原位表征技术在异相催化中的应用

摘要/Abstract

摘要： 随着催化科学的发展，如何发展新的表征技术与方法学，使之能够探测在真实化学环境下与催化性能有关的催化剂的物理化学性质，理解作为催化中心的催化活性位的构效关系，对于发展催化理论和促进产业发展都具有至关重要的意义.围绕目前异相催化发展中所关注的纳米制备和复杂表界面问题，我们针对性地探讨了原位透射电子显微镜和原位X射线光谱技术在现代异相催化领域的应用以及在基础研究中所取得的突破性成果，这些例子显示了先进的原位技术在理解催化剂构效关系和设计新型高效催化剂上的重要作用，未来会成为催化化学，甚至是物质科学研究不可或缺的手段.

关键词: 催化剂, 异相催化, 原位表征, 透射电子显微镜, X射线

Abstract: As the science of catalysis develops with an unprecedented pace in recent years, the quest for new characterization techniques and methodologies to detect physicochemical properties of catalysts related to their catalytic performance and so attain insightful understanding of structure-activity relationship has become of crucial importance in both fundamental research and industrial applications. This review briefly summaries the developments of environmental transmission electron microscopy and in-situ X-ray spectroscopy techniques with emphasis on their applications in the characterization of nanocatalysts and complex surfaces and interfaces in heterogeneous catalysis. These examples confirm the pivotal importance of in-situ techniques in understanding the structure-activity relationship in catalysis and also in facilitating the design of highly efficient catalysts.

Key words: catalyst, heterogeneous catalysis, in-situ characterization, transmission electron microscope, X-ray

卢发贵, 刘晰, 崔义, 陈立桅. 原位表征技术在异相催化中的应用[J]. 催化学报, 2019, 40(s1): 75-89.

LU Fagui, LIU Xi, CUI Yi, CHEN Liwei. Application of in-situ Characterization Techniques in Heterogenous Catalysis[J]. Chinese Journal of Catalysis, 2019, 40(s1): 75-89.

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