微量热技术测量担载型催化剂的吸附/反应能量并与反应性能相关联:综述

doi:10.1016/S1872-2067(16)62578-0

催化学报 ›› 2016, Vol. 37 ›› Issue (12): 2039-2052.DOI: 10.1016/S1872-2067(16)62578-0

微量热技术测量担载型催化剂的吸附/反应能量并与反应性能相关联:综述

李林^a, 林坚^a, 李筱玉^a,b, 王爱琴^a, 王晓东^a, 张涛^a

a 中国科学院大连化学物理研究所催化基础研究国家重点实验室, 辽宁大连 116023;
b 中国科学院大学, 北京 100049

收稿日期:2016-09-22 修回日期:2016-10-14 出版日期:2016-12-27 发布日期:2016-12-27
通讯作者: Xiaodong Wang
基金资助:
国家自然科学基金（21573232，21576251，21676269）；科技部重大研究计划（2016YFA0202801）；辽宁省科技厅院士基金（2015020086-101）.

Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review

Lin Li^a, Jian Lin^a, Xiaoyu Li^a,b, Aiqin Wang^a, Xiaodong Wang^a, Tao Zhang^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Science, Beijing 100049, China

Received:2016-09-22 Revised:2016-10-14 Online:2016-12-27 Published:2016-12-27
Contact: Xiaodong Wang
Supported by:
This work was supported by the National Natural Science Foundation of China (21573232, 21576251, 21676269), National Key Projects for Fundamental Research and Development of China (2016YFA0202801), and Department of Science and Technology of Liaoning province under contract of 2015020086-101.

摘要/Abstract

摘要：

多相催化反应过程伴随着反应分子与催化剂表面之间的相互作用.这种相互作用强度与催化剂的反应性能密切相关.根据萨巴蒂尔原理（Sabatier principle），性能最优的催化剂与反应中间体之间应该具有适中的相互作用强度，一方面促进反应物活化，另一方面允许产物脱附.这样，测量和研究反应分子与催化剂之间的相互作用强度对于理解催化反应性能有非常重要的意义.
当气体反应物接触到催化剂表面会伴随着热量的产生，该热量被定义为吸附热，并与吸附物种与催化剂之间形成的化学键强度直接相关.吸附热通常可以通过程序升温脱附（TPD）等方法间接获得.但是这些方法建立在吸附物种能够可逆地吸附和脱附的假设基础上.在实际的程序升温过程中，吸附物种通常会发生分解，并伴随着固体催化剂的重构等现象.因此，采用基于Tian-Calvet原理的热流量热计直接测量担载催化剂的吸附热是最可靠的吸附热测量方法.
基于热流量热计测量的微量热技术的一个重要优点是采用合适的探针分子吸附，可以获得担载型催化剂表面吸附活性中心的数量、强度及其能量分布的定量信息.比如，采用碱性探针分子NH₃或者吡啶，酸性探针分子CO₂或SO₂能够定量催化剂上酸-碱位的强度和数量，而金属催化剂活性中心可以应用H₂或CO进行探测.当这些催化剂活性中心的定量表征结果与催化剂的反应活性测试结果相关联时，可以区分不同强度活性中心的反应性能，并为提高和改进催化剂性能提供研制方向.
相对于NH₃或CO等小分子气体，催化反应的反应物、产物或可能的中间体通常都是复杂分子，程序升温技术测量它们的吸附热时，这些分子通常会发生分解，限制了其吸附热的测量和研究.微量热技术能够直接测量这些分子的吸附热.因此，与催化反应活性相关联，反应物、产物或可能的中间体的吸附能量的测量和研究有利于更直接地认识催化剂的反应性能.
在催化反应循环过程中，除了吸附，还包括表面反应和脱附步骤.这些步骤也伴随着吸附物种与催化剂之间键的形成与转换，并以热量的形式表现出来.测量这些热量对于认识催化反应过程，理解催化反应机理有重要的意义.热流量热计与催化微反系统相结合，为催化反应过程能量的测量和研究提供了可能.
尽管微量热技术在测量担载型催化剂的吸附/反应能量并与反应性能相关联方面有其独特的优势，但是为了更好地用于催化研究，应该结合其它的表征技术（比如红外）确定吸附或反应物种的本质，结合理论计算对量热结果进行更好地补充和认识.
本文综述了担载型催化剂的吸附/反应能量与反应性能关联的研究进展，指出了微量热技术在催化研究中的优势、不足，以及未来的研究方向.

关键词: 催化, 微量热, 反应性能, 能量, 键强, 催化剂表征

Abstract:

The formations and transformations of the chemical bonds of reactants and intermediates on catalyst surfaces occur in conjunction with the evolution of heat during catalytic reactions. Measurement of this evolved heat is helpful in terms of understanding the nature of the interactions between the catalyst and the adsorbed species, and provides insights into the reactivity of the catalyst. Although various techniques have previously been applied to assessments of evolved heat, direct measurements using a Tian-Calvet microcalorimeter are currently the most reliable method for this purpose. In this review, we summarize the relationship between the adsorption/reaction energetics determined by microcalorimetry and the reactivities of supported catalysts, and examine the important role of microcalorimetry in understanding catalytic performance from the energetic point of view.

Key words: Catalysis, Microcalorimetry, Reactivity, Energetics, Binding strength, Catalyst characterization

李林, 林坚, 李筱玉, 王爱琴, 王晓东, 张涛. 微量热技术测量担载型催化剂的吸附/反应能量并与反应性能相关联:综述[J]. 催化学报, 2016, 37(12): 2039-2052.

Lin Li, Jian Lin, Xiaoyu Li, Aiqin Wang, Xiaodong Wang, Tao Zhang. Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review[J]. Chinese Journal of Catalysis, 2016, 37(12): 2039-2052.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(16)62578-0

https://www.cjcatal.com/CN/Y2016/V37/I12/2039

参考文献

[1] P. Sabatier, Revue Déconomie Industrielle, Valbonne, 1913, 31, 100-111.
[2] K. W. Kolasinski, Surface Science:Foundations of Catalysis and Nanoscience, 3rd ed., John Wiley & Sons, Ltd, Chichester, 2012, 185-228.
[3] N. Cardona-Martinez, J. A. Dumesic, Adv Catal., 1992, 38, 149-244.
[4] P. C. Gravelle, Catal. Rev.-Sci. Eng., 1977, 16, 37-110.
[5] S. Gaisford, V. Kett, P. Haines, Principles of Thermal Analysis and Calorimetry, 2nd ed, The Royal Society of Chemistry, Cambridge, 2016,
[6] A. Auroux, A. Gervasini, J. Phys. Chem., 1990, 94, 6371-6379.
[7] A. Auroux, Top. Catal., 2002, 19, 205-213.
[8] E. L. Kunkes, D. A. Simonetti, J. A. Dumesic, W. D. Pyrz, L. E. Murillo, J. G. G. Chen, D. J. Buttrey, J. Catal., 2008, 260, 164-177.
[9] S. Cerny, Surf. Sci. Rep., 1996, 26, 3-59.
[10] W. A. Brown, R. Kose, D. A. King, Chem. Rev., 1998, 98, 797-832.
[11] O. Lytken, W. Lew, C. T. Campbell, Chem. Soc. Rev., 2008, 37, 2172-2179.
[12] B. E. Spiewak, J. A. Dumesic, Thermochim. Acta, 1998, 312, 95-104.
[13] V. E. Ostrovskii, J. Therm. Anal. Calorim., 2009, 95, 609-622.
[14] A. Guerrero-Ruiz, A. Maroto-Valiente, M. Cerro-Alarcon, B. Bachiller-Baeza, I. Rodriguez-Ramos, Top. Catal., 2002, 19, 303-311.
[15] B. E. Handy, S. B. Sharma, B. E. Spiewak, J. A. Dumesic, Meas. Sci. Technol., 1993, 4, 1350-1356.
[16] B. E. Spiewak, J. A. Dumesic, Thermochim. Acta, 1997, 290, 43-53.
[17] V. Garcia-Cuello, J. C. Moreno-Piraján, L. Giraldo-Gutiérrez, K. Sapag, G. Zgrablich, Microporous Mesoporous Mater., 2009, 120, 239-245.
[18] Y. Kobayashi, Q. X. Li, D. Z. Wang, F. Wang, Rev. Sci. Instrum., 2014, 85, 034101.
[19] V. Garcia-Cuello, J. C. Moreno-Pirajan, L. Giraldo-Gutierrez, K. Sapag, G. Zgrablich, J. Therm. Anal. Calorim., 2009, 97, 711-715.
[20] F. Siperstein, R. J. Gorte, A. L. Myers, Langmuir, 1999, 15, 1570-1576.
[21] L. Li, X. D. Wang, J. Y. Shen, L. X. Zhou, T. Zhang, Chin. J. Catal., 2003, 24, 872-876.
[22] B. E. Spiewak, R. D. Cortright, J. A. Dumesic, J. Catal., 1998, 176, 405-414.
[23] A. J. Groszek, Thermochim. Acta, 1998, 312, 133-143.
[24] E. Lalik, R. Mirek, J. Rakoczy, A. Groszek, Catal. Today, 2006, 114, 242-247.
[25] N. D. Gangal, N. M. Gupta, R. M. Iyer, J. Catal., 1990, 126, 13-25.
[26] J. Lin, L. Li, Y. Q. Huang, W. S. Zhang, X. D. Wang, A. Q. Wang, T. Zhang, J. Phys. Chem. C, 2011, 115, 16509-16517.
[27] M. Maciejewski, A. Baiker, in:E. B. Michael, K. G. Patrick eds., Handbook of Thermal Analysis and Calorimetry, Elsevier Science B.V., Amsterdam, 2008, 5, 93-132.
[28] B. Lindström, L. J. Pettersson, Cattech, 2003, 7, 130-138.
[29] B. B. Bardin, S. V. Bordawekar, M. Neurock, R. J. Davis, J. Phys. Chem. B, 1998, 102, 10817-10825.
[30] D. Tichit, M. H. Lhouty, A. Guida, B. H. Chiche, F. Figueras, A. Auroux, D. Bartalini, E. Garrone, J. Catal., 1995, 151, 50-59.
[31] A. Guerrero-Ruiz, P. Badenes, I. Rodríguez-Ramos, Appl. Catal. A, 1998, 173, 313-321.
[32] M. Boudart, Chem. Rev., 1995, 95, 661-666.
[33] G. Yaluris, R. B. Larson, J. M. Kobe, M. R. Gonzalez, K. B. Fogash, J. A. Dumesic, J. Catal., 1996, 158, 336-342.
[34] A. Auroux, Top. Catal., 1997, 4, 71-89.
[35] W. Alharbi, E. F. Kozhevnikova, I. V. Kozhevnikov, ACS Catal., 2015, 5, 7186-7193.
[36] D. Stoši?, S. Bennici, J. L. Couturier, J. L. Dubois, A. Auroux, Catal. Commun., 2012, 17, 23-28.
[37] D. Stoši?, S. Bennici, S. Sirotin, P. Stelmachowski, J. L. Couturier, J. L. Dubois, A. Travert, A. Auroux, Catal. Today, 2014, 226, 167-175.
[38] Y. D. Xia, W. M. Hua, Z. Gao, Appl. Catal. A, 1999, 185, 293-300.
[39] K. B. Fogash, G. Yaluris, M. R. Gonzalez, P. Ouraipryvan, D. A. Ward, E. I. Ko, J. A. Dumesic, Catal. Lett., 1995, 32, 241-251.
[40] X. R. Chen, Y. Q. Du, C. L. Chen, N. P. Xu, C. Y. Mou, Catal. Lett., 2006, 111, 187-193.
[41] G. M. Kumaran, S. Garg, M. Kumar, N. Viswanatham, J. K. Gupta, L. D. Sharma, G. M. Dhar, Energy Fuels, 2006, 20, 2308-2313.
[42] N. R. Shiju, D. R. Brown, K. Wilson, G. Rothenberg, Top. Catal., 2010, 53, 1217-1223.
[43] R. Kourieh, S. Bennici, M. Marzo, A. Gervasini, A. Auroux, Catal. Commun., 2012, 19, 119-126.
[44] R. Kourieh, V. Rakic, S. Bennici, A. Auroux, Catal. Commun., 2013, 30, 5-13.
[45] S. H. Hu, M. W. Xue, H. Chen, J. Y. Shen, Chem. Eng. J., 2010, 162, 371-379.
[46] H. Chen, M. W. Xue, S. H. Hu, J. Y. Shen, Chem. Eng. J., 2012, 181, 677-684.
[47] J. Zhao, H. Chen, J. Xu, J. Y. Shen, J. Phys. Chem. C, 2013, 117, 10573-10580.
[48] S. H. Hu, M. W. Xue, H. Chen, Y. L. Sun, J. Y. Shen, Chin. J. Catal., 2011, 32, 917-925.
[49] M. W. Xue, H. Chen, H. L. Zhang, A. Auroux, J. Y. Shen, Appl. Catal. A, 2010, 379, 7-14.
[50] P. Lauriol-Garbey, G. Postole, S. Loridant, A. Auroux, V. Belliere-Baca, P. Rey, J. M. M. Millet, Appl. Catal. B, 2011, 106, 94-102.
[51] D. Meloni, M. F. Sini, M. G. Cutrufello, R. Monaci, E. Rombi, I. Ferino, J. Therm. Anal. Calorim., 2012, 108, 783-791.
[52] R. Kourieh, L. Retailleau, S. Bennici, A. Giroir-Fendler, A. Auroux, Catal. Lett., 2013, 143, 74-83.
[53] T. R. Brueva, I. V. Mishin, G. I. Kapustin, Thermochim. Acta, 2001, 379, 15-23.
[54] N. Viswanadham, L. Dixit, J. K. Gupta, M. O. Garg, J. Mol. Catal. A, 2006, 258, 15-21.
[55] C. P. Nicolaides, H. H. Kung, N. P. Makgoba, N. P. Sincadu, M. S. Scurrell, Appl. Catal. A, 2002, 223, 29-33.
[56] D. Stosic, S. Bennici, S. Sirotin, C. Calais, J. L. Couturier, J. L. Dubois, A. Travert, A. Auroux, Appl. Catal. A, 2012, 447, 124-134.
[57] R. D. Cortright, J. A. Dumesic, J. Catal., 1994, 148, 771-778.
[58] R. D. Cortright, J. A. Dumesic, J. Catal., 1995, 157, 576-583.
[59] B. E. Spiewak, P. Levin, R. D. Cortright, J. A. Dumesic, J. Phys. Chem., 1996, 100, 17260-17265.
[60] S. B. Sharma, P. Ouraipyvan, H. A. Nair, P. Balaraman, T. W. Root, J. A. Dumesic, J. Catal., 1994, 150, 234-242.
[61] R. Naumann d'Alnoncourt, M. Kurtz, H. Wilmer, E. Löffler, V. Hagen, J. Shen, M. Muhler, J. Catal., 2003, 220, 249-253.
[62] A. Guerrero-Ruiz, E. Gallegos-Suarez, L. Gonzalo-Chacon, I. Rodriguez-Ramos, Thermochim. Acta, 2013, 567, 112-117.
[63] J. L. Eslava, A. Iglesias-Juez, G. Agostini, M. Fernandez-Garcia, A. Guerrero-Ruiz, I. Rodriguez-Ramos, ACS Catal., 2016, 6, 1437-1445.
[64] M. S. Chen, D. W. Goodman, Acc. Chem. Res., 2006, 39, 739-746.
[65] N. Lopez, T. V. W. Janssens, B. S. Clausen, Y. Xu, M. Mavrikakis, T. Bligaard, J. K. Nørskov, J. Catal., 2004, 223, 232-235.
[66] V. Bolis, in:Calorimetry and Thermal Methods in Catalysis, ed. A. Auroux, Springer Berlin Heidelberg, Berlin, Heidelberg, 2013, 505-519.
[67] H. A. Prescott, Z. J. Li, E. Kemnitz, A. Trunschke, J. Deutsch, H. Lieske, A. Auroux, J. Catal., 2005, 234, 119-130.
[68] A. Guerrero-Ruiz, S. W. Yang, Q. Xin, A. Maroto-Valiente, M. Beni-to-Gonzalez, I. Rodriguez-Ramos, Langmuir, 2000, 16, 8100-8106.
[69] X. T. Wang, L. Li, Y. Q. Huang, X. D. Wang, T. Zhang, Chin. J. Catal., 2008, 29, 1231-1236.
[70] J. M. Arce-Ramos, L. C. Grabow, B. E. Handy, M. G. Car-denas-Galindot, J. Phys. Chem. C, 2015, 119, 15150-15159.
[71] R. He, H. Kusaka, M. Mavrikakis, J. A. Dumesic, J. Catal., 2003, 217, 209-221.
[72] R. Alcala, J. W. Shabaker, G. W. Huber, M. A. Sanchez-Castillo, J. A. Dumesic, J. Phys. Chem. B, 2005, 109, 2074-2085.
[73] L. Li, X. D. Wang, A. Q. Wang, J. Y. Shen, T. Zhang, Thermochim. Acta, 2009, 494, 99-103.
[74] S. Wrabetz, X. B. Yang, G. Tzolova-Muller, R. Schlogl, F. C. Jentoft, J. Catal., 2010, 269, 351-358.
[75] K. Amakawa, J. Krohnert, S. Wrabetz, B. Frank, F. Hemmann, C. Jager, R. Schlogl, A. Trunschke, ChemCatChem, 2015, 7, 4059-4065.
[76] R. Arrigo, M. E. Schuster, S. Wrabetz, F. Girgsdies, J. P. Tessonnier, G. Centi, S. Perathoner, D. S. Su, R. Schlogl, ChemSusChem, 2012, 5, 577-586.
[77] Y. Wang, J. Zhao, T. F. Wang, Y. X. Li, X. Y. Li, J. Yin, C. Y. Wang, J. Catal., 2016, 337, 293-302.
[78] R. H. Cheng, Y. Y. Shu, M. Y. Zheng, L. Li, J. Sun, X. D. Wang, T. Zhang, J. Catal., 2007, 249, 397-400.
[79] O. Mihai, D. Creaser, L. Olsson, Catalysts, 2016, 6(5), 73/1-73/12.
[80] J. Zhao, H. Chen, X. C. Tian, H. Zang, Y. C. Fu, J. Y. Shen, J. Catal., 2013, 298, 161-169.
[81] J. M. Guil, N. Homs, J. Llorca, P. R. de la Piscina, J. Phys. Chem. B, 2005, 109, 10813-10819.
[82] L. Chen, J. Y. Shen, J. Catal., 2011, 279, 246-256.
[83] G. X. Pei, X. Y. Liu, A. Q. Wang, L. Li, Y. Q. Huang, T. Zhang, J. W. Lee, B. W. L. Jang, C. Y. Mou, New J. Chem., 2014, 38, 2043-2051.
[84] G. X. Pei, X. Y. Liu, A. Q. Wang, A. F. Lee, M. A. Isaacs, L. Li, X. L. Pan, X. F. Yang, X. D. Wang, Z. J. Tai, K. Wilson, T. Zhang, ACS Catal., 2015, 5, 3717-3725.
[85] H. R. Zhou, X. F. Yang, L. Li, X. Y. Liu, Y. Q. Huang, X. L. Pan, A. Q. Wang, J. Li, T. Zhang, ACS Catal., 2016, 6, 1054-1061.
[86] C. M. Y. Yeung, K. M. K. Yu, Q. J. Fu, D. Thompsett, M. I. Petch, S. C. Tsang, J. Am. Chem. Soc., 2005, 127, 18010-18011.
[87] D. R. Lide, CRC Handbook of Chemistry and Physics, CRC Press Incorpration, Boca Raton, Florida, 84th ed., 2003-2004, Chapter 4, Section 5.
[88] J. Lin, Y. Q. Huang, L. Li, A. Q. Wang, W. S. Zhang, X. D. Wang, T. Zhang, Catal. Today, 2012, 180, 155-160.
[89] V. P. Londhe, N. M. Gupta, J. Catal., 1997, 169, 415-422.
[90] N. M. Gupta, V. P. Londhe, V. S. Kamble, J. Catal., 1997, 169, 423-437.
[91] A. K. Tripathi, V. S. Kamble, N. M. Gupta, J. Catal., 1999, 187, 332-342.
[92] N. M. Gupta, A. K. Tripathi, J. Catal., 1999, 187, 343-347.
[93] L. Li, A. Q. Wang, B. T. Qiao, J. Lin, Y. Q. Huang, X. D. Wang, T. Zhang, J. Catal., 2013, 299, 90-100.
[94] E. Lalik, A. Drelinkiewicz, R. Kosydar, T. Szume?da, E. Bielańska, D. Groszek, A. Iannetelli, M. Groszek, Ind. Eng. Chem. Res.,2015, 54, 7047-7058.
[95] E. Lalik, R. Kosydar, R. Tokarz-Sobieraj, M. Witko, T. Szume?da, M. Ko?odziej, W. Rojek, T. Machej, E. Bielańska, A. Drelinkiewicz, Appl. Catal. A, 2015, 501, 27-40.
[96] E. Lalik, A. Drelinkiewicz, R. Kosydar, W. Rojek, T. Machej, J. Gurgul, T. Szumelda, M. Kolodziej, E. Bielanska, Int. J. Hydrogen Energy, 2015, 40, 16127-16136.
[97] E. Lalik, A. Drelinkiewicz, R. Kosydar, R. Tokarz-Sobieraj, M. Witko, T. Szumelda, J. Gurgul, D. Duraczynska, Appl. Catal. A, 2016, 517, 196-210.
[98] M. C. Crowe, C. T. Campbell, in:Annual Review of Analytical Chemistry, Vol 4, eds. R. G. Cooks, E. S. Yeung, Annual Reviews, Palo Alto, 2011, 4, 41-58.
[99] E. G. Moschetta, K. M. Gans, R. M. Rioux, J. Catal., 2014, 309, 11-20.
[100] M. E. Strayer, J. M. Binz, M. Tanase, S. M. Kamali Shahri, R. Shar-ma, R. M. Rioux, T. E. Mallouk, J. Am. Chem. Soc., 2014, 136, 5687-5696.

微量热技术测量担载型催化剂的吸附/反应能量并与反应性能相关联:综述

Adsorption/reaction energetics measured by microcalorimetry and correlated with reactivity on supported catalysts: A review

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	赵彬彬, 钟威, 陈峰, 王苹, 别传彪, 余火根. 高晶化g-C₃N₄光催化剂: 合成、结构调控和光催化产氢[J]. 催化学报, 2023, 52(9): 127-143.
[2]	唐小龙, 李锋, 李方, 江燕斌, 余长林. 单原子催化剂在光催化和电催化合成过氧化氢中的研究进展[J]. 催化学报, 2023, 52(9): 79-98.
[3]	张季, 俞爱民, 孙成华. 非金属掺杂石墨烯异核双原子催化剂氮还原特性研究[J]. 催化学报, 2023, 52(9): 263-270.
[4]	胡金念, 田玲婵, 王海燕, 孟洋, 梁锦霞, 朱纯, 李隽. MXene负载3d金属单原子高效氮还原电催化剂的理论筛选[J]. 催化学报, 2023, 52(9): 252-262.
[5]	洪岩, 王琦, 阚子旺, 张禹烁, 郭晶, 李思琦, 刘松, 李斌. 电化学氮还原氨反应催化剂的最新研究进展[J]. 催化学报, 2023, 52(9): 50-78.
[6]	孙嘉辰, 陈赛, 付东龙, 王伟, 王显辉, 孙国栋, 裴春雷, 赵志坚, 巩金龙. 氧扩散与表面反应在VO_x-Ce_1‒_xZr_xO₂催化丙烷脱氢反应中的影响[J]. 催化学报, 2023, 52(9): 217-227.
[7]	蔡铭洁, 刘艳萍, 董珂欣, 陈晓波, 李世杰. 漂浮型Bi₂WO₆/C₃N₄/碳布S型异质结光催化材料用于高效净化水体环境[J]. 催化学报, 2023, 52(9): 239-251.
[8]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[9]	高晖, 张恭, 程东方, 王永涛, 赵静, 李晓芝, 杜晓伟, 赵志坚, 王拓, 张鹏, 巩金龙. 构建Cu台阶位促进电催化CO₂还原制醇类化学品的研究[J]. 催化学报, 2023, 52(9): 187-195.
[10]	王思恺, 闵祥婷, 乔波涛, 颜宁, 张涛. 单原子催化: 追寻催化领域的“圣杯”[J]. 催化学报, 2023, 52(9): 1-13.
[11]	江梓聪, 程蓓, 张留洋, 张振翼, 别传彪. 氧化锌基梯型异质结光催化剂[J]. 催化学报, 2023, 52(9): 32-49.
[12]	邹心仪, 顾均. 酸性条件下二氧化碳高效电还原策略[J]. 催化学报, 2023, 52(9): 14-31.
[13]	Abhishek R. Varma, Bhushan S. Shrirame, Sunil K. Maity, Deepti Agrawal, Naglis Malys, Leonardo Rios-Solis, Gopalakrishnan Kumar, Vinod Kumar. C4二醇的发酵生产及其化学催化升级为高价值化学品的研究进展[J]. 催化学报, 2023, 52(9): 99-126.
[14]	刘鑫, 王茂弟, 任亦起, 刘嘉立, 戴慧聪, 杨启华. 构建模块化催化体系用于氢转移反应: 氢键的促进作用[J]. 催化学报, 2023, 52(9): 207-216.
[15]	赵磊, 张震, 朱昭昭, 李平波, 蒋金霞, 杨婷婷, 熊佩, 安旭光, 牛晓滨, 齐学强, 陈俊松, 吴睿. 缺陷氮掺杂碳耦合Co-N₅单原子位点用于高效锌-空气电池[J]. 催化学报, 2023, 51(8): 216-224.