催化学报 ›› 2019, Vol. 40 ›› Issue (s1): 43-50.

• 综述 • 上一篇    下一篇

羰基化学与精细化学品催化合成

石峰, 夏春谷   

  1. 中国科学院兰州化学物理研究所, 羰基合成与选择氧化国家重点实验室(OSSO), 甘肃兰州 730000
  • 出版日期:2019-12-17 发布日期:2019-10-10
  • 通讯作者: 夏春谷
  • 基金资助:
    国家自然科学基金(21633013,91745106,21802147);国家重点基础研究发展计划(2018YFB0604801);中国科学院前沿科学重点研究项目(QYZDJ-SSW-SLH051).

Carbonyl Chemistry and Catalytic Synthesis of Fine Chemicals

SHI Feng, XIA Chungu   

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China
  • Online:2019-12-17 Published:2019-10-10
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (21633013, 91745106, 21802147), the National Basic Research Program of China (2018YFB0604801), and Key Research Program of Frontier Sciences of CAS (QYZDJ-SSW-SLH051).

摘要: 羰基化学涉及到含羰分子的构建与转化.基于羰基构建与转化的精细化学品催化合成在化学化工领域占有重要地位,是精细化学品清洁、高效合成的重要手段.本文以中科院兰州化物所羰基合成与选择氧化国家重点实验室研究工作为基础,结合领域内其他团队的工作,较为系统地介绍羰基化学与精细化学品催化合成领域的进展,最后基于自身对该领域的理解,对其发展方向和前沿做出了展望.

关键词: 羰基化学, 羰基合成, 均相催化, 多相催化, 精细化学品

Abstract: Carbonyl chemistry involves the catalytic construction and conversion of carbonyl compounds, which plays an important tool in clean and economic synthesis of fine chemicals. This perspective highlights the recent research progresses on the topic includes the carbonyl compounds construction via catalytic carbonylation and selective oxidation, and the further catalytic conversion of carbonyl compounds to functional molecules and materials. Based on our own understanding, the frontiers and future of the topic are also presented.

Key words: carbonyl chemistry, oxo synthesis, homogeneous catalysis, heterogeneous catalysis, fine chemical synthesis