固定化Sn/氯化胆硷络合物制备Sn-β分子筛催化剂用于葡萄糖-果糖异构化反应

doi:10.1016/S1872-2067(17)62754-2

催化学报 ›› 2017, Vol. 38 ›› Issue (3): 426-433.DOI: 10.1016/S1872-2067(17)62754-2

• 能源与环境新型催化剂专栏 • 上一篇下一篇

固定化Sn/氯化胆硷络合物制备Sn-β分子筛催化剂用于葡萄糖-果糖异构化反应

Asep Bayu^a, Surachai Karnjanakom^a, Katsuki Kusakabe^c, Abuliti Abudula^a, Guoqing Guan^a,b

a 弘前大学科学技术研究生院, 弘前 036-8560, 日本;
b 弘前大学北日本新能源研究所, 青森 030-0813, 日本;
c 崇城大学纳米科学系, 熊本 860-0082, 日本

收稿日期:2016-09-30 修回日期:2016-11-23 出版日期:2017-03-18 发布日期:2017-03-22
通讯作者: Guoqing Guan

Preparation of Sn-β-zeolite via immobilization of Sn/choline chloride complex for glucose-fructose isomerization reaction

Asep Bayu^a, Surachai Karnjanakom^a, Katsuki Kusakabe^c, Abuliti Abudula^a, Guoqing Guan^a,b

a Graduate School of Science and Technology, Hirosaki University, Hirosaki 036-8560, Japan;
b North Japan Research Institute for Sustainable Energy (NJRISE), Hirosaki University, 2-1-3, Matsubara, Aomori 030-0813, Japan;
c Department of Nanoscience, Sojo University, 4-22-1 Ikeda, Nishi-ku, Kumamoto 860-0082, Japan

Received:2016-09-30 Revised:2016-11-23 Online:2017-03-18 Published:2017-03-22

摘要/Abstract

摘要：

在水溶液中锡盐与β分子筛金属化过程中很容易水解为氢氧化物，因此，制备高度分散的、以孤立形式存在的锡物种非常具有挑战性.我们先采用SnCl₂/氯化胆硷（ChCl）络合物将锡物种固定在高硅的商品化的β分子筛上，然后焙烧就可很方便地在水溶液条件下制得了高度分散于β分子筛上的锡物种.电镜照片、紫外-可见光光谱和X射线衍射结果证实了这一点.ChCl的存在促进了锡物种与分子筛的结合.担载（1-2）wt%Sn的β分子筛在葡萄糖-果糖异构化反应中表现出较高的催化活性和选择性.

关键词: 锡-β分子筛, 固定化, 氯化胆硷, 葡萄糖, 异构化, 果糖

Abstract:

Well dispersion of tin species in an isolated form is a quite challenge since tin salts are easily hydrolyzed into (hydr)oxides during aqueous stannation of β-zeolite. In this study, immobilization of tin species on high silica commercial β-zeolite by using SnCl₂/Choline chloride (ChCl) complex followed with calcination provided a convenient way to get well dispersed Sn in β-zeolite in the aqueous condition, which was observed based on electron microscopy images, UV visible spectra and X-ray diffraction pattern. The existence of ChCl facilitated tin species to incorporate into zeolite. (1-2) wt% of Sn loaded β-zeolites exhibited good catalytic activity and high selectivity for glucose-fructose isomerization reaction.

Key words: Sn-&beta, zeolite, Immobilization, Choline chloride, Glucose, Isomerization, Fructose

Asep Bayu, Surachai Karnjanakom, Katsuki Kusakabe, Abuliti Abudula, Guoqing Guan. 固定化Sn/氯化胆硷络合物制备Sn-β分子筛催化剂用于葡萄糖-果糖异构化反应[J]. 催化学报, 2017, 38(3): 426-433.

Asep Bayu, Surachai Karnjanakom, Katsuki Kusakabe, Abuliti Abudula, Guoqing Guan. Preparation of Sn-β-zeolite via immobilization of Sn/choline chloride complex for glucose-fructose isomerization reaction[J]. Chinese Journal of Catalysis, 2017, 38(3): 426-433.

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参考文献

[1] P. Li, G. Q. Liu, H. H. Wu, Y. M. Liu, J. G. Jiang, P. Wu, J. Phys. Chem. C, 2011, 115, 3663-3670.
[2] C. Hammond, S. Conrad, I. Hermans, Angew. Chem. Int. Ed., 2012, 51, 11736-11739.
[3] C. Hammond, D. Padovan, A. Al-Nayili, P. P. Wells, E. K. Gibson, N. Dimitratos, ChemCatChem, 2015, 7, 3322-3331.
[4] J. Dijkmans, D. Gabriels, M. Dusselier, F. de Clippel, P. Vanelderen, K. Houthoofd, A. Malfliet, Y. Pontikes, B. F. Sels, Green Chem., 2013, 15, 2777-2785.
[5] J. Dijkmans, J. Demol, K. Houthoofd, S. G. Huang, Y. Pontikes, B. F. Sels, J. Catal., 2015, 330, 545-557.
[6] P. Y. Dapsens, C. Mondelli, J. Perez-Ramirez, New J. Chem., 2016, 40, 4136-4139.
[7] M. Dusselier, P. Van Wouwe, A. Dewaele, E. Makshina, B. F. Sels, Energy Environ. Sci., 2013, 6, 1415-1442.
[8] P. Y. Dapsens, C. Mondelli, J. Perez-Ramirez, Chem. Soc. Rev., 2015, 44, 7025-7043.
[9] A. Bayu, G. Q. Guan, S. Karnjanakom, X. G. Hao, K. Kusakabe, A. Abudula, Chem. Select, 2016, 1, 180-188.
[10] F. Liu, M. Audemar, K. De Oliveria Vigier, D. Cartigny, J. M. Clacens, M. F. Costa Gomes, A. A. H. Padua, F. De Campo, F. Jerome, Green Chem., 2013, 15, 3205-3213.
[11] P. De Vreese, N. R. Brooks, K. Van Hecke, L. Van Meervelt, E. Matthijs, K. Binnemans, R. Van Deun, Inorg. Chem., 2012, 51, 4972-4981.
[12] J. Yang, K. D. O. Vigier, Y. L. Gu, F. Jerome, ChemSusChem, 2015, 8, 269-274.
[13] S. Karnjanakom, A. Bayu, P. Xiaoketi, X. G. Hao, S. Kongparakul, C. Samart, A. Abudula, G. P. Guan, RSC Adv., 2016, 6, 50618-50629.
[14] A. P. Abbot, G. Capper, D. L. Davies, H. L. Munro, R. K. Rasheed, V. Tambyrajah, Chem. Commun., 2001, 2010-2011.
[15] R. Bermejo-Deval, R. Gounder, M. E. Davis, ACS Catal., 2012, 2, 2705-2713.
[16] H. Y. Luo, J. D. Lewis, Y. Roman-Leshkov, Annu. Rev. Chem. Biomol. Eng., 2016, 7: 663-692.
[17] M. Mazur, P. S. Wheatley, M. Navarro, W. J. Roth, M. Polozij, A. Mayoral, P. Eliasova, P. Nachtigall, J. Cejka, R. E. Morris, Nat. Chem., 2016, 8, 58-62.
[18] J. Dijkmans, M. Dusselier, D. Gabriels, K. Houthoofd, P. C. M. M. Magusin, S. G. Huang, Y. Pontikes, M. Trekels, A. Vantomme, L. Giebeler, S. Oswald, B. F. Sels, ACS Catal., 2015, 5, 928-940.
[19] S. Tolborg, A. Katerinopoulou, D. D. Falcone, I. Sadaba, C. M. Osmundsen, R. J. Davis, E. Taarning, P. Fristrup, M. S. Holm, J. Mater. Chem. A, 2014, 2, 20252-20262.
[20] M. Casagrande, E. Moretti, L. Storaro, M. Lenarda, J. Gersich, L. Stievano, F. E. Wagner, Micropor. Mesopor. Mater., 2006, 91, 261-267.
[21] P. Y. Dapsens, C. Mondelli, J. Perez-Ramirez, ChemSusChem, 2013, 6, 831-839.
[22] M. Moliner, Y. Roman-Leshkov, M. E. Davis, PNASUSA, 2010, 107, 6164-6168.
[23] Y. Roman-Leshkov, M. Moliner, J. A. Labinger, M. E. Davis, Angew. Chem. Int. Ed., 2010, 49, 8954-8957.
[24] W. R. Gunther, Y. R. Wang, Y. W. Ji, V. K. Michaelis, S. T. Hunt, R. G. Griffin, Y. Roman-Leshkov, Nat. Commun., 2012, 3, 1109.
[25] G. M. Lari, P. Y. Dapsens, D. Scholz, S. Mitchell, C. Mondelli, J. Perez-Ramirez, Green Chem., 2016, 18, 1249-1260.

固定化Sn/氯化胆硷络合物制备Sn-β分子筛催化剂用于葡萄糖-果糖异构化反应

Preparation of Sn-β-zeolite via immobilization of Sn/choline chloride complex for glucose-fructose isomerization reaction

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