单核第一过渡周期金属水氧化催化剂

doi:10.1016/S1872-2067(17)63001-8

催化学报 ›› 2018, Vol. 39 ›› Issue (2): 228-244.DOI: 10.1016/S1872-2067(17)63001-8

单核第一过渡周期金属水氧化催化剂

王妮^a, 郑浩铨^a, 张伟^a, 曹睿^a,b

a 陕西师范大学化学化工学院应用表面与胶体化学教育部重点实验室, 陕西西安 710119;
b 中国人民大学理学院化学系, 北京 100872

收稿日期:2017-11-06 修回日期:2017-12-15 出版日期:2018-02-18 发布日期:2018-02-10
通讯作者: 曹睿
基金资助:
This work was supported by Thousand Talents Program of China, the National Natural Science Foundation of China (21101170, 21573139, and 21773146), the Fundamental Research Funds for the Central Universities, and the Research Funds of Shaanxi Normal University.

Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation

Ni Wang^a, Haoquan Zheng^a, Wei Zhang^a, Rui Cao^a,b

a Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, Shaanxi, China;
b Department of Chemistry, Renmin University of China, Beijing 100872, China

Received:2017-11-06 Revised:2017-12-15 Online:2018-02-18 Published:2018-02-10
Contact: 10.1016/S1872-2067(17)63001-8
Supported by:
This work was supported by Thousand Talents Program of China, the National Natural Science Foundation of China (21101170, 21573139, and 21773146), the Fundamental Research Funds for the Central Universities, and the Research Funds of Shaanxi Normal University.

摘要/Abstract

摘要：

由于传统化石能源的不可再生性，其储量日益减少.同时，传统化石能源的使用对环境产生了巨大影响，给人类社会带来了一系列问题，包括温室效应、酸雨等.因此，进入二十一世纪以后，人类面临着日益严峻的能源危机和环境问题，寻找清洁、高效的替代能源已经迫在眉睫.太阳能被认为是一种洁净的可再生能源.自然界通过光合作用将太阳能转化为化学能，在这一过程中，水被氧化产生氧气，同时释放出的电子和质子通过和二氧化碳作用生成碳水化合物.为了模拟这一过程，人工光合作用可以直接将电子和质子结合形成氢气.由此生成的氢气也被认为是洁净的可再生能源，因为在其燃烧过程中只产生水.因此，通过光致水分解析氢析氧的人工光合作用受到了越来越广泛的重视.
水分解可以分为两个独立的半反应，即水的氧化析氧和水的还原析氢.水的氧化无论在热力学还是动力学方面，都存在着非常大的阻碍.在热力学上，两分子的水氧化生成一分子氧气需要提供很多能量（△E=1.23 V vs NHE）.在动力学上，由于涉及到四个氢原子和两个氧原子的重组，并且涉及到氧氧键形成并释放出一分子氧气，因此水氧化是一个非常缓慢的过程.在自然界，水的氧化主要发生在光合作用中，在绿色植物的叶绿体中完成.通过对光合作用的研究，科学家们发现氧气的产生由光系统Ⅱ（PSⅡ）中的释氧中心来完成.释氧中心是一个钙锰簇合物，由四个锰和一个钙组成（Mn₄CaO_x）.自然界水分解产生氧气的过程给了我们很大启示，对设计和研究高效稳定的水氧化催化剂具有一定的指导意义.
目前水氧化催化剂主要有两大类.第一类是基于材料的水氧化催化剂.该类催化剂的催化效率高，过电势小，但是对水氧化催化过程的机理缺乏深入研究.第二类是基于金属配合物的分子催化剂.相比基于材料的催化剂，分子催化剂具有以下特点：（1）分子催化剂的结构可以通过实验手段表征清楚；（2）可以结合光谱对水氧化的机理进行深入研究，可以对催化过程中间体进行表征；（3）催化剂的结构可以从分子水平上进行修饰，因此可以更好地研究催化效率与结构之间的关系，为设计高效、稳定的催化剂提供必要信息；（4）比较容易组装成分子器件从而应用到实际的水氧化装置中；（5）通过实验与理论的结合，对氧氧成键提出新的认识与理解.
近几年来，一些单核的金属配合物逐渐被发现可以高效、稳定地催化水氧化.研究表明，一些基于钌和铱的催化剂具有良好的催化活性，但由于金属钌和铱储量少、价格昂贵等因素，限制了该类催化剂的大量使用.由于第一过渡系金属元素具有储量丰富、安全无毒、廉价易得等优势，第一过渡周期金属化合物逐渐成为科学家们研究的热点.近几年来，基于第一过渡系金属的水氧化催化剂已经有大量报道.
本文主要总结了近几年来基于第一过渡系金属的单核水氧化分子催化剂.通过对催化机理进行深入的讨论，特别是对氧氧成键的总结，本文将对设计合成结构新颖、具有高催化效率和良好稳定性的水氧化分子催化剂提供理论依据.

关键词: 水氧化, 氧-氧成键, 析氧, 第一过渡周期金属, 电催化

Abstract:

Water oxidation is significant in both natural and artificial photosynthesis. In nature, water oxidation occurs at the oxygen-evolving center of photosystem Ⅱ, and leads to the generation of oxygen, protons, and electrons. The last two are used for fixation of carbon dioxide to give carbohydrates. In artificial processes, the coupling of water oxidation to evolve O₂ and water reduction to evolve H₂ is known as water splitting, which is an attractive method for solar energy conversion and storage. Because water oxidation is a thermodynamically uphill reaction and is kinetically slow, this reaction causes a bottleneck in large-scale water splitting. As a consequence, the development of new and efficient water oxidation catalysts (WOCs) has attracted extensive attention. Recent efforts have identified a variety of mononuclear earth-abundant transition-metal complexes as active and stable molecular WOCs. This review article summarizes recent progress in research on mononuclear catalysts that are based on first-row transition-metal elements, namely manganese, iron, cobalt, nickel, and copper. Particular attention is paid to catalytic mechanisms and the key O-O bond formation steps. This information is critical for designing new catalysts that are highly efficient and stable.

Key words: Water oxidation, O-O bond formation, Oxygen evolution, First-row transition metal, Electrocatalysis

王妮, 郑浩铨, 张伟, 曹睿. 单核第一过渡周期金属水氧化催化剂[J]. 催化学报, 2018, 39(2): 228-244.

Ni Wang, Haoquan Zheng, Wei Zhang, Rui Cao. Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation[J]. Chinese Journal of Catalysis, 2018, 39(2): 228-244.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(17)63001-8

https://www.cjcatal.com/CN/Y2018/V39/I2/228

参考文献

[1] W. Zhang, W. Z. Lai, R. Cao, Chem. Rev, 2017, 117, 3717-3797.
[2] T. R. Cook, D. K. Dogutan, S. Y. Reece, Y. Surendranath, T. S. Teets, D. G. Nocera, Chem. Rev., 2010, 110, 6474-6502.
[3] R. Cao, W. Z. Lai, P. W. Du, Energy Environ. Sci., 2012, 5, 8134-8157.
[4] X. Liu, P. W. Du, R. Cao, Nat. Commun., 2013, 4, 2375.
[5] J. Qi, W. Zhang, R. Cao, Adv. Energy Mater., 2017, DOI:10.1002/aenm.201701620.
[6] D. Gust, T. A. Moore, A. L. Moore, Acc. Chem. Res., 2009, 42, 1890-1898.
[7] H. Dau, I. Zaharieva, Acc. Chem. Res., 2009, 42, 1861-1870.
[8] D. G. Nocera, Acc. Chem. Res., 2012, 45, 767-776.
[9] X. L. Li, H. T. Lei, X. J. Guo, X. L. Zhao, S. P. Ding, X. Q. Gao, W. Zhang, R. Cao, ChemSusChem, 2017, 10, 4632-4641.
[10] H. T. Lei, H. Y. Fang, Y. Z. Han, W. Z. Lai, X. F. Fu, R. Cao, ACS Catal., 2015, 5, 5145-5153.
[11] Y. Z. Han, H. Y. Fang, H. Z. Jing, H. L. Sun, H. T. Lei, W. Z. Lai, R. Cao, Angew. Chem. Int. Ed., 2016, 55, 5457-5462.
[12] X. Sala, S. Maji, R. Bofill, J. García-Antón, L. Escriche, A. Llobet, Acc. Chem. Res., 2014, 47, 504-516.
[13] M. D. Kärkäs, B. Åkermark, Dalton Trans., 2016, 45, 14421-14461.
[14] M. D. Kärkäs, O. Verho, E. V. Johnston, B. Åkermark, Chem. Rev., 2014, 114, 11863-12001.
[15] T. K. Michaelos, D. Y. Shopov, S. B. Sinha, L. S. Sharninghausen, K. J. Fisher, H. M. C. Lant, R. H. Crabtree, G. W. Brudvig, Acc. Chem. Res., 2017, 50, 952-959.
[16] J. D. Blakemore, R. H. Crabtree, G. W. Brudvig, Chem. Rev., 2015, 115, 12974-13005.
[17] Y. Z. Wu, M. X. Chen, Y. Z. Han, H. X. Luo, X. J. Su, M. T. Zhang, X. H. Lin, J. L. Sun, L. Wang, L. Deng, W. Zhang, R. Cao, Angew. Chem. Int. Ed., 2015, 54, 4870-4875.
[18] J. Qi, W. Zhang, R. J. Xiang, K. Q. Liu, H. Y. Wang, M. X. Chen, Y. Z. Han, R. Cao, Adv. Sci., 2015, 2, 1500199.
[19] M. X. Chen, Y. Z. Wu, Y. Z. Han, X. H. Lin, J. L. Sun, W. Zhang, R. Cao, ACS Appl. Mater. Interfaces, 2015, 7, 21852-21859.
[20] W. Zhang, J. Qi, K. Q. Liu, R. Cao, Adv. Energy Mater., 2016, 6, 1502489.
[21] D. Y. Guo, J. Qi, W. Zhang, R. Cao, ChemSusChem, 2017, 10, 394-400.
[22] W. Zhang, Y. Z. Wu, J. Qi, M. X. Chen, R. Cao, Adv. Energy Mater., 2017, 7, 1602547.
[23] Z. Gao, J. Qi, M. X. Chen, W. Zhang, R. Cao, Electrochim. Acta, 2017, 224, 412-418.
[24] D. Y. Guo, F. F. Chen, W. Zhang, R. Cao, Sci. Bull., 2017, 62, 626-632.
[25] S. H. Wan, J. Qi, W. Zhang, W. N. Wang, S. K. Zhang, K. Q. Liu, H. Q. Zheng, J. L. Sun, S. Y. Wang, R. Cao, Adv. Mater., 2017, 29, 1700286.
[26] J. Qi, W. Zhang, R. Cao, Chem. Commun., 2017, 53, 9277-9280.
[27] M. X. Chen, J. Qi, D. Y. Guo, H. T. Lei, W. Zhang, R. Cao, Chem. Commun., 2017, 53, 9566-9569.
[28] J. H. Yang, D. E. Wang, H. X. Han, C. Li, Acc. Chem. Res., 2013, 46, 1900-1909.
[29] X. Wang, Q. Xu, M. R. Li, S. Shen, X. L. Wang, Y. C. Wang, Z. C. Feng, J. Y. Shi, H. X. Han, C. Li, Angew. Chem. Int. Ed., 2012, 51, 13089-13092.
[30] S. S. Chen, Y. Qi, T. Hisatomi, Q. Ding, T. Asai, Z. Li, S. S. K. Ma, F. X. Zhang, K. Domen, C. Li, Angew. Chem. Int. Ed., 2015, 54, 8498-8501.
[31] Z. L. Wang, X. Zong, Y. Y. Gao, J. F. Han, Z. Q. Xu, Z. Li, C. M. Ding, S. Y. Wang, C. Li, ACS Appl. Mater. Interfaces, 2017, 9, 30696-30702.
[32] J. Q. Guan, D. Li, R. Si, S. Miao, F. X. Zhang, C. Li, ACS Catal., 2017, 7, 5983-5986.
[33] Z. L. Wang, J. F. Han, Z. Li, M. R. Li, H. Wang, X. Zong, C. Li, Adv. Energy Mater., 2016, 6, 1600864.
[34] T. T. Yao, R. T. Chen, J. J. Li, J. F. Han, W. Qin, H. Wang, J. Y. Shi, F. T. Fan, C. Li, J. Am. Chem. Soc., 2016, 138, 13664-13672.
[35] S. Y. Wang, Y. Y. Gao, S. Miao, T. F. Liu, L. C. Mu, R. G. Li, F. T. Fan, C. Li, J. Am. Chem. Soc., 2017, 139, 11771-11778.
[36] S. S. Chen, S. Shen, G. J. Liu, Y. Qi, F. X. Zhang, C. Li, Angew. Chem. Int. Ed., 2015, 54, 3047-3051.
[37] R. G. Li, F. X. Zhang, D. E. Wang, J. X. Yang, M. R. Li, J. Zhu, X. Zhou, H. X. Han, C. Li, Nat. Commun., 2013, 4, 1432.
[38] Y. Jiang, F. Li, F. Huang, B. B. Zhang, L. C. Sun, Chin. J. Catal., 2013, 34, 1489-1495.
[39] X. H. An, D. Shin, J. D. Ocon, J. K. Lee, Y. I. Son, J. Lee, Chin. J. Catal., 2014, 35, 891-895.
[40] Z. Liu, Y. Gao, Z. Yu, M. Zhang, J. H. Liu. Chin. J. Catal., 2015, 36, 1742-1749.
[41] C. Zhen, T. T. Wu, M. W. Kadi, I. Ismail, G. Liu, H. M. Cheng, Chin. J. Catal., 2015, 36, 2171-2177.
[42] X. Q. Du, J. W. Huang, Y. Y. Feng, Y. Ding, Chin. J. Catal., 2016, 37, 123-134.
[43] Y. B. Huang, M. Zhang, P. Liu, F. L. Cheng, L. S. Wang, Chin. J. Catal., 2016, 37, 1249-1256.
[44] L. Qian, P. F. Liu, L. Zhang, C. W. Wang, S. Yang, L. R. Zheng, A. P. Chen, H. G. Yang, Chin. J. Catal., 2017, 38, 1045-1051.
[45] X. Leng, K. H. Wu, B. J. Su, L. Y. Jang, I. R. Gentle, D. W. Wang, Chin. J. Catal., 2017, 38, 1021-1028.
[46] Y. Y. Wang, D. D. Liu, Z. J. Liu, C. Xie, J. Huo, S. Y. Wang, Chem. Commun., 2016, 52,12614-12617.
[47] L. Tao, C. Y. Lin, S. Dou, S. Feng, D. W. Chen, D. D. Liu, J. Huo, Z. H. Xia, S. Y. Wang, Nano Energy, 2017, 41, 417-425.
[48] S. Y. Wang, S. P. Jiang, Natl. Sci. Rev., 2017, 4, 163-166.
[49] Y. Z. Wu, L. Wang, M. X. Chen, Z. X. Jin, W. Zhang, R. Cao, ChemSusChem, 2017, 10, 4699-4703.
[50] D. G. H. Hetterscheid, J. N. H. Reek, Angew. Chem. Int. Ed., 2012, 51, 9740-9747.
[51] D. J. Wasylenko, R. D. Palmer, C. P. Berlinguette, Chem. Commun., 2013, 49, 218-227.
[52] J. J. Concepcion, J. W. Jurss, J. L. Templeton, T. J. Meyer, J. Am. Chem. Soc., 2008, 130, 16462-16463.
[53] D. J. Wasylenko, C. Ganesamoorthy, M. A. Henderson, B. D. Koivisto, H. D. Osthoff, C. P. Berlinguette, J. Am. Chem. Soc., 2010, 132, 16094-16106.
[54] J. J. Concepcion, M. K. Tsai, J. T. Muckerman, T. J. Meyer, J. Am. Chem. Soc., 2010, 132, 1545-1557.
[55] D. E. Polyansky, J. T. Muckerman, J. Rochford, R. F. Zong, R. P. Thummel, E. Fujita, J. Am. Chem. Soc., 2011, 133, 14649-14665.
[56] S. Roeser, P. Farràs, F. Bozoglian, M. Martínez-Belmonte, J. Benet-Buchholz, A. Llobet, ChemSusChem, 2011, 4, 197-207.
[57] H. Yamazaki, T. Hakamata, M. Komi, M. Yagi, J. Am. Chem. Soc., 2011, 133, 8846-8849.
[58] M. Murakami, D. C. Hong, T. Suenobu, S. Yamaguchi, T. Ogura, S. Fukuzumi, J. Am. Chem. Soc., 2011, 133, 11605-11613.
[59] L. P. Wang, Q. Wu, T. Van Voorhis, Inorg. Chem., 2010, 49, 4543-4553.
[60] B. Radaram, J. A. Ivie, W. M. Singh, R. M. Grudzien, J. H. Reibenspies, C. E. Webster, X. Zhao, Inorg. Chem., 2011, 50, 10564-10571.
[61] J. J. Concepcion, J. W. Jurss, M. R. Norris, Z. F. Chen, J. L. Templeton, T. J. Meyer, Inorg. Chem., 2010, 49, 1277-1279.
[62] D. J. Wasylenko, C. Ganesamoorthy, B. D. Koivisto, M. A. Henderson, C. P. Berlinguette, Inorg. Chem., 2010, 49, 2202-2209.
[63] D. J. Wasylenko, C. Ganesamoorthy, M. A. Henderson, C. P. Berlinguette, Inorg. Chem., 2011, 50, 3662-3672.
[64] L. L. Duan, Y. H. Xu, P. Zhang, M. Wang, L. C. Sun, Inorg. Chem., 2010, 49, 209-215.
[65] J. D. Blakemore, N. D. Schley, D. Balcells, J. F. Hull, G. W. Olack, C. D. Incarvito, O. Eisenstein, G. W. Brudvig, R. H. Crabtree, J. Am. Chem. Soc., 2010, 132, 16017-16029.
[66] J. F. Hull, D. Balcells, J. D. Blakemore, C. D. Incarvito, O. Eisenstein, G. W. Brudvig, R. H. Crabtree, J. Am. Chem. Soc., 2009, 131, 8730-8731.
[67] G. F. Moore, J. D. Blakemore, R. L. Milot, J. F. Hull, H. E. Song, L. Cai, C. A. Schmuttenmaer, R. H. Crabtree, G. W. Brudvig, Energy Environ. Sci., 2011, 4, 2389-2392.
[68] A. Savini, G. Bellachioma, G. Ciancaleoni, C. Zuccaccia, D. Zuccaccia, A. Macchioni, Chem, Commun., 2010, 46, 9218-9219.
[69] D. G. H. Hetterscheid, J. N. H. Reek, Chem. Commun., 2011, 47, 2712-2714.
[70] N. D. Schley, J. D. Blakemore, N. K. Subbaiyan, C. D. Incarvito, F. D'Souza, R. H. Crabtree, G. W. Brudvig, J. Am. Chem. Soc., 2011, 133, 10473-10481.
[71] K. N. Ferreira, T. M. Iverson, K. Maghlaoui, J. Barber, S. Iwata, Science, 2004, 303, 1831-1838.
[72] B. Loll, J. Kern, W. Saenger, A. Zouni, J. Biesiadka, Nature, 2005, 438, 1040-1044.
[73] Y. Umena, K. Kawakami, J. R. Shen, N. Kamiya, Nature, 2011, 473, 55-61.
[74] Y. Gao, J. H. Liu, M. Wang, Y. Na, B. Åkermark, L. C. Sun, Tetrahedron, 2007, 63, 1987-1994.
[75] T. Privalov, L. C. Sun, B. Åkermark, J. H. Liu, Y. Gao, M. Wang, Inorg. Chem., 2007, 46, 7075-7086.
[76] Y. Gao, T. Åkermark, J. H. Liu, L. C. Sun, B. Åkermark, J. Am. Chem. Soc., 2009, 131, 8726-8727.
[77] B. Lassalle-Kaiser, C. Hureau, D. A. Pantazis, Y. Pushkar, R. Guillot, V. K. Yachandra, J. Yano, F. Neese, E. Anxolabéhère-Mallart, Energy Environ. Sci., 2010, 3, 924-938.
[78] R. Gupta, T. Taguchi, B. Lassalle-Kaiser, E. L. Bominaar, J. Yano, M. P. Hendrich, A. S. Borovik, Proc. Natl. Acad. Sci. USA, 2015, 112, 5319-5324.
[79] W. T. Lee, S. B. Muñoz Ⅲ, D. A. Dickie, J. M. Smith, Angew. Chem. Int. Ed., 2014, 53, 9856-9859.
[80] D. W. Crandell, S. Xu, J. M. Smith, M. H. Baik, Inorg. Chem., 2017, 56, 4435-4445.
[81] Y. Y. Li, K. Ye, P. E. M. Siegbahn, R. Z. Liao, ChemSusChem, 2017, 10, 903-911.
[82] M. A. Luna, F. Moyano, L. Sereno, F. D'Eramo, Electrochim. Acta, 2014, 135, 301-310.
[83] W. Schöfberger, F. Faschinger, S. Chattopadhyay, S. Bhakta, B. Mondal, J. A. A. W. Elemans, S. Müllegger, S. Tebi, R. Koch, F. Klappenberger, M. Paszkiewicz, J. V. Barth, E. Rauls, H. Aldahhak, W. G. Schmidt, A. Dey, Angew. Chem. Int. Ed., 2016, 55, 2350-2355.
[84] W. C. Ellis, N. D. McDaniel, S. Bernhard, T. J. Collins, J. Am. Chem. Soc., 2010, 132, 10990-10991.
[85] F. T. de Oliveira, A. Chanda, D. Banerjee, X. P. Shan, S. Mondal, L. Que Jr, E. L. Bominaar, E. Münck, T. J. Collins, Science, 2007, 315, 835-838
[86] M. Z. Ertem, L. Gagliardi, C. J. Cramer, Chem. Sci., 2012, 3, 1293-1299.
[87] R. Z. Liao, X. C. Li, P. E. M. Siegbahn, Eur. J. Inorg. Chem., 2014, 728-741.
[88] E. L. Demeter, S. L. Hilburg, N. R. Washburn, T. J. Collins, J. R. Kitchin, J. Am. Chem. Soc., 2014, 136, 5603-5606.
[89] C. Panda, J. Debgupta, D. D. Díaz, K. K. Singh, S. S. Gupta, B. B. Dhar, J. Am. Chem. Soc., 2014, 136, 12273-12282.
[90] J. L. Fillol, Z. Codolà, I. Garcia-Bosch, L. Gómez, J. J. Pla, M. Costas, Nat. Chem., 2011, 3, 807-813.
[91] Z. Codolà, I. Garcia-Bosch, F. Acuña-Parés, I. Prat, J. M. Luis, M. Costas, J. Lloret-Fillol, Chem. Eur. J., 2013, 19, 8042-8047.
[92] Z. Codolà, L. Gómez, S. T. Kleespies, L. Que Jr, M. Costas, J. Lloret-Fillol, Nat. Commun., 2015, 6, 5865.
[93] B. M. Klepser, B. M. Bartlett, J. Am. Chem. Soc., 2014, 136, 1694-1697.
[94] W. A. Hoffert, M. T. Mock, A. M. Appel, J. Y. Yang, Eur. J. Inorg. Chem., 2013, 3846-3857.
[95] D. C. Hong, S. Mandal, Y. Yamada, Y. M. Lee, W. Nam, A. Llobet, S. Fukuzumi, Inorg. Chem., 2013, 52, 9522-9531.
[96] G. Panchbhai, W. M. Singh, B. Das, R. T. Jane, A. Thapper, Eur. J. Inorg. Chem., 2016, 3262-3268.
[97] W. P. To, T. W. S. Chow, C. W. Tse, X. G. Guan, J. S. Huang, C. M. Che, Chem. Sci., 2015, 6, 5891-5903.
[98] L. D. Wickramasinghe, R. W. Zhou, R. F. Zong, P. Vo, K. J. Gagnon, R. P. Thummel, J. Am. Chem. Soc., 2015, 137, 13260-13263.
[99] B. Das, A. Orthaber, S. Ott, A. Thapper, ChemSusChem, 2016, 9, 1178-1186.
[100] M. K. Coggins, M. T. Zhang, A. K. Vannucci, C. J. Dares, T. J. Meyer, J. Am. Chem. Soc., 2014, 136, 5531-5534.
[101] D. K. Dogutan, R. McGuire Jr, D. G. Nocera, J. Am. Chem. Soc., 2011, 133, 9178-9180.
[102] M. Z. Ertem, C. J. Cramer, Dalton Trans., 2012, 41, 12213-12219.
[103] W. Z. Lai, R. Cao, G. Dong, S. Shaik, J. N. Yao, H. Chen, J. Phys. Chem. Lett., 2012, 3, 2315-2319.
[104] B. Wang, Y. M. Lee, W. Y. Tcho, S. Tussupbayev, S. T. Kim, Y. Kim, M. S. Seo, K. B. Cho, Y. Dede, B. C. Keegan, T. Ogura, S. H. Kim, T. Ohta, M. H. Baik, K. Ray, J. Shearer, W. Nam, Nat. Commun., 2017, 8, 14839.
[105] H. T. Lei, A. L. Han, F. W. Li, M. N. Zhang, Y. Z. Han, P. W. Du, W. Z. Lai, R. Cao, Phys. Chem. Chem. Phys., 2014, 16, 1883-1893.
[106] L. Xu, H. T. Lei, Z. Y. Zhang, Z. Yao, J. F. Li, Z. Y. Yu, R. Cao, Phys. Chem. Chem. Phys., 2017, 19, 9755-9761.
[107] H. L. Sun, Y. Z. Han, H. T. Lei, M. X. Chen, R. Cao, Chem. Commun., 2017, 53, 6195-6198.
[108] H. T. Lei, C. Y. Liu, Z. J. Wang, Z. Y. Zhang, M. N. Zhang, X. M. Chang, W. Zhang, R, Cao, ACS Catal., 2016, 6, 6429-6437.
[109] Z. J. Wang, H. T. Lei, R. Cao, M. N. Zhang, Electrochim. Acta, 2015, 171, 81-88.
[110] A. Han, H. X. Jia, H. Ma, S. F. Ye, H. T. Wu, H. T. Lei, Y. Z. Han, R. Cao, P. W. Du, Phys. Chem. Chem. Phys., 2014, 16, 11209-11217.
[111] D. Wang, J. T. Groves, Proc. Natl. Acad. Sci. USA, 2013, 110, 15579-15584.
[112] T. Nakazono, A. R. Parent, K. Sakai, Chem. Commun., 2013, 49, 6325-6327.
[113] T. Nakazono, A. R. Parent, K. Sakai, Chem. Eur. J., 2015, 21, 6723-6726.
[114] D. J. Wasylenko, C. Ganesamoorthy, J. Borau-Garcia, C. P. Berlinguette, Chem. Commun., 2011, 47, 4249-4251.
[115] D. J. Wasylenko, R. D. Palmer, E. Schott, C. P. Berlinguette, Chem. Commun., 2012, 48, 2107-2109.
[116] B. Das, A. Orthaber, S. Ott, A. Thapper, Chem. Commun., 2015, 51, 13074-13077.
[117] I. Siewert, J. Galezowska, Chem. Eur. J., 2015, 21, 2780-2784.
[118] Y. K. Zhao, J. Q. Lin, Y. D. Liu, B. C. Ma, Y. Ding, M. D. Chen, Chem. Commun., 2015, 51, 17309-17312.
[119] H. A. Younus, N. Ahmad, A. H. Chughtai, M. Vandichel, M. Busch, K. Van Hecke, M. Yusubov, S. X. Song, F. Verpoort, ChemSusChem, 2017, 10, 862-875.
[120] R. Xiang, Y. Ding, J. W. Zhao, Chem. Asian J., 2014, 9, 3228-3237.
[121] R. Cao, H. Y. Ma, Y. V. Geletii, K. I. Hardcastle, C. L. Hill, Inorg. Chem., 2009, 48, 5596-5598.
[122] Y. Z. Han, Y. Z. Wu, W. Z. Lai, R. Cao, Inorg. Chem., 2015, 54, 5604-5613.
[123] M. Zhang, M. T. Zhang, C. Hou, Z. F. Ke, T. B. Lu, Angew. Chem. Int. Ed., 2014, 53, 13042-13048.
[124] G. Y. Luo, H. H. Huang, J. W. Wang, T. B. Lu, ChemSusChem, 2016, 9, 485-491.
[125] J. W. Wang, X. Q. Zhang, H. H. Huang, T. B. Lu, ChemCatChem, 2016, 8, 3287-3293.
[126] J. Masud, P. C. Ioannou, N. Levesanos, P. Kyritsis, M. Nath, ChemSusChem, 2016, 9, 3128-3132.
[127] L. Wang, L. L. Duan, R. B. Ambre, Q. Daniel, H. Chen, J. L. Sun, B. Das, A. Thapper, J. Uhlig, P. Dinér, L. C. Sun, J. Catal., 2016, 335, 72-78.
[128] S. M. Barnett, K. I. Goldberg, J. M. Mayer, Nat. Chem., 2012, 4, 498-502.
[129] T. Zhang, C. Wang, S. B. Liu, J. L. Wang, W. B. Lin, J. Am. Chem. Soc., 2014, 136, 273-281.
[130] M. T. Zhang, Z. F. Chen, P. Kang, T. J. Meyer, J. Am. Chem. Soc., 2013, 135, 2048-2051.
[131] J. S. Pap, L. Szyrwiel, D, Srankó, Z. Kerner, B. Setner, Z. Szewczuk, W. Malinka, Chem. Commun., 2015, 51, 6322-6324.
[132] P. Garrido-Barros, I. Funes-Ardoiz, S. Drouet, J. Benet-Buchholz, F. Maseras, A. Llobet, J. Am. Chem. Soc., 2015, 137, 6758-6761.
[133] K. J. Fisher, K. L. Materna, B. Q. Mercado, R. H. Crabtree, G. W. Brudvig, ACS Catal., 2017, 7, 3384-3387.
[134] M. K. Coggins, M. T. Zhang, Z. F. Chen, N. Song, T. J. Meyer, Angew. Chem. Int. Ed., 2014, 53, 12226-12230.
[135] R. J. Xiang, H. Y. Wang, Z. J. Xin, C. B. Li, Y. X. Lu, X. W. Gao, H. M. Sun, R. Cao, Chem. Eur. J., 2016, 22, 1602-1607.
[136] F. F. Chen, N. Wang, H. T. Lei, D. Y. Guo, H. F. Liu, Z. Y. Zhang, W. Zhang, W. Z. Lai, R. Cao, Inorg. Chem., 2017, 56, 13368-13375.

单核第一过渡周期金属水氧化催化剂

Mononuclear first-row transition-metal complexes as molecular catalysts for water oxidation

PDF

可视化

摘要/Abstract

引用本文

使用本文

扫码分享

参考文献

相关文章 15

编辑推荐

Metrics

[1]	唐小龙, 李锋, 李方, 江燕斌, 余长林. 单原子催化剂在光催化和电催化合成过氧化氢中的研究进展[J]. 催化学报, 2023, 52(9): 79-98.
[2]	石靖, 郭煜华, 谢飞, 章名田, 张洪涛. 氧化还原活性配体的电子效应对钌催化水氧化反应的影响[J]. 催化学报, 2023, 52(9): 271-279.
[3]	张季, 俞爱民, 孙成华. 非金属掺杂石墨烯异核双原子催化剂氮还原特性研究[J]. 催化学报, 2023, 52(9): 263-270.
[4]	胡金念, 田玲婵, 王海燕, 孟洋, 梁锦霞, 朱纯, 李隽. MXene负载3d金属单原子高效氮还原电催化剂的理论筛选[J]. 催化学报, 2023, 52(9): 252-262.
[5]	洪岩, 王琦, 阚子旺, 张禹烁, 郭晶, 李思琦, 刘松, 李斌. 电化学氮还原氨反应催化剂的最新研究进展[J]. 催化学报, 2023, 52(9): 50-78.
[6]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[7]	高晖, 张恭, 程东方, 王永涛, 赵静, 李晓芝, 杜晓伟, 赵志坚, 王拓, 张鹏, 巩金龙. 构建Cu台阶位促进电催化CO₂还原制醇类化学品的研究[J]. 催化学报, 2023, 52(9): 187-195.
[8]	邹心仪, 顾均. 酸性条件下二氧化碳高效电还原策略[J]. 催化学报, 2023, 52(9): 14-31.
[9]	王潇涵, 田汉, 余旭, 陈立松, 崔香枝, 施剑林. 非晶相电催化剂在电解水领域的研究进展[J]. 催化学报, 2023, 51(8): 5-48.
[10]	韩璟怡, 管景奇. 通过表面镧改性和体相锰掺杂协助钴尖晶石酸性下析氧[J]. 催化学报, 2023, 51(8): 1-4.
[11]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[12]	王元男, 王立娜, 张可新, 徐靖尧, 武倩楠, 谢周兵, 安伟, 梁宵, 邹晓新. 钙钛矿氧化物在水裂解反应中的电催化研究[J]. 催化学报, 2023, 50(7): 109-125.
[13]	周纳, 王家志, 张宁, 王志, 王恒国, 黄岗, 鲍迪, 钟海霞, 张新波. 富含缺陷的Cu@CuTCNQ复合材料增强电催化硝酸盐还原成氨[J]. 催化学报, 2023, 50(7): 324-333.
[14]	李轩, 蒋兴星, 孔艳, 孙建桔, 胡琪, 柴晓燕, 杨恒攀, 何传新. GaN/In₂O₃的界面工程用于高效电催化CO₂还原制备甲酸[J]. 催化学报, 2023, 50(7): 314-323.
[15]	Sang Eon Jun, Sungkyun Choi, Jaehyun Kim, Ki Chang Kwon, Sun Hwa Park, Ho Won Jang. 用于电化学能量转换反应的非贵金属单原子催化剂[J]. 催化学报, 2023, 50(7): 195-214.