催化加氢基础及应用技术研究的近期进展与未来趋势

摘要/Abstract

摘要： 催化加氢反应技术在化学制备与化工生产中应用极为广泛.本文对近年来规模工业大宗化学品生产以及精细化学品制备中催化加氢技术的基础与应用研究进展进行了简要的综述，包括石脑油裂解生产烯烃、对苯二甲酸、己内酰胺、聚苯乙烯、烷基苯、燃油脱硫等规模工业中的应用催化加氢技术，也概述了用于硝基、醛、酮、酯、α，β不饱和醛酮催化加氢等反应的催化剂研究现状；还对CO/CO₂催化加氢的反应进行了有限的讨论.希望以这些粗浅的见解，向广大同仁学习，共同把握相关研究发展趋势.

关键词: 催化加氢, 近期进展, 规模工业, 精细化学品, 催化材料

Abstract: Catalytic hydrogenation is a widely applied reaction technology in chemistry and chemical engineering. This paper has very briefly summarized the recent progresses on the study of catalytic hydrogenation used for manufactures in scalable industries such as C2/C3 olefins from naphta cracking, pure terephthalic acid, polyethylene, alkylbenzene, hydrodesulfurization of fuels and for preparations of fine chemicals such as the hydrogenation of nitro-, aldehyde, ketone, ester and α,β-unsaturated aldehydes and ketones and so on. A briefly discussion on the hydrogenation of CO/CO₂ is also involved. With these preliminary views and comments, the author hopes to master the development trend of catalysis with colleagues in the field of catalytic research.

Key words: catalytic hydrogenation, recent progress, scale industry, fine chemicals, catalytic materials

丁维平. 催化加氢基础及应用技术研究的近期进展与未来趋势[J]. 催化学报, 2019, 40(s1): 209-216.

DING Weiping. The Recent Progress and the Future Trend of the Fundamental and Applied Study on Catalytic Hydrogenation[J]. Chinese Journal of Catalysis, 2019, 40(s1): 209-216.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/

https://www.cjcatal.com/CN/Y2019/V40/Is1/209

参考文献

1 Studt F, Abild-Pedersen F, Bligaard T, Sørensen R Z, Christensen C H, Nørskov J K. Science, 2008, 320:1320
2 Zong B N, Meng X K, Mu M H, Zhang X X. Chin J Catal, 2013, 34:61
3 Gao Y L, Fang X C, Wang G, Cao F L, Li C H, Chen G. WO2008028348-A1, 2008; TW200821038-A, 2008; EP2047908-A1, 2009; EP2047908-A4, 2009; KR2009031916-A, 2009; IN200810797-P1, 2009; CA2658415-A1, 2008; JP2009544458-W, 2009; US2009308790-A1, 2009; MY142437-A, 2010; TW324529-B1, 2008; JP5086344-B2,2012; US8329610-B2, 2012; KR1311968-B1, 2013; SG149216-A1, 2014; SG149216-B, 2014; CA2658415-C, 2014; IN277428-A1, 2016; EP2047908-B1, 2017;
4 张志炳, 田洪舟, 张锋, 周政. 化工学报 (Zhang Z B, Tian H Z, Zhang F, Zhou Z, CIESC J), 2018, 69:44
5 Jiao F, Li J, Pan X L, Xiao J, Li H, Ma H, Wei M, Pan Y, Zhou Z, Li M, Miao S, Li J, Zhu Y, Xiao D, He T, Yang J, Qi F, Fu Q, Bao XH. Science, 2016, 351:1065
6 Cheng K, Gu B, Liu X, Kang J, Zhang Q H, Wang Y. Angew Chem In Ed, 2016, 55:4725
7 Zecevic J, Vanbutsele G, de Jong K P, Martens J A. Nature, 2015, 528:245
8 Behrens M, Studt F, Kasatkin I, Kühl S, Hävecker M, Abild-Pedersen F, Zander S, Girgsdies F, Kurr P, Kniep B L, Tovar M, Fischer R W, Nørskov J K, Schlögl R. Science, 2012, 336:893
9 Kattel S, Ramírez P J, Chen J G, Rodriguez J A, Liu P. Science, 2017, 355:1296
10 Cheng K, Zhou W, Kang J C, He S, Shi S L, Zhang Q H, Pan Y, Wen W, Wang Y. Chem, 2017, 3:334
11 Dong Y, Yang M, Li LL, Zhu T, Chen X D, Cheng H S. Int J Hydrogen Energy, 2019, 44:4919
12 Qiao B T, Wang A Q, Yang X F, Allard L F, Jiang Z, Cui Y T, Liu J Y, Li J, Zhang T. Nat Chem, 2011, 3:634
13 Liu P X, Zhao Y, Qin R X, Mo S G, Chen G X, Gu L, Chevrier D M, Zhang P, Guo Q, Zang D D, Wu B H, Fu G, Zheng N F. Science, 2016, 352:797
14 Vile G, Bridier B, Wichert J, Perez-Ramirez J. Angew Chem In Ed, 2012, 51:8620
15 Zhang S, Huang Z Q, Ma Y Y, Gao W, Li J, Cao FX, Li L. Chang C R, Qu YQ. Nat Commun, 2017, 8:15266
16 Wang Y B, Yang J, Gu R T, Peng L M, Guo X F, Xue N H, Zhu Y, Ding W P. ACS Catal, 2018, 8:6419
17 Marshall S T, O'Brien M, Oetter B, Corpuz A, Richards R M, Schwartz D K, Medlin J W. Nat Mater, 2010, 9:853
18 Gu J, Zhang Z Y, Hu P, Ding L P, Xue N H, Peng L M, Guo X F, Lin M, Ding W P. ACS Catal, 2015, 5:6893
19 Chen G X, Xu C F, Huang X Q, Ye J Y, Gu L, Li G, Tang Z C, Wu B H, Yang H Y, Zhao Z P, Zhou Z Y, Fu G, Zheng N F. Nat Mater, 2016, 15:564
20 Fu T, Wang M, Cai W M, Cui Y M, Gao F, Peng L M, Chen W, Ding W P. ACS Catal, 2014, 4:2536

[1]	李金鹏, 陈洁, 郑庆舒, 屠波, 涂涛. 配位组装构筑的磁性核壳复合材料促进CO₂高值催化转化[J]. 催化学报, 2023, 48(5): 258-266.
[2]	杨成功, 王冬娥, 黄蓉, 韩健强, 塔娜, 马怀军, 曲炜, 潘振栋, 王从新, 田志坚. 高效稳定的MoS₂-TiO₂纳米复合催化剂用于浆态床菲催化加氢[J]. 催化学报, 2023, 46(3): 125-136.
[3]	焦龙, 江海龙. 金属有机框架材料在催化领域的研究现状与展望[J]. 催化学报, 2023, 45(2): 1-5.
[4]	顾宇, 王磊, 徐柏庆, 施慧. 金属-水界面催化的分子机制: 加氢与氧化反应[J]. 催化学报, 2023, 54(11): 1-55.
[5]	高敦峰, 李合肥, 魏鹏飞, 王毅, 汪国雄, 包信和. 能源催化材料的电化学合成[J]. 催化学报, 2022, 43(4): 1001-1016.
[6]	周灵, 李莹莹, 逯宇轩, 王双印, 邹雨芹. pH诱导的铜电极上糠醛选择性电催化氢化[J]. 催化学报, 2022, 43(12): 3142-3153.
[7]	张文彪, 石杨豪, 杨洋, 谭静雯, 高庆生. 电催化糠醛加氢反应中钯纳米晶的晶面效应[J]. 催化学报, 2022, 43(12): 3116-3125.
[8]	杨彬, 邓威, 郭利民, 石原逹己. 铜-氧化铈固溶体催化剂用于二氧化碳催化加氢制甲醇[J]. 催化学报, 2020, 41(9): 1348-1359.
[9]	石峰, 夏春谷. 羰基化学与精细化学品催化合成[J]. 催化学报, 2019, 40(s1): 43-50.
[10]	王栋, 陈建富, 曹宵鸣, 王海丰, 龚学庆, 胡培君. 催化理论研究进展与展望[J]. 催化学报, 2019, 40(s1): 124-128.
[11]	詹望成, 郭耘, 龚学庆, 郭杨龙, 王艳芹, 卢冠忠. 稀土催化材料的应用及研究进展[J]. 催化学报, 2014, 35(8): 1238-1250.
[12]	张勤生, 李海峰, 高平, 王来来. PVP-NiB非晶态催化剂的制备和催化苯酚及其衍生物加氢反应性能[J]. 催化学报, 2014, 35(11): 1793-1799.
[13]	谢在库. 从催化导向性基础研究到工业应用的若干创新思路与实践 ——庆祝闵恩泽先生 90 华诞[J]. 催化学报, 2013, 34(1): 209-216.
[14]	李大东. 支撑未来炼油工业发展的若干关键技术[J]. 催化学报, 2013, 34(1): 48-60.
[15]	丁维平, 郭学锋, 莫敏, 祝艳, 陈懿. 非晶态合金纳米管的制备及其催化性能研究进展[J]. 催化学报, 2010, 31(8): 887-894.