原位电化学表征技术

摘要/Abstract

摘要： 随着高效清洁能源需求的不断增长，基于电化学储能的电池技术受到了高度关注.能够实现时间和空间分辨的原位电化学表征技术是研究电化学过程的重要手段，对推动电化学储能领域的发展具有重要意义，是研究的热点和前沿.本文系统综述了国内外在原位电化学表征技术方面取得的进展，主要包括原位透射电镜表征技术、同步辐射X射线表征技术以及和频振动光谱表征技术；总结了这些原位表征技术发展的难点和挑战，并展望了它们的发展方向.

关键词: 电化学, 能源材料, 原位, 透射电镜, 同步辐射, X射线吸收谱, 和频振动光谱

Abstract: With increasing demand of clean energy, electrochemical energy storage technologies have attracted intensive research interest. In-situ electrochemical characterization with high temporal and spatial resolutions has become increasingly important for investigation of the electrochemical processes in close-to-real electrochemical energy storage devices. This paper reviews the progress of in-situ electrochemical characterization methodology, including in-situ transmission electron microscopy, synchrotron radiation X-ray spectroscopy, and sum frequency generation spectroscopy. The challenges facing in-situ electrochemical characterization and the prospects for further methodological development are presented.

Key words: electrochemistry, energy storage, in-situ characterization, transmission electron microscopy, synchrotron radiation, X-ray absorption spectroscopy, sum frequency generation spectroscopy

许国光, 王敏, 王健, 蔺洪振, 吴扬, 魏洋, 张跃钢. 原位电化学表征技术[J]. 催化学报, 2019, 40(s1): 187-199.

XU Guoguang, WANG Min, WANG Jian, LIN Hongzhen, WU Yang, WEI Yang, ZHANG Yuegang. In-situ Electrochemical Characterization Methodology[J]. Chinese Journal of Catalysis, 2019, 40(s1): 187-199.

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