绿色合成:制备沸石分子筛催化材料的新路线

催化学报 ›› 2019, Vol. 40 ›› Issue (s1): 26-29.

绿色合成:制备沸石分子筛催化材料的新路线

肖丰收

浙江大学化学系, 浙江杭州 310028

出版日期:2019-12-17 发布日期:2019-10-10
通讯作者: 肖丰收
基金资助:
国家自然科学基金（21333009）.

Green Synthesis: Novel Routes for Preparation of Zeolite Catalysts

XIAO Feng-Shou

Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang

Online:2019-12-17 Published:2019-10-10
Supported by:
This work was supported by the National Natural Science Foundation of China (21333009).

摘要/Abstract

摘要： 沸石分子筛广泛应用于石油化工以及精细化学品生产的过程中，它们一般都是通过水热合成路线制备的，该路线使用了大量的水作为溶剂，有时还需加入有机模板剂，从而导致了大量的废水与废气的排放.为了解决这些问题，我们发展了沸石的绿色合成路线，包括无有机模板的沸石晶种导向合成、无溶剂沸石合成、低成本有机模板合成、无锗合成等，这为将来沸石分子筛的可持续工业生产提供了可能，其中无有机模板合成富铝的Beta沸石已经成功地在BASF公司工业化生产.

关键词: 沸石分子筛, 绿色合成, 无有机模板合成, 无溶剂合成, 可持续工业生产

Abstract: Zeolites as highly efficient catalysts have been widely applied in conversion of oils and production of chemicals, which are normally prepared from hydrothermal routes. Because a large amount of water solvent is employed for the hydrothermal synthesis of zeolites in the presence of organic templates, it is usually formed a large amount of wastes such as polluted water and gases. To solve these issues, we have developed green routes for synthesis of zeolites, including zeolite organotemplate-free synthesis, solvent-free synthesis, use of low-cost templates, and Ge-free synthesis. These approaches offer a good opportunity for sustainable production of zeolites at an industrial scale. Among them, organotemplate-free synthesis of Al-rich Beta zeolite has been commercialized in BASF.

Key words: zeolite molecular sieves, green synthesis, organotemplate-free, solvent-free, sustainable production

肖丰收. 绿色合成:制备沸石分子筛催化材料的新路线[J]. 催化学报, 2019, 40(s1): 26-29.

XIAO Feng-Shou. Green Synthesis: Novel Routes for Preparation of Zeolite Catalysts[J]. Chinese Journal of Catalysis, 2019, 40(s1): 26-29.

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