C, Bosetti A. Micropor Mesopor Mater, 2011, 144: 28
[12] Takagaki A, Ohara M, Nishimura S, Ebitani K. Chem Commun, 2009: 6276
[13] Zhao H B, Holladay J E, Brown H, Zhang Z C. Science, 2007, 316: 1597
[14] Huang R L, Qi W, Su R X, He Z M. Chem Commun, 2010, 46: 1115
[15] Otomo R, Yokoi T, Kondo J N, Tatsumi T. App Catal A, 2014, 470: 318
[16] Corma A, Nemeth L T, Renz M, Valencia S. Nature, 2001, 412: 423
[17] Corma A, Fornés V, Iborra S, Mifsud M, Renz M. J Catal, 2004, 221: 67
[18] Li P, Liu G Q, Wu H H, Liu Y M, Jiang J G, Wu P. J Phys Chem C, 2011, 115: 3663
[19] Zhu Y, Chuah G, Jaenicke S. J Catal, 2004, 227: 1
[20] Corma A, Domine M E, Nemeth L, Valencia S. J Am Chem Soc, 2002, 124: 3194
[21] Nikolla E, Roman-Leshkov Y, Moliner M, Davis M E. ACS Catal, 2011, 1: 408
[22] Velarde A M, Bartl P, Nießen T E W, Hoelderich W F. J Mol Catal A, 2000, 157: 225
[23] Hammond C, Conrad S, Hermans I. Angew Chem Int Ed, 2012, 51, 11736
[24] Dijkmans J, Gabriëls D, Dusselier M, de Clippel F, Vanelderen P, Houthoofd K, Malfilet A, Pontikes Y, Sels B F. Green Chem, 2013, 15, 2777
[25] Mal N K, Ramaswamy V, Ganapathy S, Ramaswamy A V. Appl Catal A, 1995, 125: 233
[26] Renz M, Blasco T, Corma A, Fornés V, Jensen R, Nemeth L. Chem Eur J, 2002, 8: 4708
[27] Zecchina A, Spoto G, Bordiga S, Ferrero A, Petrini G, Leofanti G, Padovan M. Stud Surf Sci Catal, 1991, 69: 251
[28] Wu P, Komatsu T, Yashima T. J Phys Chem, 1995, 99: 10923
[29] Wu P, Komatsu T, Yashima T. J Phys Chem, 1996, 100: 10316
[30] Buzzoni B, Bordiga S, Ricchiardi G, Lamberti C, Zecchina A, Bellussi G. Langmuir, 1996, 12: 930
[31] Pazé C, Bordiga S, Lamberti C, Salvalaggio M, Zecchina A, Bellussi G. J Phys Chem B, 1997, 101: 4740
[32] Bonino F, Damin A, Bordiga S, Lamberti C, Zecchina A. Langmuir, 2003, 19: 2155
[33] Ngamcharussrivichai C, Wu P, Tatsumi T. J Catal, 2005, 235: 139
[34] Wang Y, Liu Y, Li X, Wu H, He M, Wu P. J Catal, 2009, 226: 258
[35] Szmant H H, Chundury D D. J Chem Technol Biotechnol, 1981, 31: 135
[36] Despax S, Estrine B, Hoffmann N, Le Bras J, Marinkovic S, Muzart J. Catal Commun, 2013, 39: 35

双功能[Sn,Al]-Beta分子筛一步催化葡萄糖生成5-羟甲基糠醛

One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

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