温和条件下氨的高效合成

摘要/Abstract

摘要： 合成氨工业关乎粮食生产、能源安全和环境保护，在国民经济中占有非常重要的地位.而建立在Haber-Bosch工艺基础上的合成氨工业是一个高能耗、高碳排放过程.随着对可持续发展和节能减排的迫切需求，传统合成氨工业的转型升级势在必行.针对这一重大社会需求，基于可再生能源的“绿色”合成氨新技术、新工艺正成为研发重点与热点.近年来，研究人员在多相催化、电/光催化、化学链合成氨等领域取得了诸多进展，提出了许多新的思路，为这一极具挑战性的研究课题注入了新的活力.本文就这些领域的研究现状及面临的挑战进行了分析，并简要介绍了国内外最新研究进展.

关键词: 合成氨, 多相催化, 化学链, 电催化, 光催化

Abstract: Ammonia synthesis process has a great impact on food production, energy security and environmental protection. The industrial ammonia synthesis based on the Haber-Bosch process, however, is an energy consuming and high emission process. Increasing efforts have been devoted to the development of new technologies and processes for "green" ammonia synthesis driven by renewable energies under mild conditions. In recent years, encouraging progresses have been made in the fields of heterogeneous catalysis, chemical looping, electro-and photo-chemical ammonia production, with significant advancements in fundamental understanding and breakthroughs. In this paper, the research status and challenges in this field are analyzed, and the recent achievements are highlighted.

Key words: ammonia synthesis, heterogeneous catalysis, chemical looping, electro-catalysis, photo-catalysis

郭建平, 鄢俊敏, 张礼知, 陈萍. 温和条件下氨的高效合成[J]. 催化学报, 2019, 40(s1): 57-63.

GUO Jianping, YAN Junmin, ZHANG Lizhi, CHEN Ping. Ammonia Synthesis under Mild Conditions[J]. Chinese Journal of Catalysis, 2019, 40(s1): 57-63.

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