纳米ZSM-5用于石脑油催化裂化的最新进展

doi:10.1016/S1872-2067(15)61091-9

催化学报 ›› 2016, Vol. 37 ›› Issue (5): 671-680.DOI: 10.1016/S1872-2067(15)61091-9

纳米ZSM-5用于石脑油催化裂化的最新进展

Shayan Miar Alipour^a,b

a 阿米尔卡比尔理工大学(德黑兰理工学院)化学工程学院, 德黑兰, 伊朗;
b 新南威尔士大学颗粒和催化研究实验室, 新南威尔士悉尼 2052, 澳大利亚

收稿日期:2016-02-04 修回日期:2016-03-31 出版日期:2016-04-26 发布日期:2016-04-26
通讯作者: Shayan Miar Alipour

Recent advances in naphtha catalytic cracking by nano ZSM-5: A review

Shayan Miar Alipour^a,b

a Faculty of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), P.O. Box 15875-4413, Hafez Ave., Tehran, Iran;
b Particles and Catalysis Research Laboratory, University of New South Wales, UNSW Sydney, NSW 2052, Australia

Received:2016-02-04 Revised:2016-03-31 Online:2016-04-26 Published:2016-04-26
Contact: Shayan Miar Alipour

摘要/Abstract

摘要：

综述了纳米ZSM-5在石脑油催化裂解中的应用. 比较了纳米ZSM-5和毫米级ZSM-5对产物选择性、反应转化率和催化剂寿命的影响. 纳米ZSM-5的应用不仅延长了催化剂寿命, 而且表现出更稳定的轻质烯烃选择性. 讨论了反应条件, 如温度和进料对纳米ZSM-5催化性能的影响, 发现高温和线式烷烃作为进料时可提高轻质烯烃的选择性和反应转化率.

关键词: 纳米ZSM-5, 晶粒大小, 石脑油裂解, 轻质烯烃, 反应参数

Abstract:

This review discussed the use of nano ZSM-5 in naphtha catalytic cracking. The impact of nano ZSM-5 on product selectivity, reaction conversion and catalyst lifetime were compared with micro-sized ZSM-5. The application of nano ZSM-5 not only increased the catalyst lifetime, but also gave more stability for light olefins selectivity. The effects of the reaction parameters of temperature and feedstock on the performance of nano ZSM-5 were investigated, and showed that high temperature and linear alkanes as feedstock improved light olefin selectivity and conversion.

Key words: Nano ZSM-5, Crystal size, Naphtha cracking, Light olefins, Reaction parameters

Shayan Miar Alipour . 纳米ZSM-5用于石脑油催化裂化的最新进展[J]. 催化学报, 2016, 37(5): 671-680.

Shayan Miar Alipour . Recent advances in naphtha catalytic cracking by nano ZSM-5: A review[J]. Chinese Journal of Catalysis, 2016, 37(5): 671-680.

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纳米ZSM-5用于石脑油催化裂化的最新进展

Recent advances in naphtha catalytic cracking by nano ZSM-5: A review

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