石墨烯衍生物负载的纳米催化剂用于氧还原反应

doi:10.1016/S1872-2067(15)60971-8

催化学报 ›› 2015, Vol. 36 ›› Issue (11): 1799-1810.DOI: 10.1016/S1872-2067(15)60971-8

石墨烯衍生物负载的纳米催化剂用于氧还原反应

Ilkeun Lee^a, Ji Bong Joo^b, Mohammadreza Shokouhimehr^c

a 加利福尼亚大学河滨分校化学系, 美国;
b 韩国能源研究所低碳过程实验室, 大田305-343, 韩国;
c 国立首尔大学工程学院, 化工和生物工程系, 首尔151-741, 韩国

收稿日期:2015-06-30 修回日期:2015-09-09 出版日期:2015-11-02 发布日期:2015-11-02
通讯作者: Ilkeun Lee. 电子信箱:ilkeun@ucr.edu;Ji Bong Joo. 电子信箱:jbjoo@kier.re.kr;Mohammadreza Shokouhimehr. 电子信箱:mrsh2@snu.ac.kr

Graphene derivatives supported nanocatalysts for oxygen reduction reaction

Ilkeun Lee^a, Ji Bong Joo^b, Mohammadreza Shokouhimehr^c

a Department of Chemistry, University of California, Riverside, CA, 92521, USA;
b Low Carbon Process Lab, Korea Institute of Energy Research, Deajeon 305-343, Korea;
c School of Chemical and Biological Engineering, College of Engineering, Seoul National University, Seoul 151-741, Korea

Received:2015-06-30 Revised:2015-09-09 Online:2015-11-02 Published:2015-11-02
Contact: Ilkeun Lee. 电子信箱:ilkeun@ucr.edu;Ji Bong Joo. 电子信箱:jbjoo@kier.re.kr;Mohammadreza Shokouhimehr. 电子信箱:mrsh2@snu.ac.kr

摘要/Abstract

摘要：

综述了用于燃料电池中氧还原反应(ORR)的石墨烯衍生物负载的各种纳米催化剂的最新进展. 介绍了用于表征石墨烯基电催化剂的常规电化学技术以及石墨烯基电催化剂最新的研究进展. 负载于还原氧化石墨烯(RGO)上的Pt催化剂的电化学活性和稳定性均得到显著提高. 其它贵金属催化剂, 如Pd, Au和Ag也表现出较高的催化活性. 当以RGO或少层石墨烯为载体时, Pd催化剂的稳定性提高. 讨论了氧化石墨烯负载Au或Ag催化剂的合成方法. 另外, 以N₄螯合络合物形式存在的非贵过渡金属可降低氧的电化学性能. Fe和Co是可替代的廉价ORR催化剂. 在大多数情况下, 这些催化剂稳定性和耐受性的问题均可得到解决, 但其整体性能还很难超越Pt/C催化剂.

关键词: 石墨烯, 氧还原反应, 电催化剂, 纳米催化剂

Abstract:

Very recent progress on the graphene derivatives supported variable nanocatalysts for oxygen reduction reaction (ORR) in fuel cell is reviewed. First, common electrochemical techniques to characterize graphene-based electrocatalysts are mentioned. Second, recent updates on graphene-derived electrocatalysts are introduced. In this part, both electrochemical activity and stability of Pt catalysts can be improved when they are supported by reduced graphene oxide (RGO). Other noble-metal catalysts including Pd, Au, and Ag showing comparable performance have been investigated. The stability of Pd catalyst is enhanced by RGO or few-layered graphene support. Synthetic approaches for Au or Ag catalysts supported on graphene oxide are discussed. In addition, non-noble transition metals in N₄-chelate complexes can reduce oxygen electrochemically. Fe and Co are cheap alternative catalysts for ORR. In most cases, the stability and tolerance issues are overcome well, but their overall performances don't seem to surpass Pt/C catalyst yet.

Key words: Graphene, Oxygen reduction reaction, Electrocatalyst, Nanocatalyst

Ilkeun Lee, Ji Bong Joo, Mohammadreza Shokouhimehr. 石墨烯衍生物负载的纳米催化剂用于氧还原反应[J]. 催化学报, 2015, 36(11): 1799-1810.

Ilkeun Lee, Ji Bong Joo, Mohammadreza Shokouhimehr. Graphene derivatives supported nanocatalysts for oxygen reduction reaction[J]. Chinese Journal of Catalysis, 2015, 36(11): 1799-1810.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(15)60971-8

https://www.cjcatal.com/CN/Y2015/V36/I11/1799

参考文献

[1] Zhu C Z, Dong S J. Nanoscale, 2013, 5: 1753
[2] Guo S J, Zhang S, Sun S H. Angew Chem Int Ed, 2013, 52: 8526
[3] Wang Y J, Wilkinson D P, Zhang J J. Chem Rev, 2011, 111: 7625
[4] Song C J, Zhang J J. In: Zhang J Ed. PEM Fuel Cell Electrocatalysts and Catalyst Layers. London: Springer, 2008. 89
[5] Liu Y, Wu Y Y, Lü G J, Pu T, He X Q, Cui L L. Electrochim Acta, 2013, 112: 269
[6] Liu J F, Takeshi D, Orejon D, Sasaki K, Lyth S M. J Electrochem Soc, 2014, 161: F544
[7] Monteverde Videla A H A, Ban S, Specchia S, Zhang L, Zhang J J. Carbon, 2014, 76: 386
[8] Jin S, Chen M, Dong H F, He B Y, Lu H T, Su L, Dai W H, Zhang Q C, Zhang X J. J Power Sources, 2015, 274: 1173
[9] Ghanbarlou H, Rowshanzamir S, Kazeminasab B, Parnian M J. J Power Sources, 2015, 273: 981
[10] Knights S D, Colbow K M, St-Pierre J, Wilkinson D P. J Power Sources, 2004, 127: 127
[11] Yuan X Z, Wang H J. In: Zhang J Ed. PEM Fuel Cell Electrocatalysts and Catalyst Layers. London: Springer, 2008. 1
[12] He D P, Cheng K, Li H G, Peng T, Xu F, Mu S C, Pan M. Langmuir, 2012, 28: 3979
[13] Li Y J, Li Y J, Zhu E B, McLouth T, Chiu C Y, Huang X Q, Huang Y. J Am Chem Soc, 2012, 134: 12326
[14] He D P, Cheng K, Peng T, Sun X L, Pan M, Mu S C. J Mater Chem, 2012, 22: 21298
[15] Yu X Q, Wang H, Guo L P, Wang L. Chem Asian J, 2014, 9: 3221
[16] Seo M H, Choi S M, Kim H J, Kim W B. Electrochem Commun, 2011, 13: 182
[17] Kong X K, Chen Q W, Lun Z Y. ChemPhysChem, 2014, 15: 344
[18] Huang Y X, Xie J F, Zhang X, Xiong L, Yu H Q. ACS Appl Mater Interf, 2014, 6: 15795
[19] Truong-Phuoc L, Pham-Huu C, Da Costa V, Janowska I. Chem Commun, 2014, 50: 14433
[20] Janowska I, Vigneron F, Begin D, Ersen O, Bernhardt P, Romero T, Ledoux M J, Pham-Huu C. Carbon, 2012, 50: 3106
[21] Haruta M, Yamada N, Kobayashi T, Iijima S. J Catal, 1989, 115: 301
[22] Haruta M. Catal Today, 1997, 36: 153
[23] Lee I, Joo J B, Yin Y, Zaera F. Angew Chem Int Ed, 2011, 50: 10208
[24] Wang S N, Zhang M C, Zhang W Q. ACS Catal, 2011, 1: 207
[25] Wu X F, Song H Y, Yoon J M, Yu Y T, Chen Y F. Langmuir, 2009, 25: 6438
[26] Geim A K, Novoselov K S. Nat Mater, 2007, 6: 183
[27] Allen M J, Tung C V, Kaner B R. Chem Rev, 2010, 110: 132
[28] Xu S J, Wu P Y. J Mater Chem A, 2014, 2: 13682
[29] Lightcap I V, Kosel T H, Kamat P V. Nano Lett, 2010, 10: 577
[30] Wu D Q, Zhang F, Liu P, Feng X L. Chem Eur J, 2011, 17: 10804
[31] Xu S J, Yong L,Wu P Y. ACS Appl Mater Interfaces, 2013, 5: 654
[32] Dhavale V M, Gaikwad S S, Kurungot S. J Mater Chem A, 2014, 2: 1383
[33] Zhang P P, Huang Y, Lu X, Zhang S Y, Li J F, Wei G, Su Z Q. Langmuir, 2014, 30: 8980
[34] Wang F B, Wang J, Shao L, Zhao Y, Xia X H. Electrochem Commun, 2014, 38: 82
[35] Govindhan M, Chen A. J Power Sources, 2015, 274: 928
[36] Li X R, Li X L, Xu M C, Xu J J, Chen H Y. J Mater Chem A, 2014, 2: 1697
[37] Kim S S, Kim Y R, Chung T D, Sohn B H. Adv Funct Mater, 2014, 24: 2764
[38] Liu F, Choi J Y, Seo T S. Chem Commun, 2010, 46: 2844
[39] Liu J B, Li Y L, Li Y M, Li J H, Deng Z X. J Mater Chem, 2010, 20: 900
[40] Imura Y, Maezawa A, Morita C, Kawai T. Langmuir, 2012, 28: 14998
[41] Yin H J, Tang H J, Wang D, Gao Y, Tang Z Y. ACS Nano, 2012, 6: 8288
[42] Ji X H, Song X N, Li J, Bai Y B, Yang W S, Peng X G. J Am Chem Soc, 2007, 129: 13939
[43] Huo Z Y, Tsung C K, Huang W Y, Zhang X F, Yang P D. Nano Lett, 2008, 8: 2041
[44] Choi H C, Shim M, Bangsaruntip S, Dai H J. J Am Chem Soc, 2002, 124: 9058
[45] Yuan L Z, Jiang L H, Liu J, Xia Z X, Wang S L, Sun G Q. Electrochim Acta, 2014, 135: 168
[46] Liu R J, Yu X L, Zhang G J, Zhang S J, Cao H B, Dolbecq A, Mialane P, Keita B, Zhi L J. J Mater Chem A, 2013, 1: 11961
[47] Davis D J, Raji A R O, Lambert T N, Vigil J A, Li L, Nan K, Tour J M. Electroanalysis, 2014, 26: 164
[48] Kumar S, Selvaraj C, Scanlon L G, Munichandraiah N. Phys Chem Chem Phys, 2014, 16: 22830
[49] Lim E J, Choi S M, Seo M H, Kim Y, Lee S, Kim W B. Electrochem Commun, 2013, 28: 100
[50] Genies L, Faure R, Durand R. Electrochim Acta, 1998, 44: 1317
[51] Shin H J, Kim K K, Benayad A, Yoon S M, Park H K, Jung I S, Jin M H, Jeong H K, Kim J M, Choi J Y, Lee Y H. Adv Funct Mater, 2009, 19: 1987
[52] Jasinski R J. Nature, 1964, 201: 1212
[53] Jiang Y Y, Lu Y Z, Lü X Y, Han D X, Zhang Q X, Niu L, Chen W. ACS Catal, 2013, 3: 1263
[54] Zhao X N, Zhang P P, Chen Y T, Su Z Q, Wei G. Nanoscale, 2015, 7: 5080
[55] Tiwari J N, Kemp K C, Nath K, Tiwari R N, Nam H G, Kim K S. ACS Nano, 2013, 7: 9223
[56] Chen H S, Liang Y T, Chen T Y, Tseng Y C, Liu C W, Chung S R, Hsieh C T, Lee C E, Wang K W. Chem Commun, 2014, 50: 11165
[57] Tiido K, Alexeyeva N, Couillard M, Bock C, MacDougall B R, Tammeveski K. Electrochim Acta, 2013, 107: 509
[58] Tan Y M, Xu C F, Chen G X, Zheng N F, Xie Q J. Energy Environ Sci, 2012, 5: 6923
[59] Chou C C, Liu C H, Chen B H. Energy, 2014, 70: 231
[60] Tiwari J N, Nath K, Kumar S, Tiwari R N, Kemp C, Le N H, Youn D H, Lee J S, Kim K S. Nat Commun, 2013, 4: 3221
[61] Nam K W, Song J, Oh K H, Choo M J, Park H A, Park J K, Choi J W. J Solid State Electrochem, 2013, 17: 767
[62] Li Y J, Li Y J, Zhu E B, McLouth T, Chiu C Y, Huang X Q, Huang Y. J Am Chem Soc, 2012, 134: 12326
[63] Carrera-Cerritos R, Baglio V, Aricò A S, Ledesma-García J, Sgroi M F, Pullini D, Pruna A J, Mataix D B, Fuentes-Ramírez R, Arriaga L G. Appl Catal B, 2014, 144: 554
[64] Kakaei K, Gharibi H. Energy, 2014, 65: 166
[65] Zhang P D, Zhang X Y, Zhang S Y, Lu X, Li Q, Su Z Q, Wei G. J Mater Chem B, 2013, 1: 6525
[66] Yu D B, Yao J F, Qiu L, Wu Y Z, Li L X, Feng Y, Liu Q, Li D, Wang H T. RSC Adv, 2013, 3: 11552
[67] Yin H, Zhang C Z, Liu F, Hou Y L. Adv Funct Mater, 2014, 24: 2930
[68] Gao X, Wang J F, Ma Z, Ye J S. Electrochim Acta, 2014, 130: 543
[69] He C Y, Zhang J J, Shen P K. J Mater Chem A, 2014, 2: 3231
[70] Lin L, Li M, Jang L Q, Li Y F, Liu D J, He X Q, Cui L L. J Power Sources, 2014, 268: 269
[71] Li M, Bo X J, Zhang Y F, Han C, Guo L P. J Power Sources, 2014, 264: 114
[72] Lim C S, Ambrosi, A, Sofer Z, Pumera M. Nanoscale, 2014, 6: 7391
[73] Taniguchi T, Tateishi H, Miyamoto S, Hatakeyama K, Ogata C, Funatsu A, Hayami S, Makinose Y, Matsushita N, Koinuma M, Matsumoto Y. Part Part Syst Charact, 2013, 30: 1063
[74] Zheng B, Wang J, Wang F B, Xia X H. J Mater Chem A, 2014, 2: 9079
[75] Jiang Y Y, Lu Y Z, Wang X D, Bao Y, Chen W, Niu L. Nanoscale, 2014, 6: 15066

石墨烯衍生物负载的纳米催化剂用于氧还原反应

Graphene derivatives supported nanocatalysts for oxygen reduction reaction

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	张季, 俞爱民, 孙成华. 非金属掺杂石墨烯异核双原子催化剂氮还原特性研究[J]. 催化学报, 2023, 52(9): 263-270.
[2]	赵磊, 张震, 朱昭昭, 李平波, 蒋金霞, 杨婷婷, 熊佩, 安旭光, 牛晓滨, 齐学强, 陈俊松, 吴睿. 缺陷氮掺杂碳耦合Co-N₅单原子位点用于高效锌-空气电池[J]. 催化学报, 2023, 51(8): 216-224.
[3]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[4]	贡立圆, 王颖, 刘杰, 王显, 李阳, 侯帅, 武志坚, 金钊, 刘长鹏, 邢巍, 葛君杰. 重塑位于火山曲线右支的弱吸附金属单原子位点的配位环境及电子结构[J]. 催化学报, 2023, 50(7): 352-360.
[5]	欧阳玲, 梁杰, 罗永嵩, 郑冬冬, 孙圣钧, 刘倩, Mohamed S. Hamdy, 孙旭平, 应斌武. 电催化合成氨的研究进展[J]. 催化学报, 2023, 50(7): 6-44.
[6]	张光颖, 刘旭, 张欣欣, 梁志坚, 邢耕宇, 蔡斌, 沈迪, 王蕾, 付宏刚. P修饰提高Fe-N-C的氧反应活性用于高稳定的锌-空气电池[J]. 催化学报, 2023, 49(6): 141-151.
[7]	李静静, 张锋伟, 詹新雨, 郭河芳, 张涵, 昝文艳, 孙振宇, 张献明. 酞菁镍分子结构的精确设计: 优化电子和空间效应用于CO₂电还原[J]. 催化学报, 2023, 48(5): 117-126.
[8]	姜润, 乔泽龙, 许昊翔, 曹达鹏. 用于氧还原反应的Fe-N-C单原子催化剂的缺陷工程[J]. 催化学报, 2023, 48(5): 224-234.
[9]	张文静, 李静, 魏子栋. 碳基氧还原电催化剂: 机理研究和多孔结构[J]. 催化学报, 2023, 48(5): 15-31.
[10]	张锋伟, 郭河芳, 刘萌萌, 赵阳, 洪峰, 李静静, 董正平, 乔波涛. 表面应力介导的碳基Pt纳米催化剂用于硝基芳烃的高选择性加氢[J]. 催化学报, 2023, 48(5): 195-204.
[11]	詹麒尼, 帅婷玉, 徐慧民, 黄陈金, 张志杰, 李高仁. 单原子催化剂的合成及其在电化学能量转换中的应用[J]. 催化学报, 2023, 47(4): 32-66.
[12]	唐甜蜜, 王寅, 韩憬怡, 张巧巧, 白雪, 牛效迪, 王振旅, 管景奇. 用于氧还原反应的双原子钴-铁催化剂[J]. 催化学报, 2023, 46(3): 48-55.
[13]	吴则星, 高玉肖, 王子璇, 肖卫平, 王新萍, 李彬, 李镇江, 刘晓斌, 马天翼, 王磊. 表面富集的超小铂纳米颗粒耦合缺陷磷化钴用于高效的电催化水分解和柔性锌空气电池[J]. 催化学报, 2023, 46(3): 36-47.
[14]	刘轩, 梁嘉顺, 李箐. 燃料电池金属间Pt-M合金氧还原催化剂的设计原理及合成方法[J]. 催化学报, 2023, 45(2): 17-26.
[15]	刘小妮, 刘晓斌, 李彩霞, 杨波, 王磊. 缺陷工程在金属基电池中的研究进展[J]. 催化学报, 2023, 45(2): 27-87.