铂族金属催化剂低温CO氧化研究近期进展

doi:10.1016/S1872-2067(16)62513-5

催化学报 ›› 2016, Vol. 37 ›› Issue (11): 1805-1813.DOI: 10.1016/S1872-2067(16)62513-5

铂族金属催化剂低温CO氧化研究近期进展

林坚, 王晓东, 张涛

中国科学院大连化学物理研究所, 催化基础国家重点实验室, 辽宁大连 116023

收稿日期:2016-06-25 修回日期:2016-07-30 出版日期:2016-11-25 发布日期:2016-11-25
通讯作者: Tao Zhang,Tel:+86-411-84379015; Fax:+86-411-84691570; E-mail:taozhang@dicp.ac.cn;Xiaodong Wang,Tel:+86-411-84379680; Fax:+86-411-84691570; E-mail:xdwang@dicp.ac.cn
基金资助:
国家自然科学基金（21076211，21203181，21576251，21676269）；中国科学院B类战略性先导科技专项（XDB17020100）；科技部重大研发计划2016YFA0202801；辽宁省科技厅院士基金2015020086-101.

Recent progress in CO oxidation over Pt-group-metal catalysts at low temperatures

Jian Lin, Xiaodong Wang, Tao Zhang

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, Liaoning, China

Received:2016-06-25 Revised:2016-07-30 Online:2016-11-25 Published:2016-11-25
Contact: Tao Zhang,Tel:+86-411-84379015; Fax:+86-411-84691570; E-mail:taozhang@dicp.ac.cn;Xiaodong Wang,Tel:+86-411-84379680; Fax:+86-411-84691570; E-mail:xdwang@dicp.ac.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21076211, 21203181, 21576251, 21676269), the "Strategic Priority Research Program" of the Chinese Academy of Sciences (XDB17020100), the National Key projects for Fundamental Research and Development of China (2016YFA0202801) and Department of Science and Technology of Liaoning Province under contract of 2015020086-101.

摘要/Abstract

摘要：

CO氧化可能是多相催化领域最常见的反应，它不仅能作为探针反应研究催化剂结构、反应活性位等，而且在诸多实际过程如空气净化、汽车尾气污染物控制、燃料电池所用氢源净化等扮演重要角色.最早的CO氧化催化剂为霍加拉特剂，其组分主要为CuO与MnO₂混合氧化物，然而在实际应用过程中存在低温活性低、吸湿易失活等缺点.1987年，Haruta等发现湿化学法制备的氧化物负载Au催化剂表现出非常高的低温CO氧化活性及耐水稳定性，其Au粒子以纳米尺度分散，进而引发了催化研究领域的“淘金热”及纳米催化研究热潮.而CO氧化通常作为考察Au催化剂结构性质的探针反应，也成为考核其它金属催化剂是否具有高活性的判据之一.
Pt族金属上CO氧化反应从Langmuir等研究开始至今已有100多年，然而低温下该金属催化剂活性与Au催化剂相比要低一个数量级.本质原因为Pt族金属上CO吸附较强，O₂吸附与活化受到抑制，而该步骤被认为是CO氧化的速控步，因而表现出较低的催化活性.通常Pt族金属催化剂需要100℃以上CO才能脱附，O₂进而得以吸附.目前研究人员采取多种策略，其基本原则为削弱Pt族金属上CO吸附强度或者提供其它活性位供O₂吸附与活化.本综述将概括近十年来Pt族金属催化剂CO氧化研究进展，主要总结室温甚至超低温条件下的研究成果.
高活性CO氧化催化剂主要是通过采用可还原氧化物为载体或助剂，或者改变催化剂表面性质如使表面富OH基物种来形成.Au催化剂的研究发现，改变金属粒子尺寸极有可能获得不同寻常的催化性能，而常规的Pt族金属催化剂研究主要是在纳米尺度.近期人们发现逐渐减小Pt族金属粒子尺寸，从纳米到亚纳米甚至单原子时，其电荷状态逐渐呈正价形式，这有利于削弱其CO吸附强度.此外，可通过增强金属载体间的相互作用，改变金属载体接触方式，如从核壳到交叉结联结构，构筑出更多的金属载体界面，使得O₂更容易吸附与活化或稳定更多的OH基物种进而在此界面与吸附的CO反应.
伴随着表征技术的发展，CO氧化机理的认识也更加深入，这给催化剂的设计带来更多新的思路.（1）改变CO吸附活化位，将CO吸附活化位从金属转移到载体上，从而大大降低CO吸附强度，活化的CO物种在反应过程中容易溢流到金属载体界面处，这甚至有利于超低温度下（-100℃左右）CO氧化.（2）改变O₂活化形式.O₂通常在Pt族金属上容易以解离氧原子形式存在，通过改变载体、金属载体界面性质使得O₂以分子氧形式活化，如形成超氧或过氧物种，这有利于降低CO氧化的活化能垒，进而提高其低温甚至超低温下CO氧化活性.今后，设计并合成出在超低温度下能够氧化CO的Pt族金属催化剂将成为CO氧化催化剂研究的重要方向之一.

关键词: 一氧化碳氧化, 金, 铂族金属, 低温, 尺寸效应, 界面

Abstract:

CO oxidation is probably the most studied reaction in heterogeneous catalysis. This reaction has become a hot topic with the discovery of nanogold catalysts, which are active at low temperatures (at or below room temperature). Au catalysts are the benchmark for judging the activities of other metals in CO oxidation. Pt-group metals (PGMs) that give comparable performances are of particu-lar interest. In this mini-review, we summarize the advances in various PGM (Pt, Pd, Ir, Rh, Ru) catalysts that have high catalytic activities in low-temperature CO oxidation arising from reducible supports or the presence of OH species. The effects of the size of the metal species and the im-portance of the interface between the metal and the reducible support are covered and discussed in terms of their promotional role in CO oxidation at low temperatures.

Key words: Carbon monoxide oxidation, Gold, Platinum group metal, Low temperature, Size effect, Interface

林坚, 王晓东, 张涛. 铂族金属催化剂低温CO氧化研究近期进展[J]. 催化学报, 2016, 37(11): 1805-1813.

Jian Lin, Xiaodong Wang, Tao Zhang. Recent progress in CO oxidation over Pt-group-metal catalysts at low temperatures[J]. Chinese Journal of Catalysis, 2016, 37(11): 1805-1813.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(16)62513-5

https://www.cjcatal.com/CN/Y2016/V37/I11/1805

参考文献

[1] H. J. Freund, G. Meijer, M. Scheffler, R. Schlögl, M. Wolf, Angew. Chem. Int. Ed., 2011, 50, 10064-10094.
[2] M. V. Twigg, Appl. Catal. B, 2007, 70, 2-15.
[3] K. Liu, A. Q. Wang, T. Zhang, ACS Catal., 2012, 2, 1165-1178.
[4] A. B. Lamb, W. C. Bray, J. C. W. Frazer, J. Ind. Eng. Chem., 1920, 12, 213-221.
[5] D. R. Merrill, C. C. Scalione, J. Am. Chem. Soc., 1921, 43, 1982-2002.
[6] C. Yoon, D. L. Cocke, J. Catal., 1988, 113, 267-280.
[7] X. W. Xie, Y. Li, Z. Q. Liu, M. Haruta, W. J. Shen, Nature, 2009, 458, 746-749.
[8] M. Haruta, T. Kobayashi, H. Sano, N. Yamada, Chem. Lett., 1987, 405-408.
[9] M. Haruta, N. Yamada, T. Kobayahsi, S. Iijima, J. Catal., 1989, 115, 301-309.
[10] M. Haruta, Nature, 2005, 437, 1098-1099.
[11] S. Golunski, Platinum Met. Rev., 2013, 57, 82-84.
[12] I. Langmuir, Trans. Faraday Soc., 1922, 17, 621-654.
[13] D. Widmann, R. J. Behm, Acc. Chem. Res., 2014, 47, 740-749.
[14] A. D. Allian, K. Takanabe, K. L. Fujdala, X. H. Hao, T. J. Truex, J. Cai, C. Buda, M. Neurock, E. Iglesia, J. Am. Chem. Soc., 2011, 133, 4498-4517.
[15] W. D. Michalak, J. M. Krier, S. Alayoglu, J. Y. Shin, K. An, K. Komvopoulos, Z. Liu, G. A. Somorjai, J. Catal., 2014, 312, 17-25.
[16] B. T. Qiao, L. Q. Liu, J. Zhang, Y. Q. Deng, J. Catal., 2009, 261, 241-244.
[17] L. Q. Liu, F. Zhou, L. G. Wang, X. J. Qi, F. Shi, Y. Q. Deng, J. Catal., 2010, 274, 1-10.
[18] L. Q. Liu, B. T. Qiao, Y. D. He, F. Zhou, B. Q. Yang, Y. Q. Deng, J. Catal., 2012, 294, 29-36.
[19] X.L. Tang, B.C. Zhang, Y. Li, Q. Xin, W.J. Shen, Chin. J. Catal., 2005, 26, 1-3.
[20] W. S. Zhang, A. Q. Wang, L. Li, X. D. Wang, T. Zhang, Catal. Today, 2008, 131, 457-463.
[21] K. Liu, A. Q. Wang, W. S. Zhang, J. H. Wang, Y. Q. Huang, J. Y. Shen, T. Zhang, J. Phys. Chem. C, 2008, 114, 8533-8541.
[22] Y. N. Sun, Z. H. Qin, M. Lewandowski, E. Carrasco, M. Sterrer, S. Shaikhutdinov, H. J. Freund, J. Catal., 2009, 266, 359-368.
[23] Q. Fu, W. X. Li, Y. X. Yao, H. Y. Liu, H. Y. Su, D. Ma, X. K. Gu, L. M. Chen, Z. Wang, H. Zhang, B. Wang, X. H. Bao, Science, 2010, 328, 1141-1144.
[24] P. Li, D. E. Miser, S. Rabiei, R. T. Yadav, M. R. Hajaligol, Appl. Catal. B, 2003, 43, 151-162.
[25] J. Lin, B. T. Qiao, J. Y. Liu, Y. Q. Huang, A. Q. Wang, L. Li, W. S. Zhang, L. F. Allard, X. D. Wang, T. Zhang, Angew. Chem. Int. Ed., 2012, 51, 2920-2924.
[26] J. Lin, B. T. Qiao, L. Li, H. L. Guan, C. Y. Ruan, A. Q. Wang, W. S. Zhang, X. D. Wang, T. Zhang, J.Catal., 2014, 319,142-149.
[27] H. L. Guan, J. Lin, L. Li, X. D. Wang, T. Zhang, Appl. Catal. B, 2016, 184, 299-308.
[28] B. T. Qiao, A. Q. Wang, L. Li, Q. Q. Lin, H. S. Wei, J. Y. Liu, T. Zhang, ACS Catal., 2014, 4, 2113-2117.
[29] B. T. Qiao, J. Lin, L. Li, A. Q. Wang, J. Y. Liu, T. Zhang, ChemCatChem, 2014, 6, 547-554.
[30] B. T. Qiao, A. Q. Wang, X. F. Yang, L. F. Allard, Z. Jiang, Y. T. Cui, J. Y. Liu, J. Li, T. Zhang, Nat. Chem.,2011, 3, 634-641.
[31] J. Lin, A. Q. Wang, B. T. Qiao, X. Y. Liu, X. F. Yang, X. D. Wang, J. X.Liang, J. Li, J. Y. Liu, T. Zhang, J. Am. Chem. Soc., 2013, 135, 15314-15317.
[32] J. Lin, B. T. Qiao, N. Li, L. Li, X. C. Sun, J. Y. Liu, X. D. Wang, T. Zhang, Chem. Commun., 2015, 51, 7911-7914.
[33] X. F. Yang, A. Q. Wang, B. T. Qiao, J. Li, J. Y. Liu, T. Zhang, Acc. Chem. Res., 2013, 46, 1740-1748.
[34] H. Q. Zhu, Z. F. Qin, W. J. Shan, W. J. Shen, J. G. Wang, J. Catal., 2005, 233, 41-50.
[35] E. Y. Ko, E. D. Park, H. C. Lee, D. Lee, S. Kim, Angew. Chem. Int. Ed., 2007, 46, 734-737.
[36] S. Alayoglu, A. U. Nilekar, M. Mavrikakis, B. Eichhorn, Nat. Mater., 2008, 7, 333-338.
[37] D. Widmann, R.J. Behm, Angew. Chem. Int. Ed., 2011, 50, 10241-10245.
[38] M. Okumura, N. Masuyama, E. Konishi, S. Ichikawa, T. Akita, J. Catal., 2002, 208, 485-489.
[39] F. Yang, S. Kundu, A. B. Vidal, J. Graciani, P. J. Ramírez, S. D. Senanayake, D. Stacchiola, J. Evans, P. F. Liu, J. Sanz, J. A. Rodriguez, Angew. Chem. Int. Ed., 2011, 50, 10198-10202.
[40] I. X. Green, W. J. Tang, M. Neurock, J. T. Yates, Science, 2011, 333, 736-739.
[41] I. Lee, F. Zaera, J. Catal., 2014, 319, 155-162.
[42] H. L. Guan, J. Lin, B. T. Qiao, X. F. Yang, L. Li, S. Miao, J. Y. Liu, A. Q. Wang, X. D. Wang, T. Zhang, Angew. Chem. Int. Ed., 2016, 55, 2820-2824.
[43] K. Liu, A. Q. Wang, W. S. Zhang, J. H. Wang, Y. Q. Huang, X. F. Wang, J. Y. Shen, T. Zhang, Ind. Eng. Chem. Res., 2010, 50, 758-766.
[44] M. Daté, M. Okumura, S. Tsubota, M. Haruta, Angew. Chem. Int. Ed., 2004, 43, 2129-2132.
[45] J. Saavedra, H. A. Doan, C. J. Pursell, L. C. Grabow, B. D. Chandler, Science, 2014, 345, 1599-1602.
[46] H. F. Wang, R. Kavanagh, Y. L. Guo, Y. Guo, G. Z. Lu, P. Hu, Angew. Chem. Int. Ed., 2012, 51, 6657-6661.
[47] G. Šmit, S. Zrncevic, K. Lázár, J. Mol. Catal. A, 2006, 252, 103-106.
[48] S. Golunski, R. Rajaram, N. Hodge, G. J. Hutchings, C. J. Kiely, Catal. Today, 2002, 72, 107-113.
[49] A. Tomita, K. Shimizu, K. Kato, Y. Tai, Catal. Commun., 2012, 17, 194-199.
[50] A. Fukuoka, J. Kimura, T. Oshio, Y. Sakamoto, M. Ichikawa, J. Am. Chem. Soc., 2007, 29, 10120-10125.
[51] L. S. Xu, Y. S. Ma, Y. L. Zhang, Z. Q. Jiang, W. X. Huang, J. Am. Chem. Soc., 2009, 131, 16366-16367.
[52] M. Yang, S. Li, Y. Wang, J. A. Herron, Y. Xu, L. F. Allard, S. Lee, J. Huang, M. Mavrikakis, M. Flytzani-Stephanopoulos, Science, 2014, 346, 1498-1501.
[53] G. X. Chen, Y. Zhao, G. Fu, P. N. Duchesne, L. Gu, Y. P. Zheng, X. F. Weng, M. S. Chen, P. Zhang, C. W. Pao, J. F. Lee, N. F. Zheng, Science, 2014, 344, 495-499.
[54] M. Haruta, Chem. Rec., 2003, 3, 75-87.
[55] A. A. Herzing, C. J. Kiely, A. F. Carley, P. Landon, G. J. Hutchings, Science, 2008, 321, 1331-1334.
[56] B. T. Qiao, J. Lin, A. Q. Wang, Y. Chen, T. Zhang, J. Y. Liu, Chin. J. Catal., 2015, 36, 1505-1511.
[57] B. T. Qiao, J. X. Liu, Y. G. Wang, Q. Q. Lin, X. Y. Liu, A. Q. Wang, J. Li, T. Zhang, J. Y. Liu, ACS Catal., 2015, 5, 6249-6254.
[58] H. V. Roy, P. Fayet, F. Patthey, W. D. Schneider, B. Delley, C. Masso-brio, Phys. Rev. B,1994, 49, 5611-5620.
[59] D. A. J. M. Ligthart, R. A. van Santen, E. J. M. Hensen, Angew. Chem. Int. Ed., 2011, 50, 5306-5310.
[60] S. F. J. Hackett, R. M. Brydson, M. H. Gass, I. Harvey, A. D. Newman, K. Wilson, A. F. Lee, Angew. Chem. Int. Ed.,2007, 46, 8593-8596.
[61] W. E. Kaden, T. Wu, W. A. Kunkel, S. L. Anderson, Science, 2009, 326, 826-829.
[62] A. Guerrero-Ruiz, S. Yang, Q. Xin, A. Maroto-Valiente, M. Beni-to-Gonzalez, I. Rodriguez-Ramos, Langmuir, 2000, 16, 8100-8106.
[63] J. H. Fischer-Wolfarth, J. A. Farmer, J. M. Flores-Camacho, A. Gen-est, I. V. Yudanov, N. Rçsch, C. T. Campbell, S. Schauermann, H. J. Freund, Phys. Rev. B, 2010, 81, 241416/1-241416/4.
[64] M. Moses-DeBusk, M. Yoon, L. F. Allard, D. R. Mullins, Z. L. Wu, X. F. Yang, G. Veith, G. M. Stocks, C. K. Narula, J. Am. Chem. Soc., 2013, 135, 12634-12637.
[65] E. J. Peterson, A. T. DeLaRiva, S. Lin, R. S. Johnson, H. Guo, J. T. Mil-ler, J. H. Kwak, C. H. F. Peden, B. Kiefer, L. F. Allard, F. H. Ribeiro, A. K. Datye, Nat. Commun., 2014, 5, 4885.
[66] E. G. Derouane, CATTECH, 2001, 5, 214-225.
[67] P. Sonström, D. Arndt, X. Wang, V. Zielasek, M. Bäumer, Angew. Chem. Int. Ed., 2011, 50, 3888-3891.
[68] G. M. Veith, A. R. Lupini, S. J. Pennycook, N. J. Dudney, Chem-CatChem, 2010, 2, 281-286.
[69] X. G. Guo, Q. Fu, Y. X. Ning, M. M. Wei, M. R. Li, S. Zhang, Z. Jiang, X. H. Bao, J. Am. Chem. Soc., 2012, 134, 12350-12353.
[70] M. Cargnello, V. V. T. Doan-Nguyen, T. R. Gordon, R. E. Diaz, E. A. Stach, R. J. Gorte, P. Fornasiero, C. B. Murray, Science, 2013, 34, 771-774.

铂族金属催化剂低温CO氧化研究近期进展

Recent progress in CO oxidation over Pt-group-metal catalysts at low temperatures

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[2]	孙丽娟, 于晓慧, 唐丽永, 王伟康, 刘芹芹. 构建K₃PW₁₂O₄₀/CdS核壳S型异质结实现同步太阳能光催化分解水和选择性苯甲醇氧化反应[J]. 催化学报, 2023, 52(9): 164-175.
[3]	李世杰, 王春春, 董珂欣, 张鹏, 陈晓波, 李鑫. 新型MIL-101(Fe)/BiOBr S型异质催化剂用于高效光催化降解抗生素和还原六价铬: 光催化性能分析和光催化机理研究[J]. 催化学报, 2023, 51(8): 101-112.
[4]	阎菲, 张由子, 刘思碧, 邹睿卿, Jahan B Ghasemi, 李炫华. 供体-受体型卟啉基金属有机框架实现有效电荷分离高效光催化析氢[J]. 催化学报, 2023, 51(8): 124-134.
[5]	孙利娟, 王伟康, 路平, 刘芹芹, 王乐乐, 唐华. 纳米高熵合金实现光催化剂肖特基势垒的调控用于光催化制氢与苯甲醇氧化耦合反应[J]. 催化学报, 2023, 51(8): 90-100.
[6]	刘海峰, 黄祥, 陈加藏. 电子态调控促进氢气无损耗纯化中CO的光致富集和氧化[J]. 催化学报, 2023, 51(8): 49-54.
[7]	袁鑫, 范海滨, 刘杰, 覃龙州, 王剑, 段秀, 邱江凯, 郭凯. 连续流技术在光氧化还原催化转化的最新进展[J]. 催化学报, 2023, 50(7): 175-194.
[8]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[9]	李慧杰, 池漫洲, 辛兴, 王瑞杰, 刘天府, 吕红金, 杨国昱. 异金属取代的多金属氧酸盐@光响应型金属-有机框架用于高选择性光催化CO₂还原[J]. 催化学报, 2023, 50(7): 343-351.
[10]	李轩, 蒋兴星, 孔艳, 孙建桔, 胡琪, 柴晓燕, 杨恒攀, 何传新. GaN/In₂O₃的界面工程用于高效电催化CO₂还原制备甲酸[J]. 催化学报, 2023, 50(7): 314-323.
[11]	Sang Eon Jun, Sungkyun Choi, Jaehyun Kim, Ki Chang Kwon, Sun Hwa Park, Ho Won Jang. 用于电化学能量转换反应的非贵金属单原子催化剂[J]. 催化学报, 2023, 50(7): 195-214.
[12]	刘诗瑶, 巩玉同, 杨晓, 张楠楠, 刘会斌, 梁长海, 陈霄. 具有富电子镍位点的耐酸金属间化合物CaNi₂Si₂催化剂用于不饱和有机酸酐/酸的水相加氢[J]. 催化学报, 2023, 50(7): 260-272.
[13]	韩璟怡, 管景奇. 通过限域-热解策略可控合成双原子催化剂[J]. 催化学报, 2023, 49(6): 1-4.
[14]	夏思源, 李奇远, 张仕楠, 许冬, 林秀, 孙露菡, 许景三, 陈接胜, 李国栋, 李新昊. Pd纳米立方体异质结尺寸依赖的电子界面效应对苯酚加氢反应的促进作用[J]. 催化学报, 2023, 49(6): 180-187.
[15]	娄向西, 高璇, 刘钰, 褚名宇, 张丛洋, 邱盈华, 杨文秀, 曹暮寒, 王贵领, 张桥, 陈金星. 高效光热催化废旧聚酯塑料升级回收[J]. 催化学报, 2023, 49(6): 113-122.