TiO2光催化降解胸腺嘧啶的动力学和机理

doi:10.1016/S1872-2067(15)60967-6

催化学报 ›› 2015, Vol. 36 ›› Issue (11): 1818-1824.DOI: 10.1016/S1872-2067(15)60967-6

TiO₂光催化降解胸腺嘧啶的动力学和机理

L. Elsellami^a,b,c, N. Hafidhi^b, F. Dappozze^a, A. Houas^b, C. Guillard^a

a 里昂第一大学催化与环境研究所(IRCELYON), 法国国家科学研究中心混合研究单位(CNRS UMR)5256, 里昂, 法国;
b 加贝斯大学环境与过程催化材料研究单位, 突尼斯;
c 加贝斯大学加贝斯高级应用科学与技术研究所, 突尼斯

收稿日期:2015-08-08 修回日期:2015-08-24 出版日期:2015-11-02 发布日期:2015-11-02
通讯作者: L. Elsellami. 电话: +216-75-392600; 传真: +216-75-392241; 电子信箱: elsellami_leila@yahoo.fr

Kinetics and mechanism of thymine degradation by TiO₂ photocatalysis

L. Elsellami^a,b,c, N. Hafidhi^b, F. Dappozze^a, A. Houas^b, C. Guillard^a

a IRCELYON, CNRS UMR 5256/Université Lyon 1, 2 Avenue Albert Einstein, 69626 Villeurbanne Cedex, Lyon, France;
b Research Unit Catalysis and Materials for the Environment and Processes URCMEP (UR11ES85), University of Gabes, University Campus Hatem Bettahar-Erriadh-6072 Gabes, Tunisia;
c Higher Institute of Applied Sciences and Technology of Gabes, University of Gabes, Tunisia

Received:2015-08-08 Revised:2015-08-24 Online:2015-11-02 Published:2015-11-02
Contact: L. Elsellami. 电话: +216-75-392600; 传真: +216-75-392241; 电子信箱: elsellami_leila@yahoo.fr
Supported by:
This work was supported by The French Institute of Tunisia and University of Gabes, Tunisia (Scientific Stay High Level 2015).

摘要/Abstract

摘要：

考察了用于降解来自嘧啶家族的一种核酸—胸腺嘧啶(C₅H₆N₂O₂)的高级氧化过程. 结果发现, 在光催化剂TiO₂作用下, 胸腺嘧啶的光降解进行得很快, 且在紫外光照射和水溶液中时更为明显. 研究了胸腺嘧啶在TiO₂催化剂上的吸附、降解动力学、以及pH值对光催化降解胸腺嘧啶性能的影响. 另外, 考察了胸腺嘧啶降解产物的矿化; 比较和讨论了在光催化过程中胸腺嘧啶的消失和矿化速率. 同时还研究了氮的矿化, 确立了中间产物的识别方法. 最后, 采用电子密度计算提出了在紫外光照射下TiO₂催化剂上胸腺嘧啶降解的可能化学途径.

关键词: 二氧化钛, 光催化, 胸腺嘧啶, 光矿化, 前沿电子密度

Abstract:

The advanced oxidation processes were examined toward the degradation of thymine (C₅H₆N₂O₂), a type of nucleic acid from the pyrimidine family. As observed, the photodegradation of thymine over TiO₂ photocatalyst was rapid and significant in aqueous solution under UV irradiation. Different parameters were studied, including the adsorption of thymine onto TiO₂ photocatalyst, the kinetics of degradation, and the effect of pH on the photocatalytic properties of thymine degradation. Additionally, the mineralization of the products obtained upon thymine photodegradation was studied. The disappearance and mineralization rates of thymine during the photocatalytic process were also compared and discussed. The mineralization of nitrogen was also investigated, and the identification of the intermediate products was established. Finally, electronic density calculations were used to propose possible chemical pathways for the photodegradation of thymine over TiO₂ photocatalyst under UV irradiation.

Key words: Titania, Photocatalysis, Thymine, Photomineralization, Frontier electron density

L. Elsellami, N. Hafidhi, F. Dappozze, A. Houas, C. Guillard. TiO₂光催化降解胸腺嘧啶的动力学和机理[J]. 催化学报, 2015, 36(11): 1818-1824.

L. Elsellami, N. Hafidhi, F. Dappozze, A. Houas, C. Guillard. Kinetics and mechanism of thymine degradation by TiO₂ photocatalysis[J]. Chinese Journal of Catalysis, 2015, 36(11): 1818-1824.

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参考文献

[1] Cadet J, Douki T, Gasparutto D, Ravanat J L. Mutat Res, 2003, 531: 5
[2] Perrier S, Hau J, Gasparutto D, Cadet J, Favier A, Ravanat J L. J Am Chem Soc, 2006, 128: 5703
[3] Steenkeste K, Guiot E, Tfibel F, Pernot P, Mérola F, Georges P, Fontaine-Aupart M P. Chem Phys, 2002, 275: 93
[4] Steenkeste K, Enescu M, Tfibel F, Perrée-Fauvet M, Fontaine- Aupart M P. J Phys Chem B, 2004, 108: 12215
[5] Lee H S, Hur T, Kim S, Kim J H, Lee H I. Catal Today, 2003, 84: 173
[6] Liu J Q, de la Garza L, Zhang L G, Dimitrijevic N M, Zuo X B, Tiede D M, Rajh T. Chem Phys, 2007, 339: 154
[7] Horikoshi S, Hidaka H. J Photochem Photobiol A, 2001, 141: 201
[8] Dhananjeyan M R, Kandavelu V, Renganathan R. J Mol Catal A, 2000, 151: 217
[9] Vaz J L L, Boussaoud A, Ichouet Y A, Petit-Ramel M. Analusis, 1998, 26: 83
[10] Plantard G, Janin T, Goetz V, Brosillon S. Appl Catal B, 2012, 115-116: 38
[11] Hou H B, Wang X X, Chen C C, Johnson D M, Fang Y F, Huang Y P. Catal Commun, 2014, 48: 65
[12] Jaussaud C, Païssé O, Faure R. J Photochem Photobiol A, 2000, 130: 157
[13] Horikoshi S, Serpone N, Yoshizawa S, Knowland J, Hidaka H. J Photochem Photobiol A, 1999, 120: 63
[14] Li G Y, Liu X L, An T C, Yang H, Zhang S Q, Zhao H J. Catal Today, 2015, 242: 363
[15] Singh H K, Saquib M, Haque M M, Muneer M. J Hazard Mater, 2007, 142: 425
[16] El Madani M, Guillard C, Perol N, Chovelon J M, El Azzouzi M, Zrineh A, Herrmann J M. Appl Catal B, 2006, 65: 70
[17] Boehm H P, Herrmann M. Z Anorg Allg Chem, 1967, 352: 156
[18] Elsellami L, Vocanson F, Dappozze F, Baudot R, Febvay G, Rey M, Houas A, Guillard C. Appl Catal B, 2010, 94: 192
[19] Elsellami L, Vocanson F, Dappozze F, Puzenat E, Païsse O, Houas A, Guillard C. Appl Catal A, 2010, 380: 142
[20] Tran T H, Nosaka A Y, Nosaka Y. J Phys Chem B, 2006, 110: 25525
[21] Helali S, Dappozze F, Horikoshi S, Bui T H, Perol N, Guillard C. J Photochem Photobiol A, 2013, 255: 50
[22] Turki A, Guillard C, Dappozze F, Berhault G, Ksibi Z, Kochkar H. J Photochem Photobiol A, 2014, 279: 8
[23] Marci G, Sclafani A, Augugliaro V, Palmisano L, Schiavello M. J Photochem Photobiol A, 1995, 89: 69
[24] Chiou C H, Wu C Y, Juang R S. Chem Eng J, 2008, 139: 322
[25] Valencia S, Cataño F, Rios L, Restrepo G, Marín J. Appl Catal B, 2011, 104: 300
[26] Pelizzetti E, Calza P, Mariella G, Maurino V, Minero C, Hidaka H. Chem Commun, 2004: 1504
[27] Dhananjeyan M R, Annapoorani R, Renganathan R. J Photochem Photobiol A, 1997, 109: 147
[28] Ollis D F, Pelizzetti E, Serpone N. Environ Sci Technol, 1991, 25: 1522
[29] Hu C, Yu J C, Hao Z, Wong P K. Appl Catal B, 2003, 46: 35

TiO₂光催化降解胸腺嘧啶的动力学和机理

Kinetics and mechanism of thymine degradation by TiO₂ photocatalysis

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