烷烃脱氢制烯烃用碳催化剂的微结构和表面化学调控研究进展

doi:10.1016/S1872-2067(15)61065-8

催化学报 ›› 2016, Vol. 37 ›› Issue (5): 644-670.DOI: 10.1016/S1872-2067(15)61065-8

烷烃脱氢制烯烃用碳催化剂的微结构和表面化学调控研究进展

赵忠奎, 葛桂芳, 李伟作, 郭新闻, 王桂茹

大连理工大学化工与环境生命学部精细化工国家重点实验室, 辽宁大连 116024

收稿日期:2016-01-13 修回日期:2016-02-22 出版日期:2016-04-26 发布日期:2016-04-26
通讯作者: Zhongkui Zhao
基金资助:
国家自然科学基金(21276041);教育部新世纪优秀人才支持计划(NCET-12-0079);辽宁省自然科学基金(2015020200);中央高校基本科研业务费专项资金(DUT15LK41).

Modulating the microstructure and surface chemistry of carbocatalysts for oxidative and direct dehydrogenation: A review

Zhongkui Zhao, Guifang Ge, Weizuo Li, Xinwen Guo, Guiru Wang

State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2016-01-13 Revised:2016-02-22 Online:2016-04-26 Published:2016-04-26
Contact: Zhongkui Zhao
Supported by:
This work was supported by the National Natural Science Foundation of China (21276041), the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0079), the Natural Science Foundation of Liaoning Province (2015020200) and the Fundamental Research Funds for the Central Universities (DUT15LK41).

摘要/Abstract

摘要：

烯烃是重要的大宗有机化工原料, 广泛用于塑料、树脂、橡胶等高分子材料和基础有机化工产品和中间体的生产. 同时, 烯烃也是重要的精细化工原料和中间体, 广泛用于染料、医药、香料、农用化学品、水性油墨和感光树脂等精细化工领域. 长链烯烃通常是由小分子烯烃聚合制得, 而小分子烯烃和苯乙烯的合成在学术界和工业界备受关注. 在脱氢、裂解、脱水等诸多合成方法中, 烷烃脱氢制烯烃是直接而中的路线, 包括直接脱氢和氧化脱氢. 小分子烷烃和乙苯催化脱氢制备对应的烯烃, 尤其是乙苯制苯乙烯, 目前工业上主要采用铁基催化剂催化直接脱氢工艺. 积炭失活是该工艺面临的严峻挑战. 工业上采用引入大量过热水蒸气的方法来解决这一难题, 同时, 还可以为脱氢反应提供热量. 但是, 这势必造成巨大的能耗和反应器容积效率的显著降低. 氧化脱氢工艺是放热反应, 并可有效抑制积炭, 但又存在过氧化所致的低选择性的问题. 直接脱氢和氧化脱氢各有利弊. 目前, 科学家和工业界都在扬长避短, 开展两种脱氢工艺的新结构高性能催化剂的研究, 并取得了长足进展.
碳催化是近年来发展起来的一类重要的无机非金属固相催化剂, 在光催化、电催化, 以及热催化领域得到了广泛关注, 同时也是材料领域研究的前沿和热点. 碳材料, 尤其是纳米碳, 在诸多反应中展示出了比常规金属催化剂更好的催化性能, 且具有可持续的特征. 因此, 碳催化具有广阔的发展空间和巨大的应用前景. 众所周知, 固体催化剂的催化性能重要依赖于催化剂表面催化活性位的性质及其可及性. 元素组成、化学状态及缺陷边角特征决定着活性位的性质, 而形貌、尺寸、形状、纹理、表面结构等催化剂的微结构特征决定着固相催化剂活性位的可及性. 因此, 探索有效的方法和策略, 来调节固相催化剂的微结构和表面化学性质, 已成为催化学术研究的热点领域. 碳材料的表界面和边角的官能团和结构缺陷是催化反应的活性位. 对于烷烃脱氢反应, 碳材料的表界面羰基和结构缺陷是催化剂的活性位, 而杂原子掺杂可以调控活性位的电子结构.
本文综述了烷烃脱氢用碳催化剂微结构和表面化学调控方法和效果的最新研究进展, 并讨论了烷烃脱氢碳催化材料的微结构和表面化学性质调控的重要性和严峻挑战. 通过碳材料合成中前驱体的优选、合成方法和策略的创新, 以及通过后处理的方法, 均可有效调控碳催化剂的微结构和表面化学性质, 从而调控其烷烃脱氢催化性能. 碳催化用于烷烃脱氢反应制烯烃, 尤其是直接脱氢, 前景看好. 目前, 研究的碳催化剂多为粉末状, 用于固定床, 存在流体阻力大、压力降高、操作困难的问题, 并有可能阻塞床层, 造成安全隐患; 用于流化床, 粉末碳易于团聚, 催化剂过滤分离困难, 流失严重. 纳米碳基整体式催化剂可以是碳催化的未来发展方向. 但是, 目前才刚刚起步. 碳基整体式催化剂活性单元本身可及活性位的性质及活性单元的分散性、抗脱落性和整体式催化剂的机械强度、导热性等诸多问题需要深入研究和探讨.
总之, 碳催化烷烃脱氢, 尤其是无氧化剂、无水蒸气条件下的直接脱氢, 是经济、节能、清洁、高效的烯烃生产方法, 具有广阔的发展空间和美好前景. 微结构和化学性质的调变是调控固相催化剂催化活性位性质和可接近性的重要方法, 碳催化材料及整体式催化剂的碳基活性单元微结构和化学性质的调控是实现其催化性能调控的有效策略.

关键词: 碳催化, 微结构, 表面化学, 调控, 脱氢, 烯烃

Abstract:

The catalytic performance of solid catalysts depends on the properties of the catalytically active sites and their accessibility to reactants, which are significantly affected by the microstructure (morphology, shape, size, texture, and surface structure) and surface chemistry (elemental components and chemical states). The development of facile and efficient methods for tailoring the microstructure and surface chemistry is a hot topic in catalysis. This contribution reviews the state of the art in modulating the microstructure and surface chemistry of carbocatalysts by both bottom-up and top-down strategies and their use in the oxidative dehydrogenation (ODH) and direct dehydrogenation (DDH) of hydrocarbons including light alkanes and ethylbenzene to their corresponding olefins, important building blocks and chemicals like oxygenates. A concept of microstructure and surface chemistry tuning of the carbocatalyst for optimized catalytic performance and also for the fundamental understanding of the structure-performance relationship is discussed. We also highlight the importance and challenges in modulating the microstructure and surface chemistry of carbocatalysts in ODH and DDH reactions of hydrocarbons for the highly-efficient, energy-saving, and clean production of their corresponding olefins.

Key words: Carbocatalysis, Microstructure, Surface chemistry, Modulation, Dehydrogenation, Olefin

赵忠奎, 葛桂芳, 李伟作, 郭新闻, 王桂茹. 烷烃脱氢制烯烃用碳催化剂的微结构和表面化学调控研究进展[J]. 催化学报, 2016, 37(5): 644-670.

Zhongkui Zhao, Guifang Ge, Weizuo Li, Xinwen Guo, Guiru Wang. Modulating the microstructure and surface chemistry of carbocatalysts for oxidative and direct dehydrogenation: A review[J]. Chinese Journal of Catalysis, 2016, 37(5): 644-670.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(15)61065-8

https://www.cjcatal.com/CN/Y2016/V37/I5/644

参考文献

[1] J. J. H. B. Sattler, J. Ruiz-Martinez, E. Santillan-Jimenez, B. M. Weckhuysen, Chem. Rev., 2014, 114, 10613-10653.
[2] C. A. Carrero, R. Schlögl, I. E. Wachs, R. Schomaecker, ACS Catal., 2014, 4, 3357-3380.
[3] F. Cavani, F. Trifiro, Appl. Catal. A, 1995, 133, 219-239.
[4] W. Qi, D. S. Su, ACS Catal., 2014, 4, 3212-3218.
[5] D. Chen, A. Holmen, Z. J. Sui, X. G. Zhou, Chin. J. Catal., 2014, 35, 824-841.
[6] L. M. Madeira, M. F. Portela, Catal. Rev.-Sci. Eng., 2002, 44, 247-286.
[7] M. S. Chen, M. C. White, Science, 2010, 327, 566-571.
[8] Y. H. Li, S. Das, S. L. Zhou, K. Junge, M. Beller, J. Am. Chem. Soc., 2012, 134, 9727-9732.
[9] Q. S. Gao, C. Giordano, M. Antonietti, Angew. Chem. Int. Ed., 2012, 51, 11740-11744.
[10] D. R. Dreyer, C. W. Bielawski, Chem. Sci., 2011, 2, 1233-1240.
[11] C. L. Su, K. P. Loh, Acc. Chem. Res., 2013, 46, 2275-2285.
[12] X. Y. Sun, R. Wang, D. S. Su, Chin. J. Catal., 2013, 34, 508-523.
[13] A. Schaetz, M. Zeltner, W. J. Stark, ACS Catal., 2012, 2, 1267-1284.
[14] M. A. Patel, F. X. Luo, M. R. Khoshi, E. Rabie, Q. Zhang, C. R. Flach, R. Mendelsohn, E Garfunkel, M. Szostak, H. He, ACS Nano, 2016, 10, 2305-2315.
[15] W. Qi, W. Liu, B. S. Zhang, X. M. Gu, X. L. Guo, D. S. Su, Angew. Chem. Int. Ed., 2013, 52, 14224-14228.
[16] Y. J. Gao, G. Hu, J. Zhong, Z. J. Shi, Y. S. Zhu, D. S. Su, J. G. Wang, X. H. Bao, D. Ma, Angew. Chem. Int. Ed., 2013, 52, 2109-2113.
[17] S. P. Pitre, C. D. McTiernan, H. Ismaili, J. C. Scaiano, J. Am. Chem. Soc., 2013, 135, 13286-13289.
[18] Y. Wang, X. C. Wang, M. Antonietti, Angew. Chem. Int. Ed., 2012, 51, 68-89.
[19] J. Bedia, R. Ruiz-Rosas, J. Rodríguez-Mirasol, T. Cordero, AIChE J., 2010, 56, 1557-1568.
[20] P. J. Ji, H. S. Tan, X. Xu, W. Feng, AIChE J., 2010, 56, 3005-3011.
[21] K. Schwinghammer, B. Tuffy, M. B. Mesch, E. Wirnhier, C. Martineau, F. Taulelle, W. Schnick, J. Senker, B. V. Lotsch, Angew. Chem. Int. Ed., 2013, 52, 2435-2439.
[22] M. Younessi-Sinaki, F. Hamdullahpur, AIChE J., 2014, 60, 2228-2234.
[23] M. Shalom, S. Inal, C. Fettkenhauer, D. Neher, M. Antonietti, J. Am. Chem. Soc., 2013, 135, 7118-7121.
[24] Y. S. Jun, E. Z. Lee, X. C. Wang, W. H. Hong, G. D. Stucky, A. Thomas, Adv. Funct. Mater., 2013, 23, 3661-3667.
[25] Y. Zheng, Y. Jiao, Y. L. Ge, M. Jaroniec, S. Z. Qiao, Angew. Chem. Int. Ed., 2013, 52, 3110-3116.
[26] Y. Zhao, L. J. Yang, S. Chen, X. Z. Wang, Y. W. Ma, Q. Wu, Y. F. Jiang, W. J. Qian, Z. Hu, J. Am. Chem. Soc., 2013, 135, 1201-1204.
[27] K. Ai, Y. L. Liu, C. P. Ruan, L. H. Lu, G. Q. Lu, Adv. Mater., 2013, 25, 998-1003.
[28] H. Wang, K. Sun, F. Tao, D. J. Stacchiola, Y. H. Hu, Angew. Chem. Int. Ed., 2013, 52, 9210-9214.
[29] I. V. Lightcap, P. V. Kamat, Acc. Chem. Res., 2013, 46, 2235-2243.
[30] R. Schlögl, Adv. Catal., 2013, 56, 103-185.
[31] S. Navalon, A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Chem. Rev., 2014, 114, 6179-6212.
[32] Y. Wang, X. C. Wang, M. Antonietti, Angew. Chem. Int. Ed., 2012, 51, 68-89.
[33] L. R. Radovic, C. Mora-Vilches, A. J. A. Salgado-Casanova, Chin. J. Catal., 2014, 35, 792-797.
[34] C. C. Huang, C. Li, G. Q. Shi, Energy Environ. Sci., 2012, 5, 8848-8868.
[35] X. K. Kong, C. L. Chen, Q. W. Chen, Chem. Soc. Rev., 2014, 43, 2841-2857.
[36] D. W. Wang, D. S. Su, Energy Environ. Sci., 2014, 7, 576-591.
[37] C. Ampelli, S. Perathoner, G. Centi, Chin. J. Catal., 2014, 35, 783-791.
[38] X. Y. Sun, R. Wang, D. S. Su, Chin. J. Catal., 2013, 34, 508.
[39] D. S. Su, J. Zhang, B. Frank, A. Thomas, X. C. Wang, J. Paraknowitsch, R. Schlögl, ChemSusChem, 2010, 3, 169-180.
[40] J. J. Vilatela, D. Eder, ChemSusChem, 2012, 5, 456-478.
[41] J. Zhu, A. Holmen, D. Chen, ChemCatChem, 2013, 5, 378-401.
[42] D. S. Su, S. Perathoner, G. Centi, Chem. Rev., 2013, 113, 5782-5816.
[43] A. Guerrero-Ruiz, I. Rodriguez-Ramos, Carbon, 1994, 32, 23-29.
[44] M. F. R. Pereira, J. M. Orfao, J. L. Figueiredo, Appl. Catal. A, 1999, 184, 153-160.
[45] H. Ba, S. Podila, Y. Liu, X. Mu, J.-M. Nhut, V. Papaefthimiou, S. Zafeiratos, P. Granger, C. Pham-Huu, Catal. Today, 2015, 249, 167-175.
[46] J. Zhang, X. Liu, R. Blume, A. Zhang, R. Schlögl and D. S. Su, Science, 2008, 322, 73-77.
[47] J. Zhang, D. S. Su, R. Blume, R. Schlögl, R. Wang, X. Yang, A. Gajovi?, Angew. Chem. Int. Ed., 2010, 49, 8640-8644.
[48] S. J. Guo, S. D. Zhang, S. Sun, Angew. Chem. Int. Ed., 2013, 52, 8526-8544.
[49] I. Lee, F. Delbecq, R. Morales, M. A. Albiter, F. Zaera, Nat. Mater., 2009, 8, 132-138.
[50] R. Krishna, Chem. Soc. Rev., 2012, 41, 3099-3118.
[51] F. Tao, Chem. Soc. Rev., 2012, 41, 7977-7979.
[52] Y. Li, W. Shen, Chem. Soc. Rev., 2014, 43, 1543-1574.
[53] W. X. Huang, Y. X. Gao, Catal. Sci. Technol., 2014, 4, 3772-3784.
[54] D. F. van der Vliet, C. Wang, D. Tripkovic, D. Strmcnik, X. F. Zhang, M. K. Debe, R. T. Atanasoski, N. M. Markovic, V. R. Stamenkovic, Nat. Mater., 2012, 11, 1051-1058.
[55] J. L. Gong, Chem. Rev., 2011, 112, 2987-3054.
[56] C. C. Lin, Y. Guo, J. Vela, ACS Catal., 2015, 5, 1037-1044.
[57] J. G. Yu, J. X. Low, W. Xiao, P. Zhou, M. Jaroniec, J. Am. Chem. Soc., 2014, 136, 8839-8842.
[58] Y. Zhao, C. Eley, J. P. Hu, J. S. Foord, L. Ye, H. W. He, S. C. E. Tsang, Angew. Chem. Int. Ed., 2012, 51, 3846-3849.
[59] C. L. Chen, J. Zhang, B. S. Zhang, C. L. Yu, F. Peng, D. S. Su, Chem. Commun., 2013, 49, 8151-8153.
[60] X. D. Hu, Y. T. Wu, H. R. Li, Z. B. Zhang, J. Phys. Chem. C, 2010, 114, 9603-9607.
[61] S. Mao, B. Li, D. S. Su, J. Mater. Chem. A, 2014, 2, 5287-5294.
[62] H. Xie, Z. L. Wu, S. H. Overbury, C. D. Liang, V. Schwartz, J. Catal., 2009, 267, 158-166.
[63] R. Huang, H. Y. Liu, B. S. Zhang, X. Y. Sun, C. H. Liang, D. S. Su, B. N. Zong, J. F. Rong, ChemSusChem, 2014, 7, 3476-3482.
[64] G. K. P. Dathar, Y. T. Tsai, K. Gierszal, Y. Xu, C. D. Liang, A. J. Rondinone, S. H. Overbury, V. Schwartz, ChemSusChem, 2014, 7, 483-491.
[65] R. C. Rao, M. Yang, Q. Ling, C. S. Li, Q. Y. Zhang, H. X. Yang, A. M. Zhang, Catal. Sci. Technol., 2014, 4, 665-671.
[66] I. Pelech, O. S. G. P. Soares, M. F. R. Pereira, J. L. Figueiredo, Catal Today, 2015, 249, 176-183.
[67] G. Mestl, N. I. Maksimova, N. Keller, V. V. Roddatis, R. Schlögl, Angew. Chem. Int. Ed., 2001, 40, 2066-2068.
[68] T. J. Zhao, W. Z. Sun, X. Y. Gu, M. Rønning, D. Chen, Y. C. Dai, W. K. Yuan, A. Holmen, Appl. Catal. A, 2007, 323, 135-146.
[69] P. Niebrzydowska, R. Janus, P. Ku?trowski, S. Jarczewski, A. Wach, A. M. Silvestre-Albero, F. Rodríguez-Reinoso, Carbon, 2013, 64, 252-261.
[70] J. J. Delgado, X.-W. Chen, B. Frank, D. S. Su, R. Schlögl, Catal today, 2012, 186, 93-98.
[71] B. Frank, J. Zhang, R. Blume, R. Schlögl, D. S. Su, Angew. Chem. Int. Ed., 2009, 48, 6913-6917.
[72] J. Zhang, D. Su, A. Zhang, D. Wang, R. Schlögl, C. Hébert, Angew. Chem. Int. Ed., 2007, 119, 7319-7323.
[73] W. Qi, W. Liu, B. S. Zhang, X. M. Gu, X. L. Guo, D. S. Su, Angew. Chem. Int. Ed., 2013, 52, 14224-14228.
[74] S. B. Tang, Z. X. Cao, Phys. Chem. Chem. Phys., 2012, 14, 16558-16565.
[75] X. Y. Sun, B. Li, D. S. Su, Chem. Commun., 2014, 50, 11016-11019.
[76] X. Y. Sun, R. Wang, B. S. Zhang, R. Huang, X. Huang, D. S. Su, T. Chen, C. X. Miao, W. M. Yang, ChemCatChem, 2014, 6, 2270-2275.
[77] X. Y. Sun, Y. X. Ding, B. S. Zhang, R. Huang, D. Chen, D. S. Su, ACS Catal., 2015, 5, 2436-2444.
[78] X. Y. Sun, Y. X. Ding, B. S. Zhang, R. Huang, D. S. Su, Chem. Commun., 2015, 51, 9145-9148.
[79] B. Frank, S. Wrabetz, O. V. Khavryuchenko, R. Blume, A. Trunschke, R. Schlögl, ChemPhysChem, 2011, 12, 2709-2713.
[80] A. M. Zheng, Y. Y. Chu, S. H. Li, D. S. Su, F. Deng, Carbon, 2014, 77, 122-129.
[81] L. Liu, Q. F. Deng, B. Agula, X. Zhao, T. Z. Ren, Z. Y. Yuan, Chem. Commun., 2011, 47, 8334-8336.
[82] R. Wang, X. Y. Sun, B. S. Zhang, X. Y. Sun, D. S. Su, Chem. Eur. J., 2014, 20, 6324-6331.
[83] Z. K. Zhao, Y. T. Dai, G. F. Ge, G. R. Wang, Chem. Eur. J, 2015, 21, 8004-8009.
[84] Z. K. Zhao, Y. T. Dai, G. F. Ge, G. R. Wang, AIChE J., 2015, 61, 2543-2561.
[85] Z. Zhao, Y. T. Dai, G. F. Ge, Catal. Sci. Technol., 2015, 5, 1548-1557.
[86] T. T. Thanh, H. Ba, L. Truong-Phuoc, J.-M. Nhut, O. Ersen, D. Begin, I. Janowska, D. L. Nguyen, P. Granger, C. Pham-Huu, J. Mater. Chem. A, 2014, 2, 11349-11357.
[87] Z. K. Zhao, Y. T. Dai, J. Mater. Chem. A, 2014, 2, 13442-13451.
[88] Z. K. Zhao, Y. T. Dai, G. F. Ge, G. R. Wang, ChemCatChem, 2015, 7, 1135-1144.
[89] Z. K. Zhao, Y. T. Dai, J. H. Lin, G. R. Wang, Chem. Mater., 2014, 26, 3151-3161.
[90] L. Liu, Q. F. Deng, B. Agula, T. Z. Ren, Y.-P. Liu, B. Zhaorigetu, Z. Y. Yuan, Catal Today, 2012, 186, 35-41.
[91] L. Liu, Q. F. Deng, Y. P. Liu, T. Z. Ren, Z. Y. Yuan, Catal. Commun., 2011, 16, 81-85.
[92] X. Liu, D. S. Su, R. Schlögl, Carbon, 2008, 46, 547-549.
[93] X. Liu, B. Frank, W. Zhang, T. P. Cotter, R. Schlögl, D. S. Su, Angew. Chem. Int. Ed., 2011, 50, 3318-3322.
[94] D. Y. Jung, H. G. Jang, G. R. Kim, G. J. Kim, Res. Chem. Intermed., 2011, 37, 1145-1156.
[95] N. Keller, N. I. Maksimova, V. V. Roddatis, M. Schur, G. Mestl, Y. V. Butenko, V. L. Kuznetsov, R. Schlögl, Angew. Chem. Int. Ed., 2002, 41, 1885-1888.
[96] D. S. Su, N. Maksimova, J. J. Delgado, N. Keller, G. Mestl, M. J. Ledoux, R. Schlögl, Catal. Today, 2005, 102, 110-114.
[97] D. S. Su, J. J. Delgado, X. Liu, D. Wang, R. Schlögl, L. F. Wang, Z. Zhang, Z. Shan, F. S. Xiao, Chem. Asian J., 2009, 4, 1108-1113.
[98] V. Zarubina, H. Talebi, C. Nederlof, F. Kapteijn, M. Makkee, I. Melián-Cabrera, Carbon, 2014, 77, 329-340.
[99] M. F. R. Pereira, J. L. Figueiredo, J. J. Órfão, P. Serp, P. Kalck, Y. Kihn, Carbon, 2004, 42, 2807-2813.
[100] J. W. Diao, H. W. Liu, J. Wang, Z. B. Feng, T. Chen, C. X. Miao, W. M. Yang, D. S. Su, Chem. Commun., 2015, 51, 3423-3425.
[101] Z. J. Sui, T. J. Zhao, J. H. Zhou, P. Li, Y. C. Dai, Chin. J. Catal., 2005, 26, 521-526.
[102] M. F. R. Pereira, J. J. M. Órfão, J. L. Figueiredo, Carbon, 2002, 40, 2393-2401.
[103] I. Gniot, P. Kirszensztejn, M. Koz?owski, Appl. Catal. A, 2009, 362, 67-74.
[104] M. F. R. Pereira, J. J. M. Órfão, J. L.Figueiredo, Colloids Surf. A, 2004, 241, 165-171.
[105] A. Malaika, P. Rechnia, B. Krzy?yńska, M. Koz?owski, Microporous Mesoporous Mater., 2012, 163, 300-306.
[106] C. D. Liang, H. Xie, V. Schwartz, J. Howe, S. Dai, S. H. Overbury, J. Am. Chem. Soc., 2009, 131, 7735-7741.
[107] L. F. Wang, J. J. Delgado, B. Frank, Z. Zhang, Z. C. Shan, D. S. Su, F. S. Xiao, ChemSusChem, 2012, 5, 687-693.
[108] N. Xiao, Y. Zhou, Z. Ling, Z. B. Zhao, J. S. Qiu, Carbon, 2013, 60, 514-522.
[109] L. F. Wang, J. Zhang, D. S. Su, Y. Y. Ji, X. J. Cao, F. S. Xiao, Chem. Mater., 2007, 19, 2894-2897.
[110] J. J. Delgado, X. W. Chen, D. S. Su, S. B. A. Hamid, R. Schlögl, J. Nanosci. Nanotechnol., 2007, 7, 3495-3501.
[111] H. Yuan, Z. H. Sun, H. Y. Liu, B. S. Zhang, C. L. Chen, H. H. Wang, Z. M. Yang, J. S. Zhang, F. Wei, D. S. Su, ChemCatChem, 2013, 5, 1713-1717.
[112] J. J. Delgado, D. S. Su, G. Rebmann, N. Keller, A. Gajovic, R. Schlögl, J. Catal., 2006, 244, 126-129.
[113] J. Zhang, R. Wang, E. Z. Liu, X. F. Gao, Z. H. Sun, F. S. Xiao, F. Girgsdies, D. S. Su, Angew. Chem. Int. Ed., 2012, 51, 7581-7585.
[114] P. Li, T. Li, J. H. Zhou, Z. J. Sui, Y. C. Dai, W. K. Yuan, D. Chen, Microporous Mesoporous Mater., 2006, 95, 1-7.
[115] J. Wang, H. Y. Liu, J. Y. Diao, X. M. Gu, H. H. Wang, J. F. Rong, B. N. Zong, D. S. Su, J. Mater. Chem. A, 2015, 3, 2305-2313.
[116] Y. Ito, H. J. Qiu, T. Fujita, Y. Tanabe, K. Tanigaki, M. W. Chen, Adv. Mater., 2014, 26, 4145-4150.
[117] K. P. Gong, F. Du, Z. H. Xia, M. Durstock, L. M. Dai, Science, 2009, 323, 760-764.
[118] X. H. Li, M. Antonietti, Chem. Soc. Rev., 2013, 42, 6593-6604.
[119] H. B. Wang, T. Maiyalagan, X. Wang, ACS Catal., 2012, 2, 781-794.
[120] S. Zhang, P. Kang, S. Ubnoske, M. K. Brennaman, N. Song, R. L. House, J. T. Glass, T. J. Meyer, J. Am. Chem. Soc., 2014, 136, 7845-7848.
[121] M. Park, J. Ryu, Y. Kim, J. Cho, Energy Environ. Sci., 2014, 7, 3727-3735.
[122] L. F. Velasco, J. C. Lima, C. Ania, Angew. Chem. Int. Ed., 2014, 53, 4146-4148.
[123] K. N. Wood, R. O'Hayre, S. Pylypenko, Energy Environ. Sci., 2014, 7, 1212-1249.
[124] W. J. Lee, U. N. Maiti, J. M. Lee, J. Lim, T. H. Han, S. O. Kim, Chem. Commun., 2014, 50, 6818-6830.
[125] Z. H. Sheng, L. Shao, J. J. Chen, W. J. Bao, F. B. Wang, X. H. Xia, ACS Nano, 2011, 5, 4350-4358.
[126] J. T. Jin, X. G. Fu, Q. Liu, Y. R. Liu, Z. Y. Wei, K. X. Niu, J. Y. Zhang, ACS Nano, 2013, 7, 4764-4773.
[127] Z. Y. Lin, G. Waller, Y. Liu, M. L. Liu, C. P. Wong, Adv. Energy Mater., 2012, 2, 884-888.
[128] Z. K. Zhao, Y. T. Dai, G. F. Ge, X. W. Guo, G. R. Wang, Phys. Chem. Chem. Phys., 2015, 17, 18895-18899.
[129] Z. K. Zhao, Y. T. Dai, G. F. Ge, X. W. Guo, G. R. Wang, RSC Adv., 2015, 5, 53095-53099.
[130] Z. K. Zhao, Y. T. Dai, G. F. Ge, X. W. Guo, G. R. Wang, Green Chem., 2015, 17, 3723-3727.
[131] Z. K. Zhao, Y. T. Dai, G. F. Ge, Q. Mao, Z. M. Rong, G. R. Wang, ChemCatChem, 2015, 7, 1070-1077.
[132] C. Duong-Viet, H. Ba, Y. F. Liu, L. Truong-Phuoc, J. M. Nhut, C. Pham-Huu, Chin. J. Catal., 2014, 35, 906-913.
[133] H. Ba, Y. F. Liu, X. K. Mu, W. H. Doh, J. M. Nhut, P. Granger, C. Pham-Huu, Appl. Catal. A, 2015, 499, 217-226.
[134] H. Y. Liu, J. Y. Diao, Q. Wang, S. Y. Gu, T. Chen, C. X. Miao, W. M. Yang, D. S. Su, Chem. Commun., 2014, 50, 7810-7812.
[135] X. Y. Sun, R. Wang, B. S. Zhang, R. Huang, X. Huang, D. S. Su, T. Chen, C. X. Miao, W. M. Yang, ChemCatChem, 2014, 6, 2270-2275.
[136] J. J. Delgado, X. Chen, J. P. Tessonnier, M. E. Schuster, E. Del Rio, R. Schlögl, D. S. Su, Catal. Today, 2010, 150, 49-54.
[137] R. Huang, C. H. Liang, D. S. Su, B. Zong, J. F. Rong, Catal. Today, 2015, 249, 161-166.
[138] A. Rinaldi, J. Zhang, B. Frank, D. S. Su, S. B. Abd Hamid, R. Schlögl, ChemSusChem, 2010, 3, 254-260.
[139] M. F. R. Pereira, J. J. M. Orfao, J. L. Figueiredo, Appl. Catal. A, 1999, 184, 153-160.
[140] J. d. J. D. Velásquez, L. M. C. Suárez, J. L. Figueiredo, Appl. Catal. A, 2006, 311, 51-57.
[141] N. V. Qui, P. Scholz, T. F. Krech, T. Keller, K. Pollok, B. Ondruschka, Catal. Commun., 2011, 12, 464-469.
[142] D. S. Su, N. I. Maksimova, G. Mestl, V. L. Kuznetsov, V. Keller, R. Schlögl, N. Keller, Carbon, 2007, 45, 2145-2151.
[143] P. Janus, R. Janus, P. Ku?trowski, S. Jarczewski, A. Wach, A. M. Silvestre-Albero, F. Rodríguez-Reinoso, Catal. Today, 2014, 235, 201-209.
[144] Z. J. Sui, J. H. Zhou, Y. C. Dai, W. K. Yuan, Catal. Today, 2005, 106, 90-94.
[145] Y. Marco, L. Roldán, E. Muñoz, E. García-Bordejé, ChemSusChem, 2014, 7, 2496-2504.
[146] V. Schwartz, H. Xie, H. M. Meyer, S. H. Overbury, C. D. Liang, Carbon, 2011, 49, 659-668.
[147] J. Y. Diao, H. Y. Liu, Z. B. Feng, Y. J.Zhang, T. Chen, C. X. Miao, W. M. Yang, D. S. Su, Catal. Sci. Technol., 2015, 5, 4950-4953.
[148] Z. K. Zhao, W. Z. Li, Y. T. Dai, G. F. Ge, X. W. Guo, G. R. Wang, ACS Sust. Chem. Eng., 2015, 3, 3355-3364.
[149] H. Ba, L. Truong-Phuoc, Y. F. Liu, C. Duong-Viet, J. M. Nhut, L. Nguyen-Dinh, P. Granger, C. Pham-Huu, Carbon, 2016, 96, 1060-1069.

烷烃脱氢制烯烃用碳催化剂的微结构和表面化学调控研究进展

Modulating the microstructure and surface chemistry of carbocatalysts for oxidative and direct dehydrogenation: A review

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	孙嘉辰, 陈赛, 付东龙, 王伟, 王显辉, 孙国栋, 裴春雷, 赵志坚, 巩金龙. 氧扩散与表面反应在VO_x-Ce_1‒_xZr_xO₂催化丙烷脱氢反应中的影响[J]. 催化学报, 2023, 52(9): 217-227.
[2]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[3]	肖汉至, 于博, 颜思顺, 章炜, 李茜茜, 鲍莹, 罗书平, 叶剑衡, 余达刚. 可见光催化二氧化碳参与非活化烯烃1,3-双羧基化反应[J]. 催化学报, 2023, 50(7): 222-228.
[4]	李孜孜, 王嘉蔚, 黄衍钧, 欧阳钢锋. 钴(II)酞菁全氟化策略用于提升非贵金属体系中光催化还原CO₂性能[J]. 催化学报, 2023, 49(6): 160-167.
[5]	李显泉, 庞纪峰, 赵于嘉, 吴鹏飞, 于文广, 颜佩芳, 苏扬, 郑明远. Cu-MFI催化剂上Cu^δ⁺催化乙醇脱氢制乙醛[J]. 催化学报, 2023, 49(6): 91-101.
[6]	张功, 张炜松, 王小雨, 杨洋, 季定纬, 万伯顺, 陈庆安. 镍催化杂芳烃的非天然戊烯基化及环状单萜化反应[J]. 催化学报, 2023, 49(6): 123-131.
[7]	刘培功, 林铁军, 郭磊, 刘晓哲, 龚坤, 尧泰真, 安芸蕾, 钟良枢. 调控Co₂C局域浸润环境实现高碳效合成气直接制烯烃[J]. 催化学报, 2023, 48(5): 150-163.
[8]	李金鹏, 陈洁, 郑庆舒, 屠波, 涂涛. 配位组装构筑的磁性核壳复合材料促进CO₂高值催化转化[J]. 催化学报, 2023, 48(5): 258-266.
[9]	邢亚楠, 康磊磊, 马静远, 蒋齐可, 苏杨, 张盛鑫, 徐晓燕, 李林, 王爱琴, 刘智攀, 马思聪, 刘晓艳, 张涛. Sn₁Pt单原子合金催化剂在丙烷脱氢反应中的应用[J]. 催化学报, 2023, 48(5): 164-174.
[10]	解志鹏, 杨修贝, 张沛, 柯夏婷, 袁昕, 翟黎鹏, 王文滨, 秦娜, 崔乘幸, 屈凌波, 陈雄. 具有可控载流子动力学的烯烃连接的共价有机框架用于高效太阳能光催化制氢[J]. 催化学报, 2023, 47(4): 171-180.
[11]	林杉帆, 郅玉春, 张文娜, 袁小帅, 张成伟, 叶茂, 徐舒涛, 魏迎旭, 刘中民. 氢转移反应对分子筛催化甲醇和二甲醚动态自催化反应历程的贡献: 深入理解甲醛的生成机理和作用机制[J]. 催化学报, 2023, 46(3): 11-27.
[12]	焦龙, 江海龙. 金属有机框架材料在催化领域的研究现状与展望[J]. 催化学报, 2023, 45(2): 1-5.
[13]	张龙康, 马跃, 刘昌呈, 万志鹏, 翟承伟, 王新, 徐浩, 关业军, 吴鹏. 脱金属-还原策略诱导创制高分散PtZn合金催化剂用于丙烷脱氢反应[J]. 催化学报, 2023, 55(12): 241-252.
[14]	万凯, 罗江水, 刘文博, 张婷, Jordi Arbiol, 张漩, Palaniappan Subramanian, 傅志勇, Jan Fransaer. 金属有机框架衍生的阳离子调控金属硫化物增强析氧反应活性[J]. 催化学报, 2023, 54(11): 290-297.
[15]	汪晋, 萧祖耀, 徐梽川, 任肖. 烯烃的选择性电化学氧化: 研究进展与前景[J]. 催化学报, 2023, 53(10): 34-51.