中孔氧化硅负载铬催化剂上苯高选择性生成苯酚:响应曲面分析法用于反应条件优化

doi:10.1016/S1872-2067(15)60898-1

催化学报 ›› 2015, Vol. 36 ›› Issue (11): 2020-2029.DOI: 10.1016/S1872-2067(15)60898-1

中孔氧化硅负载铬催化剂上苯高选择性生成苯酚:响应曲面分析法用于反应条件优化

Milad Jourshabani^a, Alireza Badiei^a,b, Negar Lashgari^a, Ghodsi Mohammadi Ziarani^c

a 德黑兰大学理学院化学学院, 德黑兰, 伊朗;
b 德黑兰大学纳米科学和纳米技术研究中心, 纳米生物医药杰出研究中心, 德黑兰, 伊朗;
c Alzahra大学理学院化学系, 德黑兰, 伊朗

收稿日期:2015-04-23 修回日期:2015-05-18 出版日期:2015-11-02 发布日期:2015-11-02
通讯作者: Alireza Badiei. 电话: +98-216-1112614; 传真: +98-216-6405141; 电子信箱: abadiei@khayam.ut.ac.ir

Highly selective production of phenol from benzene over mesoporous silica-supported chromium catalyst: Role of response surface methodology in optimization of operating variables

Milad Jourshabani^a, Alireza Badiei^a,b, Negar Lashgari^a, Ghodsi Mohammadi Ziarani^c

a School of Chemistry, College of Science, University of Tehran, Tehran, Iran;
b Nanobiomedicine Center of Excellence, Nanoscience and Nanotechnology Research Center, University of Tehran, Tehran, Iran;
c Department of Chemistry, Faculty of Science, Alzahra University, Tehran, Iran

Received:2015-04-23 Revised:2015-05-18 Online:2015-11-02 Published:2015-11-02

摘要/Abstract

摘要：

以硝酸铬为前驱体, 中孔氧化硅SBA-16为载体, 采用简单浸渍法制备了Cr/SBA-16催化剂, 并采用广角和小角X射线衍射、N₂吸附-脱附、透射电镜和紫外-可见光谱等技术对其进行了表征. 同时将该催化剂用于以H₂O₂为氧化剂的苯直接羟基化制苯酚反应以考察其催化性能. 将中心组合设计与响应曲面分析法(RSM)相结合, 对影响反应性能的操作变量如反应温度、反应时间及H₂O₂和催化剂用量进行了优化. 结果表明, 独立变量和苯酚产率之间的关系可用二阶多项式模型来表达, 其相关系数(R²)高达0.985, 表明用RSM预测的数值与实验值吻合较好. 得到的苯酚选择性较高时的操作条件为: 反应温度324 K, 反应时间8 h, H₂O₂和催化剂用量分别为3.28 mL和0.09 g. 由此可见, 将RSM法用于苯羟基化制苯酚反应条件优化是可靠的.

关键词: 中孔氧化硅, 铬/SBA-16催化剂, 苯羟基化, 苯酚, 响应曲面分析法

Abstract:

A Cr/SBA-16 catalyst was prepared using Cr(NO₃)₃ as a precursor and mesoporous silica SBA-16 as a support via a simple impregnation method. The catalyst was characterized using wide-angle X-ray diffraction (XRD), low-angle XRD, N₂ adsorption-desorption, transmission electron microscopy, and ultraviolet-visible spectroscopy. The catalyst activity was investigated in the direct hydroxylation of benzene to phenol using H₂O₂ as the oxidant. Various operating variables, namely reaction temperature, reaction time, amount of H₂O₂, and catalyst dosage, were optimized using central composite design combined with response surface methodology (RSM). The results showed that the correlation between the independent parameters and phenol yield was represented by a second-order polynomial model. The high correlation coefficient (R²), i.e., 0.985, showed that the data predicted using RSM were in good agreement with the experimental results. The optimization results also showed that high selectivity for phenol was achieved at the optimized values of the operating variables: reaction temperature 324 K, reaction time 8 h, H₂O₂ content 3.28 mL, and catalyst dosage 0.09 g. This study showed that RSM was a reliable method for optimizing process variables for benzene hydroxylation to phenol.

Key words: Mesoporous silica, Chromium/SBA-16 catalyst, Benzene hydroxylation, Phenol, Response surface methodology

Milad Jourshabani, Alireza Badiei, Negar Lashgari, Ghodsi Mohammadi Ziarani. 中孔氧化硅负载铬催化剂上苯高选择性生成苯酚:响应曲面分析法用于反应条件优化[J]. 催化学报, 2015, 36(11): 2020-2029.

Milad Jourshabani, Alireza Badiei, Negar Lashgari, Ghodsi Mohammadi Ziarani. Highly selective production of phenol from benzene over mesoporous silica-supported chromium catalyst: Role of response surface methodology in optimization of operating variables[J]. Chinese Journal of Catalysis, 2015, 36(11): 2020-2029.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(15)60898-1

https://www.cjcatal.com/CN/Y2015/V36/I11/2020

参考文献

[1] Zhang J, Tang Y, Li G Y, Hu C W. Appl Catal A, 2005, 278: 251
[2] Stöckmann M, Konietzni F, Notheis J U, Voss J, Keune W, Maier W F. Appl Catal A, 2001, 208: 343
[3] Kubacka A, Wang Z L, Sulikowski B, Cortés Corberán V. J Catal, 2007, 250: 184
[4] Pirutko L V, Uriarte A K, Chernyavsky V S, Kharitonov A S, Panov G I. Microporous Mesoporous Mater, 2001, 48: 345
[5] Panov G I, Sheveleva G A, Kharitonov A S, Romannikov V N, Vostrikova L A. Appl Catal A, 1992, 82: 31
[6] Okamura J, Nishiyama S, Tsuruya S, Masai M. J Mol Catal A, 1998, 135: 133
[7] Lee C W, Lee W J, Park Y K, Park S-E. Catal Today, 2000, 61: 137
[8] Lemke K, Ehrich H, Lohse U, Berndt H, Jähnisch K. Appl Catal A, 2003, 243: 41
[9] Jiang T, Wang W T, Han B X. New J Chem, 2013, 37: 1654
[10] Song S Q, Jiang S J, Rao R C, Yang H X, Zhang A M. Appl Catal A, 2011, 401: 215
[11] Arab P, Badiei A, Koolivand A, Mohammadi Ziarani G. Chin J Catal (催化学报), 2011, 32: 258
[12] Xu J, Jiang Q, Chen T, Wu F, Li Y-X. Catal Sci Technol, 2015, 5: 1504
[13] Parida K M, Rath D. Appl Catal A, 2007, 321: 101
[14] Nemati Kharat A, Moosavikia S, Tamaddoni Jahromi B, Badiei A. J Mol Catal A, 2011, 348: 14
[15] Lee C-H, Lin T-S, Mou C-Y. J Phys Chem B, 2003, 107: 2543
[16] Taguchi A, Schüth F. Microporous Mesoporous Mater, 2005, 77: 1
[17] Weitkamp J, Hunger M, Rymsa U. Microporous Mesoporous Mater, 2001, 48: 255
[18] Corma A. Chem Rev, 1997, 97: 2373
[19] Rivera-Muñoz E M, Huirache-Acuña R. Int J Mol Sci, 2010, 11: 3069
[20] Zhu Y J, Dong Y L, Zhao L N, Yuan F L. J Mol Catal A, 2010, 315: 205
[21] Dong Y L, Zhan X L, Niu X Y, Li J, Yuan F L, Zhu Y J, Fu H G. Microporous Mesoporous Mater, 2014, 185: 97
[22] Spinacé E V, Schuchardt U, Cardoso D. Appl Catal A, 1999, 185: L193
[23] Yuvaraj S, Palanichamy M, Krishnasamy V. Chem Commun, 1996: 2707
[24] Tagawa T, Uchida H, Goto S. React Kinet Catal Lett, 1991, 44: 25
[25] Zhang W Z, Wang J L, Tanev P T, Pinnavaia T J. Chem Commun, 1996: 979
[26] Li Y, Wang Z, Chen R Z, Wang Y, Xing W H, Wang J, Huang J. Catal Commun, 2014, 55: 34
[27] Leng Y, Liu J, Jiang P P, Wang J. Chem Eng J, 2014, 239: 1
[28] Xu D, Jia L H, Guo X F. Chin J Catal (徐丹, 贾丽华, 郭祥峰. 催化学报), 2013, 34: 341
[29] Ding G D, Wang W T, Jiang T, Han B X, Fan H L, Yang G Y. ChemCatChem, 2013, 5: 192
[30] Zhao P P, Leng Y, Wang J. Chem Eng J, 2012, 204-206: 72
[31] Tang Y, Zhang J. J Serbian Chem Soc, 2006, 71: 111
[32] Olutoye M A, Hameed B H. Appl Catal A, 2009, 371: 191
[33] Lazi? ? R. Design and Analysis of Experiments. Section 2.3. New York: Wiley Online Library, 2004
[34] Mason R L, Gunst R F, Hess J L. Statistical Design and Analysis of Experiments: With Applications to Engineering and Science. 2nd Ed. New York: John Wiley & Sons, 2003
[35] Kosuge K, Kikukawa N, Takemori M. Chem Mater, 2004, 16: 4181
[36] Hosseinpour V, Kazemeini M, Mohammadrezaee A. Appl Catal A, 2011, 394: 166
[37] Bobet J-L, Desmoulins-Krawiec S, Grigorova E, Cansell F, Chevalier B. J Alloys Compd, 2003, 351: 217
[38] Weckhuysen B M, Wachs I E, Schoonheydt R A. Chem Rev, 1996, 96: 3327
[39] Jian M, Zhu L F, Wang J Y, Zhang J, Li G Y, Hu C W. J Mol Catal A, 2006, 253: 1
[40] Dapurkar S E, Sakthivel A, Selvam P. J Mol Catal A, 2004, 223: 241
[41] Neumann R, Levin-Elad M. Appl Catal A, 1995, 122: 85
[42] Huybrechts D R C, Buskens P L, Jacobs P A. J Mol Catal, 1992, 71: 129
[43] Iwamoto M, Hirata J, Matsukami K, Kagawa S. J Phys Chem, 1983, 87: 903

中孔氧化硅负载铬催化剂上苯高选择性生成苯酚:响应曲面分析法用于反应条件优化

Highly selective production of phenol from benzene over mesoporous silica-supported chromium catalyst: Role of response surface methodology in optimization of operating variables

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Mengistu Tulu Gonfa, 申升, 陈浪, 胡彪, 周威, 白张君, 区泽堂, 尹双凤. 光催化苯制苯酚的研究进展[J]. 催化学报, 2023, 49(6): 16-41.
[2]	夏思源, 李奇远, 张仕楠, 许冬, 林秀, 孙露菡, 许景三, 陈接胜, 李国栋, 李新昊. Pd纳米立方体异质结尺寸依赖的电子界面效应对苯酚加氢反应的促进作用[J]. 催化学报, 2023, 49(6): 180-187.
[3]	刘江永, 李金兴, 叶荣飞, 晏晓东, 王理霞, 菅盘铭. 生物质基双功能氮掺杂多孔碳在对硝基苯酚还原和苯乙烯氧化中的应用[J]. 催化学报, 2020, 41(8): 1217-1229.
[4]	谢顺吉, 王野. 催化选择氧化领域近年研究进展、挑战与展望[J]. 催化学报, 2019, 40(s1): 129-142.
[5]	陈宇卓, 孔祥千, 毛善俊, 王哲, 巩玉同, 王勇. 碱性钠添加剂在苯酚选择性加氢中的作用[J]. 催化学报, 2019, 40(10): 1516-1524.
[6]	张佳光, Loris Lombardoa, Gökalp Gözaydın, Paul J. Dyson, 颜宁. 催化一步转化木质素单体为苯酚:建立木质素到高附加值化学品的通道[J]. 催化学报, 2018, 39(9): 1445-1452.
[7]	薛冰, 陈晔, 洪颖, 马丁阳, 许杰, 李永昕. 简便方法合成含铁石墨相氮化碳材料及其催化苯直接羟基化制苯酚[J]. 催化学报, 2018, 39(7): 1263-1271.
[8]	赵萍萍, 张云云, 李道宽, 崔洪友, 张丽鹏. 基于多金属氧酸盐的介孔离子催化剂催化苯一步氧化制苯酚[J]. 催化学报, 2018, 39(2): 334-341.
[9]	田坚, 刘仁月, 刘珍, 余长林, 刘敏超. 复合微量NCQDs对提高Ag₂CO₃半导体降解苯酚的光催化性能研究[J]. 催化学报, 2017, 38(12): 1999-2008.
[10]	丁望, 刘素琴, 何震. 一步法合成g-C₃N₄纳米片用作苯酚可见光降解高效催化剂[J]. 催化学报, 2017, 38(10): 1711-1718.
[11]	曾振兴, 李可心, 魏凯, 戴玉华, 颜流水, 郭会琴, 罗旭彪. 原位光还原法制备高分散铂沉积多孔氮化碳复合材料及其降解水中4-氟苯酚的高效可见光光催化活性[J]. 催化学报, 2017, 38(1): 29-38.
[12]	孟婉婉, 胡瑞生, 杨军, 杜燕飞, 李景佳, 王宏叶. La掺杂BiFeO₃对苯酚光催化降解性能的影响[J]. 催化学报, 2016, 37(8): 1283-1292.
[13]	李一冰, Ali Jawad, Aimal Khan, 卢小艳, 陈朱琦, 刘卫东, 尹国川. 负载型铜钴氧化物协同催化H₂O₂/HCO₃^-降解苯酚[J]. 催化学报, 2016, 37(6): 963-970.
[14]	党丹, 王泽, 林伟刚, 宋文立. 氧化铝负载催化剂作用下以甲醇为烷基化试剂的苯酚气相转化制备苯甲醚[J]. 催化学报, 2016, 37(5): 720-726.
[15]	Eda Sinirtas, Meltem Isleyen, Gulin Selda Pozan Soylu. V₂O₅-TiO₂催化剂光催化降解2,4-二氯苯酚:催化剂载体和表面活性剂的影响[J]. 催化学报, 2016, 37(4): 607-615.