MOFs光催化材料的设计和调控

doi:10.1016/S1872-2067(15)60984-6

催化学报 ›› 2015, Vol. 36 ›› Issue (12): 2071-2088.DOI: 10.1016/S1872-2067(15)60984-6

MOFs光催化材料的设计和调控

沈丽娟^a,c, 梁若雯^a, 吴棱^a,b

a 福州大学能源与环境光催化国家重点实验室, 福建福州 350002;
b 中国科学院福建物质结构研究所结构化学国家重点实验室, 福建福州 350002;
c 福州大学化肥催化剂国家工程研究中心, 福建福州 350002

收稿日期:2015-08-29 修回日期:2015-09-24 出版日期:2015-12-02 发布日期:2015-12-07
通讯作者: 吴棱
基金资助:
国家自然科学基金(21273036, 21177024); 国家重点基础研究发展计划(973计划)资助项目(2014CB239303).

Strategies for engineering metal-organic frameworks as efficient photocatalysts

Lijuan Shen^a,c, Ruowen Liang^a, Ling Wu^a,b

a State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou 350002, Fujian, China;
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China;
c National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, Fujian, China

Received:2015-08-29 Revised:2015-09-24 Online:2015-12-02 Published:2015-12-07
Supported by:
This work was supported by the National Natural Science Foundation of China (21273036, 21177024) and the National Basic Research Program of China (973 Program, 2014CB239303).

摘要/Abstract

摘要：

环境污染和能源短缺是制约当今社会发展的重大问题.光催化技术可直接利用太阳能驱动一系列重要的化学反应,具有能耗低、反应条件温和、无二次污染等优点,是解决这一问题的有效途径.实现这个过程的关键在于寻找设计高效的光催化剂.目前,光催化材料主要由无机半导体组成,其结构的改造和修饰难度很大,难以根据实际需要来控制其大小、形状以及物理化学特性.而有机化合物具有优良的分子剪裁与修饰的功能,但它们却在坚固性与稳定性等方面具有明显的缺点.因此如果能发展既具有无机化合物的稳定性又具有有机化合物的可剪裁与修饰性的新型光催化材料,无疑将促进光催化的发展和应用.
金属-有机骨架材料(Metal-Organic Frameworks, MOFs)正是这样一类结合了无机物的稳定性和有机物的可修饰性的杂化材料.MOFs是一类以金属阳离子为节点、有机配体为连接体的多孔配位聚合物的总称.这类材料不仅拥有超高的比表面积、丰富的拓扑结构,而且其结构兼具可剪裁性、可设计性、易调变等特点,在气体吸附储存、分离、传感等领域都有广泛的应用.在催化领域MOFs也显示出巨大的应用前景:(1)比表面积大,有利于对反应底物的吸附,促进催化反应的进行;(2)组成多样,结构具可剪裁性、可设计性、易调变等特点,通过对其金属单元或者配体进行改变修饰,可以实现对MOFs结构和性能的调变;(3)MOFs中金属-氧单元之间由有机配体隔开,相当于分立的半导体量子点,在反应中不易发生团聚.并且各个分立的金属-氧单元之间可能存在协同效应,有利于保持催化剂的稳定性和产生高的催化活性.因此,MOFs材料是一类非常有潜力的异相催化剂.光催化是一类典型的多相催化技术,与传统半导体光催化材料相比,MOFs由于具有可在分子水平进行灵活调控的优点,在光催化领域的应用更有优势.此外,MOFs结构上的确定性为研究催化剂的界面电荷迁移和光催化机理提供了便利条件, 通过对其构-效关系的研究和光催化反应机理的探索反过来有助于我们从微观尺度上进一步认识光催化的本质.
MOFs材料在光催化领域已经有了初步的研究.越来越多的MOFs材料被成功应用于光催化降解染料、选择性转化有机物、光解水制氢和CO₂还原等反应.典型的有MOF-5、UiO-66和MIL-125系列等.近年来,已有少量的文献综述了MOFs这类材料在光催化领域的研究.这些文献主要围绕MOFs在光催化过程中所起到的作用,比如作为催化剂、助催化剂或载体来展开;或者是从MOFs的光催化应用领域,比如污染物降解、产氢、二氧化碳还原、有机物转化来分类展开.本文围绕如何设计合成高效的MOFs光催化剂,综述了近年来国内外关于提高MOFs的光催化性能而开展的相关研究工作,包括理论研究MOFs的能级结构及化学性质、在MOFs配体上修饰官能团调变其能带结构、染料或者金属化合物光敏化MOFs提高其光吸收性能、负载金属/碳材料及半导体复合提高光生载流子的分离效率等.最后,本文对MOFs光催化剂的未来发展趋势进行了展望,强调开发新型的MOFs光催化剂,并加强对MOFs光催化机制的研究,有助于指导现有MOFs催化剂的改良和设计新型光催化剂.

关键词: 金属-有机骨架材料, 光催化, 配体, 功能化, 光敏化, 助催化剂, 复合材料

Abstract:

Environmental pollution and energy deficiency represent major problems for the sustainability of the modern world. Photocatalysis has recently emerged as an effective and environmentally friendly technique to address some of these sustainability issues, although the key to the success of this approach is dependent on the photocatalysts themselves. Based on their attractive physic chemical properties, including their ultrahigh surface areas, homogeneous active sites and tunable functionality, metal-organic frameworks (MOFs) have become interesting platforms for the development of solar energy conversion devices. Furthermore, MOFs have recently been used in a wide variety of applications, including heterogeneous photocatalysis for pollutant degradation, organic transformations, hydrogen production and CO₂ reduction. In this review, we have highlighted recent progress towards the application of MOFs in all of these areas. We have collected numerous reported examples of the use of MOFs in these areas, as well as providing some analysis of the key factors influencing the efficiency of these systems. Moreover, we have provided a detailed discussion of new strategies that have been developed for enhancing the photocatalytic activity of MOFs. Finally, we have provided an outlook for this area in terms of the future challenges and potential prospects for MOFs in photocatalysis.

Key words: Metal-organic frameworks, Photocatalysis, Ligand, Functionalization, Photosensitization, Co-catalyst, Composite

沈丽娟, 梁若雯, 吴棱. MOFs光催化材料的设计和调控[J]. 催化学报, 2015, 36(12): 2071-2088.

Lijuan Shen, Ruowen Liang, Ling Wu. Strategies for engineering metal-organic frameworks as efficient photocatalysts[J]. Chinese Journal of Catalysis, 2015, 36(12): 2071-2088.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(15)60984-6

https://www.cjcatal.com/CN/Y2015/V36/I12/2071

参考文献

[1] Fujishima A, Honda K. Nature, 1972, 238: 37
[2] Liang S J, Wen L R, Lin S, Bi J H, Feng P Y, Fu X Z, Wu L. Angew Chem Int Ed, 2014, 53: 2951
[3] Fox M A, Dulay M T. Chem Rev, 1993, 93: 341
[4] Liu Y C, Xing M Y, Zhang J L. Chin J Catal (刘允昌,刑明阳,张金龙. 催化学报), 2014, 35: 1511
[5] Kudo A, Miseki Y. Chem Soc Rev, 2009, 38: 253
[6] Wang M Y, Ioccozia J, Sun L, Lin J C, Lin Z Q. Energy Environ Sci, 2014, 7: 2182
[7] Liu G, Yang H G, Pan J, Yang Y Q, Lu G Q, Cheng H M. Chem Rev, 2014, 114: 9559
[8] Yu J G, Yu X X. Environ Sci Technol, 2008, 42: 4902
[9] Zeng H B, Cai W P, Liu P S, Xu X X, Zhou H J, Klingshirn C, Kalt H. ACS Nano, 2008, 2: 1661
[10] Hou J G, Wang Z, Kan W B, Jiao S Q, Zhu H M, Kumar R V. J Mater Chem, 2012, 22: 7291
[11] Wu W M, Liu G D, Xie Q H, Liang S J, Zheng H R, Yuan R, Su W Y, Wu L. Green Chem, 2012, 14: 1705
[12] Xiang Q J, Cheng B, Yu J G. Appl Catal B, 2013, 138-139: 299
[13] Xu L, Xia J X, Wang K, Wang L G, Li H M, Xu H, Huang L Y, He M Q,. Dalton Trans, 2013, 42: 6468
[14] Li Q, Guo B, Yu J G, Ran J R, Zhang B H, Yan H J, Gong J R. J Am Chem Soc, 2011, 133: 10878
[15] Hernandez-Alonso M D, Fresno F, Suarez S, Coronado J M. Energy Environ Sci, 2009, 2: 1231
[16] Nasalevich M A, Becker R, Ramos-Fernandez E V, Castellanos S, Veber S L, Fedin M V, Kapteijn F, Reek J N H, van der Vlugt J I, Gascan J. Energy Environ Sci, 2015, 8: 364
[17] Wu T B, Zhang P, Ma J, Fan H L, Wang W T, Jiang T, Han B X. Chin J Catal (吴天斌,张鹏,马珺,樊红雷,王伟涛,姜涛,韩布兴. 催化学报), 2013, 34: 167
[18] Collins D J, Zhou H-C. J Mater Chem, 2007, 17: 3154
[19] Liu J, Strachan D M, Thallapally P K. Chem Commun, 2014, 50: 466
[20] Tanh Jeazet H B, Staudt C, Janiak C. Dalton Trans, 2012, 41: 14003
[21] Guo Z Y, Xu H, Su S Q, Cai J F, Dang S, Xiang S C, Qian G D, Zhang H J, O'Keeffe M, Chen B L. Chem Commun, 2011, 47: 5551
[22] Chen B L, Wang L B, Xiao Y Q, Fronczek F R, Xue M, Cui Y J, Qian G D. Angew Chem Int Ed, 2009, 48: 500
[23] Lee J, Farha O K, Roberts J, Scheidt K A, Nguyen S T, Hupp J T. Chem Soc Rev, 2009, 38: 1450
[24] Wu C-D, Lin W. Angew Chem Int Ed, 2007, 46: 1075
[25] Llabrés i Xamena F X, Casanova O, Galiasso Tailleur R, Garcia H, Corma A. J Catal, 2008, 255: 220
[26] Corma A, García H, Llabrés i Xamena F X. Chem Rev, 2010, 110: 4606
[27] Choi J R, Tachikawa T, Fujitsuka M, Majima T. Langmuir, 2010, 26: 10437
[28] Horiuchi Y, Toyao T, Takeuchi M, Matsuoka M, Anpo M. Phys Chem Chem Phys, 2013, 15: 13243
[29] Wang S B, Yao W S, Lin J L, Ding Z X, Wang X C. Angew Chem Int Ed 2014, 53: 1034
[30] Li S, Huo F. Nanoscale, 2015, 7: 7482
[31] Johnson J A, Luo J, Zhang X, Chen Y-S, Morton M D, Echeverría E, Torres F E, Zhang J. ACS Catal, 2015: 5283
[32] Alvaro M, Carbonell E, Ferrer B, Llabrés i Xamena F X, Garcia H. Chem Eur J, 2007, 13: 5106
[33] Jiang D M, Mallat T, Krumeich F, Baiker A. J Catal, 2008, 257: 390
[34] Hasegawa S, Horike S, Matsuda R, Furukawa S, Mochizuki K, Kinoshita Y, Kitagawa S. J Am Chem Soc, 2007, 129: 2607
[35] Kovtunov K V, Zhivonitko V V, Corma A, Koptyug I V. J Phys Chem Lett, 2010, 1: 1705
[36] Wang J L, Wang C, Lin W B. ACS Catal, 2012, 2: 2630
[37] Zhang T, Lin W B. Chem Soc Rev, 2014, 43: 5982
[38] Wang C C, Li J R, Lv X L, Zhang Y Q, Guo G. Energy Environ Sci, 2014, 7: 2831
[39] Wang S B, Wang X C. Small, 2015, 11: 3097
[40] Wang C C, Zhang Y Q, Li J, Wang P. J Mol Struct, 2015, 1083: 127
[41] Fuentes-Cabrera M, Nicholson D M, Sumpter B G, Widom M. J Chem Phys, 2005, 123: 124713
[42] Bordiga S, Lamberti C, Ricchiardi G, Regli L, Bonino F, Damin A, Lillerud K P, Bjorgen M, Zecchina A. Chem Commun, 2004: 2300
[43] Tachikawa T, Choi J R, Fujitsuka M, Majima T. J Phys Chem C, 2008, 112: 14090
[44] Du J J, Yuan Y P, Sun J X, Peng F M, Jiang X, Qiu L G, Xie A J, Shen Y H, Zhu J F. J Hazard Mater, 2011, 190: 945
[45] Wu P Y, He C, Wang J, Peng X J, Li X Z, An Y L, Duan C Y. J Am Chem Soc, 2012, 134: 14991
[46] Pu S, Xu L, Sun L, Du H B. Inorg Chem Commun, 2015, 52: 50
[47] Mohaghegh N, Tasviri M, Rahimi E, Gholami M R. Appl Surf Sci, 2015, 351: 216
[48] Wang H, Yuan X Z, Wu Y, Zeng G M, Chen X H, Leng L J, Li H. Appl Catal B, 2015, 174-175: 445
[49] Wang H, Yuan X Z, Wu Y, Zeng G M, Chen X H, Leng L J, Wu Z B, Jiang L B, Li H. J Hazard Mater, 2015, 286: 187
[50] Zhou J J, Wang R, Liu X L, Peng F M, Li C H, Teng F, Yuan Y P. Appl Surf Sci, 2015, 346: 278
[51] Zhang S Q, Li L N, Zhao S G, Sun Z H, Hong M C, Luo J H. J Mater Chem A, 2015, 3: 15764
[52] Yang J H, Wang D G, Han H X, Li C. Acc Chem Res, 2013, 46: 1900
[53] Fu Y H, Sun D R, Chen Y J, Huang R K, Ding Z X, Fu X Z, Li Z H. Angew Chem Int Ed, 2012, 51: 3364
[54] Shen L J, Liang S J, Wu W M, Liang R W, Wu L. Dalton Trans, 2013, 42: 13649
[55] Shen L J, Liang R W, Luo M B, Jing F F, Wu L. Phys Chem Chem Phys, 2015, 17: 117
[56] Zhou T H, Du Y H, Borgna A, Hong J D, Wang Y, Han J Y, Zhang W, Xu R. Energy Environ Sci, 2013, 6: 3229
[57] Toyao T, Saito M, Dohshi S, Mochizuki K, Iwata M, Higashimura H, Horiuchi Y, Matsuoka M. Chem Commun, 2014, 50: 6779
[58] Nasalevich M A, Goesten M G, Savenije T J, Kapteijn F, Gascon J. Chem Commun, 2013, 49: 10575
[59] He J, Wang J Q, Chen Y J, Zhang J P, Duan D L, Wang Y, Yan Z Y. Chem Commun, 2014, 50: 7063
[60] Yang H, He X-W, Wang F, Kang Y, Zhang J. J Mater Chem, 2012, 22: 21849
[61] Wen M C, Kuwahara Y, Mori K, Zhang D Q, Li H X, Yamashita H. J Mater Chem A, 2015, 3: 14134
[62] Sun D R, Liu W J, Qiu M, Zhang Y F, Li Z H. Chem Commun, 2015, 51: 2056
[63] Horiuchi Y, Toyao T, Saito M, Mochizuki K, Iwata M, Higashimura H, Anpo M, Matsuoka M. J Phys Chem C, 2012, 116: 20848
[64] Shen L J, Wu W M, Liang R, Lin R, Wu L. Nanoscale, 2013, 5: 9374
[65] Liang R W, Luo S G, Jing F F, Shen L J, Qin N, Wu L. Appl Catal B, 2015, 176-177: 240
[66] Liang R W, Jing F F, Shen L J, Qin N, Wu L. Nano Res, 2015, 8: 3237
[67] Shen L J, Luo M B, Huang L J, Feng P Y, Wu L. Inorg Chem, 2015, 54: 1191
[68] Wu Y, Luo Hanjin, Wang H. RSC Adv, 2014, 4: 40435
[69] Shen L J, Huang L J, Liang S J, Liang R W, Qin N, Wu L. RSC Adv, 2014, 4: 2546
[70] Liang R W, Shen L J, Jing F F, Qin N, Wu L. ACS Appl Mater Interfaces, 2015, 7: 9507
[71] Shen L J, Liang, S J, Wu W M, Liang R W, Wu L. J Mater Chem A, 2013, 1: 11473
[72] Zhang C F, Qiu L G, Ke F, Zhu Y J, Yuan Y P, Xu G S, Jiang X. J Mater Chem A, 2013, 1: 14329
[73] Xu Y L, Lv M M, Yang H B, Chen Q, Liu X T, Wei F Y. RSC Adv, 2015, 5: 43473
[74] Gao S J, Liu W H, Shang N Z, Feng C, Wu Q H, Wang Z, Wang C. RSC Adv, 2014, 4: 61736
[75] Shi L, Wang T, Zhang H B, Chang K, Ye J H. Adv Funct Mater, 2015, 25: 5260
[76] Nasalevich M A, van der Veen M, Kapteijn F, Gascon J. CrystEngComm, 2014, 16: 4919
[77] Dan-Hardi M, Serre C, Frot T, Rozes L, Maurin G, Sanchez C, Férey G. J Am Chem Soc, 2009, 131: 10857
[78] Hendon C H, Tiana D, Fontecave M, Sanchez C, D'arras L, Sassoye C, Rozes L, Mellot-Draznieks C, Walsh A. J Am Chem Soc, 2013, 135: 10942
[79] Cavka J H, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud K P. J Am Chem Soc, 2008, 130: 13850
[80] Fateeva A, Chater P A, Ireland C P, Tahir A A, Khimyak Y Z, Wiper P V, Darwent J R, Rosseinsky M J. Angew Chem Int Ed, 2012, 51: 7440
[81] Tran P D, Wong L H, Barber J, Loo J S C. Energy Environ Sci, 2012, 5: 5902
[82] Vinodgopal K, Wynkoop D E, Kamat P V. Environ Sci Technol, 1996, 30: 1660
[83] Takanabe K, Kamata K, Wang X C, Antonietti M, Kubota J, Domen K. Phys Chem Chem Phys, 2010, 12: 13020
[84] Taira S, Miki T, Yanagi H. Appl Surf Sci, 1999, 143: 23
[85] Yuan Y P, Yin L S, Cao S W, Xu G S, Li C H, Xue C. Appl Catal B, 2015, 168-169: 572
[86] Ni Y H, Zhu Y, Ma X. Dalton Trans, 2011, 40: 3689
[87] Liu S, Guo E Y, Yin L M. J Mater Chem, 2012, 22: 5031
[88] Xiong Z, Wang H B, Xu N Y, Li H L, Fang B Z, Zhao Y C, Zhang J Y, Zheng C G. Int J Hydrogen Energ, 2015, 40: 10049
[89] Zhu Q L, Xu Q. Chem Soc Rev, 2014, 43: 5468
[90] Toyao T, Saito M, Horiuchi Y, Mochizuki K, Iwata M, Higashimura H, Matsuoka M. Catal Sci Technol, 2013, 3: 2092
[91] Zhou W, Li T, Wang J Q, Qu Y, Pan K, Xie Y, Tian G H, Wang L, Ren Z Y, Jiang B J, Fu H G. Nano Res, 2014, 7: 731
[92] Bouhadoun S, Guillard C, Dapozze F, Singh S, Amans D, Bouclé J, Herlin-Boime N. Appl Catal B, 2015, 174-175: 367
[93] Chen J J, Wang W K, Li W W, Pei D N, Yu H Q. ACS Appl Mater Interfaces, 2015, 7: 12671
[94] Nguyen N T, Altomare M, Yoo J E, Schmuki P. Adv Mater, 2015, 27: 3208
[95] Hermes S, Schröter M-K, Schmid R, Khodeir L, Muhler M, Tissler A, Fischer R W, Fischer R A. Angew Chem Int Ed, 2005, 44: 6237
[96] Gu X J, Lu Z H, Jiang H L, Akita T, Xu Q. J Am Chem Soc, 2011, 133: 11822
[97] Ishida T, Nagaoka M, Akita T, Haruta M. Chem Eur J, 2008, 14: 8456
[98] El-Shall M S, Abdelsayed V, Khder A E R S, Hassan H M A, El-Kaderi H M, Reich T E. J Mater Chem, 2009, 19: 7625
[99] Yang M Q, Zhang N, Pagliaro M, Xu Y J. Chem Soc Rev, 2014, 43: 8240
[100] An X Q,Yu J C. RSC Adv, 2011, 1: 1426
[101] Yang M Q, Xu Y J. J Phys Chem C, 2013, 117: 21724
[102] Yang M Q, Zhang N, Xu Y J. ACS Appl Mater Interfaces, 2013, 5: 1156
[103] Zhang J, Yu J, Jaroniec M, Gong J R. Nano Lett, 2012, 12: 4584
[104] Han C, Chen Z, Zhang N, Colmenares J C, Xu Y-J. Adv Funct Mater, 2015, 25: 221
[105] Liang R W, Jing F F, Shen L J, Qin N, Wu L. J Hazard Mater, 2015, 287: 364
[106] Zhang X, Zhang N, Xu Y J, Tang Z-R. New J Chem, 2015, 39: 6756
[107] Zhang J Y, Wang Y H, Jin J, Zhang J, Lin Z, Huang F, Yu J G. ACS Appl Mater Interfaces, 2013, 5: 10317
[108] Wang X F, Li S F, Ma Y Q, Yu H G, Yu J G. J Phys Chem C, 2011, 115: 14648
[109] Chen X F, Zhang J, Huo Y N, Li H X. Chin J Catal (陈小芳,张佳,霍宇凝,李和兴.催化学报), 2013, 34: 949
[110] Shen L, Luo M, Liu Y, Liang R, Jing F, Wu L. Appl Catal B, 2015, 166-167: 445
[111] Peng R, Wu C M, Baltrusaitis J, Dimitrijevic N M, Rajh T, Koodali R T. Chem Commun, 2013, 49: 3221
[112] Lin R, Shen L J, Ren Z Y, Wu W M, Tan Y X, Fu H R, Zhang J, Wu L. Chem Commun, 2014, 50: 8533
[113] Wang S B, Wang X C. Appl Catal B, 2015, 162: 494
[114] Li R, Hu J H, Deng M S, Wang H L, Wang X J, Hu Y L, Jiang H L, Jiang J, Zhang Q, Xie Y, Xiong Y J. Adv Mater, 2014, 26: 4783
[115] Liu Q, Low Z X, Li L X, Razmjou A, Wang K, Yao J F, Wang H T. J Mater Chem A, 2013, 1: 11563

MOFs光催化材料的设计和调控

Strategies for engineering metal-organic frameworks as efficient photocatalysts

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	赵彬彬, 钟威, 陈峰, 王苹, 别传彪, 余火根. 高晶化g-C₃N₄光催化剂: 合成、结构调控和光催化产氢[J]. 催化学报, 2023, 52(9): 127-143.
[2]	唐小龙, 李锋, 李方, 江燕斌, 余长林. 单原子催化剂在光催化和电催化合成过氧化氢中的研究进展[J]. 催化学报, 2023, 52(9): 79-98.
[3]	石靖, 郭煜华, 谢飞, 章名田, 张洪涛. 氧化还原活性配体的电子效应对钌催化水氧化反应的影响[J]. 催化学报, 2023, 52(9): 271-279.
[4]	蔡铭洁, 刘艳萍, 董珂欣, 陈晓波, 李世杰. 漂浮型Bi₂WO₆/C₃N₄/碳布S型异质结光催化材料用于高效净化水体环境[J]. 催化学报, 2023, 52(9): 239-251.
[5]	王思恺, 闵祥婷, 乔波涛, 颜宁, 张涛. 单原子催化: 追寻催化领域的“圣杯”[J]. 催化学报, 2023, 52(9): 1-13.
[6]	江梓聪, 程蓓, 张留洋, 张振翼, 别传彪. 氧化锌基梯型异质结光催化剂[J]. 催化学报, 2023, 52(9): 32-49.
[7]	刘博文, 蔡家杰, 张建军, 谭海燕, 程蓓, 许景三. MOF/CdS梯型光催化剂同时进行苯甲醇氧化和析氢反应及其机理研究[J]. 催化学报, 2023, 51(8): 204-215.
[8]	宋明明, 宋相海, 刘鑫, 周伟强, 霍鹏伟. ZnIn₂S₄/MOF-808微球结构S型异质结光催化剂的制备及其光还原CO₂性能研究[J]. 催化学报, 2023, 51(8): 180-192.
[9]	李晓娟, 祁明雨, 李婧宇, 谭昌龙, 唐紫蓉, 徐艺军. PdS修饰的ZnIn₂S₄复合材料用于可见光催化硫醇偶联制备二硫化物同时产氢[J]. 催化学报, 2023, 51(8): 55-65.
[10]	邵秀丽, 李可, 李静萍, 程强, 王国宏, 王楷. 揭示NiS@Ta₂O₅纳米纤维中梯型电荷转移路径及光催化CO₂转化性能[J]. 催化学报, 2023, 51(8): 193-203.
[11]	李嘉明, 李源, 王小田, 杨直雄, 张高科. TiO₂上原子分散的Fe位点促进光催化CO₂还原: 增强的催化活性、 DFT计算和机制洞察[J]. 催化学报, 2023, 51(8): 145-156.
[12]	阎菲, 张由子, 刘思碧, 邹睿卿, Jahan B Ghasemi, 李炫华. 供体-受体型卟啉基金属有机框架实现有效电荷分离高效光催化析氢[J]. 催化学报, 2023, 51(8): 124-134.
[13]	孙利娟, 王伟康, 路平, 刘芹芹, 王乐乐, 唐华. 纳米高熵合金实现光催化剂肖特基势垒的调控用于光催化制氢与苯甲醇氧化耦合反应[J]. 催化学报, 2023, 51(8): 90-100.
[14]	刘海峰, 黄祥, 陈加藏. 电子态调控促进氢气无损耗纯化中CO的光致富集和氧化[J]. 催化学报, 2023, 51(8): 49-54.
[15]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.