基于分子水氧化催化剂光电分解水的研究进展

摘要/Abstract

摘要： 模拟光合作用将水分解为氢气和氧气是制备太阳能燃料的潜在手段，而水氧化反应是全分解水反应中最具挑战的步骤.作为光合作用体系Ⅱ释氧活性中心的功能模型配合物，分子水氧化催化剂的出现为解决这一难题提供了更多方案.尽管近年来围绕分子水氧化催化剂的研究取得了巨大的进展，但是构建基于分子催化剂的光解水器件仍然极具挑战.基于以上背景，本文系统地综述了国内外围绕分子水氧化催化剂在电解水和光电分解水器件的构筑方面所取得的最新研究进展，总结了构建相关杂化电极和光电极的策略与原则.这些成果表明，分子工程是建立高效人工光合作用体系至关重要的手段.

关键词: 人工光合作用, 水分解, 分子水氧化催化剂, 电催化, 光阳极, 染料敏化

Abstract: Solar water splitting into hydrogen and oxygen has been considered as a promising method for production of solar fuel. A key challenge in overall water splitting is the catalytic water oxidation. And the emergence of molecular water oxidation catalysts (WOCs) has provided an opportunity to mimic the function of the oxygen-evolving complex (OEC) of photosystem Ⅱ in nature and an alternative way for artificial photosynthesis. Despite progress made on molecular approaches to solar energy conversion, construction of molecularly-based artificial photosynthetic devices that enable simultaneous oxygen and hydrogen evolution remains a significant challenge. This paper reviews recent progress in electrochemical and photoelectrochemical water splitting based on molecular WOCs. Strategies and principles for hybrid anodes and photoanodes design were summarized. And these results show great promise for improving the efficiency of artificial photosynthesis by taking advantage of molecular engineering.

Key words: artificial photosynthesis, water splitting, molecular water oxidation catalyst, nelectrocatalysis, photoanode, dye-sensitized

朱勇, 李斐, 孙立成. 基于分子水氧化催化剂光电分解水的研究进展[J]. 催化学报, 2019, 40(s1): 227-234.

ZHU Yong, LI Fei, SUN Licheng. Recent Progress on Photoelectrochemical Water Splitting Based on Molecular Water Oxidation Catalysts[J]. Chinese Journal of Catalysis, 2019, 40(s1): 227-234.

×
扫码分享

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.cjcatal.com/CN/

https://www.cjcatal.com/CN/Y2019/V40/Is1/227

参考文献

1 Li F, Yang H, Li W, Sun L. Joule, 2018, 2:36
2 Frischmann P D, Mahata K, Wurthner F. Chem Soc Rev, 2013, 42:1847
3 Jean J, Brown P R, Jaffe R L, Buonassisi T, Bulovi? V. Energy Environ Sci, 2015, 8:1200
4 Tachibana Y, Vayssieres L, Durrant J R. Nat Photonics, 2012, 6:511
5 Duan L, Wang L, Li F, Li F, Sun L. Acc Chem Res, 2015, 48:2084
6 Yang J, Wang D, Han H, Li C. Acc Chem Res, 2013, 46:1900
7 Gersten S W, Samuels G J, Meyer T J. J Am Chem Soc, 1982, 104:4029
8 Karkas M D, Verho O, Johnston E V, Akermark B. Chem Rev, 2014, 114:11863
9 Duan L, Fischer A, Xu Y, Sun L. J Am Chem Soc, 2009, 131:10397
10 Duan L, Bozoglian F, Mandal S, Stewart B, Privalov T, Llobet A, Sun L. Nat Chem, 2012, 4:418
11 Dogutan D K, McGuire R, Nocera D G. J Am Chem Soc, 2011, 133:9178
12 Barnett S M, Goldberg K I, Mayer J M. Nat Chem, 2012, 4:498
13 Garrido-Barros P, Funes-Ardoiz I, Drouet S, Benet-Buchholz J, Maseras F, Llobet A. J Am Chem Soc, 2015, 137:6758
14 Han X, Li Y, Zhang Z, Tan H, Lu Y, Wang E. J Am Chem Soc, 2015, 137:5486
15 Pan Z, Mora-Sero I, Shen Q, Zhang H, Li Y, Zhao K, Wang J, Zhong X, Bisquert J. J Am Chem Soc, 2014, 136:9203
16 Du H, Chen S, Su X, Jiao L, Zhang M. J Am Chem Soc, 2018, 140:1557
17 Su X, Gao M, Jiao L, Liao R, Siegbahn P E, Cheng J, Zhang M. Angew Chem Int Ed, 2015, 54:4909
18 Liu Y, Han Y, Zhang Z, Zhang W, Lai W, Wang Y, Cao R. Chem Sci, 2019, 10:2613
19 Okamura M, Kondo M, Kuga R, Kurashige Y, Yanai T, Hayami S, Praneeth V K, Yoshida M, Yoneda K, Kawata S, Masaoka S. Nature, 2016, 530:465
20 Gafney H D, Adamson A W. J Am Chem Soc, 1972, 94:8238
21 Li F, Jiang Y, Zhang B, Huang F, Gao Y, Sun L. Angew Chem Int Ed, 2012, 51:2417
22 Li H, Li F, Zhang B, Zhou X, Yu F, Sun L. J Am Chem Soc, 2015, 137:4332
23 Luo J S, Im J H, Mayer M T, Schreier M, Nazeeruddin M K, Park N G, Tilley S D, Fan H J, Gratzel M. Science, 2014, 345:1593
24 Cox C R, Lee J Z, Nocera D G, Buonassisi T. Proc Natl Acad Sci USA, 2014, 111:14057
25 Yagi M, Kinoshita K, Kaneko M. J Phys Chem, 1996, 100:11098
26 Zhang B, Li F, Yu F, Wang X, Zhou X, Li H, Jiang Y, Sun L. ACS Catal, 2014, 4:804
27 Wang L, Fan K, Daniel Q, Duan L, Li F, Philippe B, Rensmo H, Chen H, Sun J, Sun L. Chem Commun, 2015, 51:7883
28 Tong L, Gothelid M, Sun L. Chem Commun, 2012, 48:10025
29 Gerken J B, Rigsby M L, Ruther R E, Perez-Rodriguez R J, Guzei I A, Hamers R J, Stahl S S. Inorg Chem, 2013, 52:2796
30 Liu F, Cardolaccia T, Hornstein B J, Schoonover J R, Meyer T J. J Am Chem Soc, 2007, 129:2446
31 Vannucci A K, Alibabaei L, Losego M D, Concepcion J J, Kalanyan B, Parsons G N, Meyer T J. Proc Natl Acad Sci USA, 2013, 110:20918
32 Joya K S, Subbaiyan N K, D'Souza F, de Groot H J. Angew Chem Int Ed, 2012, 51:9601
33 Materna K L, Rudshteyn B, Brennan B J, Kane M H, Bloomfield A J, Huang D L, Shopov D Y, Batista V S, Crabtree R H, Brudvig G W. ACS Catal, 2016, 6:5371
34 Toma F M, Sartorel A, Iurlo M, Carraro M, Parisse P, Maccato C, Rapino S, Gonzalez B R, Amenitsch H, Da Ros T, Casalis L, Goldoni A, Marcaccio M, Scorrano G, Scoles G, Paolucci F, Prato M, Bonchio M. Nat Chem, 2010, 2:826
35 Li F, Zhang B, Li X, Jiang Y, Chen L, Li Y, Sun L. Angew Chem Int Ed, 2011, 50:12276
36 McCool N S, Robinson D M, Sheats J E, Dismukes G C. J Am Chem Soc, 2011, 133:11446
37 Wang J W, Sahoo P, Lu T B. ACS Catal, 2016, 6:5062
38 Xia L, Bai J, Li J, Zeng Q, Li L, Zhou B. Appl Catal B, 2017, 204:127
39 Fujishima A, Honda K. Nature, 1972, 238:37
40 Chen X, Ren X, Liu Z, Zhuang L, Lu J. Electrochem Commun, 2013, 27:148
41 Zhong D K, Zhao S, Polyansky D E, Fujita E. J Catal, 2013, 307:140
42 Liu B, Li J, Wu H, Liu W, Jiang X, Li Z, Chen B, Tung C, Wu L. ACS Appl Mater Interfaces, 2016, 8:18577
43 Ye S, Ding C, Chen R, Fan F, Fu P, Yin H, Wang X, Wang Z, Du P, Li C. J Am Chem Soc, 2018, 140:3250
44 Wang Y, Li F, Zhou X, Yu F, Du J, Bai L, Sun L. Angew Chem Int Ed, 2017, 56:6911
45 Li F, Fan K, Wang L, Daniel Q, Duan L, Sun L. ACS Catal, 2015, 5:3786
46 Jiang W, Yang X, Li F, Zhang Q, Li S, Tong H, Jiang Y, Xia L. Chem Commun, 2019, 55:1414
47 Zhai P, Haussener S, Ager J, Sathre R, Walczak K, Greenblatt J, McKone T. Energy Environ Sci, 2013, 6:2380
48 Brennaman M K, Dillon R J, Alibabaei L, Gish M K, Dares C J, Ashford D L, House R L, Meyer G J, Papanikolas J M, Meyer T J. J Am Chem Soc, 2016, 138:13085
49 Wang P, Zakeeruddin S M, Moser J E, Nazeeruddin M K, Sekiguchi T, Grätzel M. Nat Mater, 2003, 2:402
50 Brimblecombe R, Koo A, Dismukes G C, Swiegers G F, Spiccia L. J Am Chem Soc, 2010, 132:2892
51 Hocking R K, Brimblecombe R, Chang L Y, Singh A, Cheah M H, Glover C, Casey W H, Spiccia L. Nat Chem, 2011, 3:461
52 Li L, Duan L, Xu Y, Gorlov M, Hagfeldt A, Sun L. Chem Commun, 2010, 46:7307
53 Gao Y, Ding X, Liu J, Wang L, Lu Z, Li L, Sun L. J Am Chem Soc, 2013, 135:4219
54 Wu L, Eberhart M, Nayak A, Brennaman M K, Shan B, Meyer T J. J Am Chem Soc, 2018, 140:15062
55 Bettis S E, Ryan D M, Gish M K, Alibabaei L, Meyer T J, Waters M L, Papanikolas J M. J Phys Chem C, 2014, 118:6029
56 Sherman B D, Ashford D L, Lapides A M, Sheridan M V, Wee K R, Meyer T J. J Phys Chem Lett, 2015, 6:3213
57 Wang L, Ashford D L, Thompson D W, Meyer T J, Papanikolas J M. J Phys Chem C, 2013, 117:24250
58 Song W, Glasson C R K, Luo H, Hanson K, Brennaman M K, Concepcion J J, Meyer T J. J Phys Chem Lett, 2011, 2:1808
59 Yamamoto M, Wang L, Li F, Fukushima T, Tanaka K, Sun L, Imahori H. Chem Sci, 2016, 7:1430
60 Alibabaei L, Brennaman M K, Norris M R, Kalanyan B, Song W, Losego M D, Concepcion J J, Binstead R A, Parsons G N, Meyer T J. Proc Natl Acad Sci USA, 2013, 110:20008
61 Li F, Fan K, Xu B, Gabrielsson E, Daniel Q, Li L, Sun L. J Am Chem Soc, 2015, 137:9153
62 Wang D, Marquard S L, Troian-Gautier L, Sheridan M V, Sherman B D, Wang Y, Eberhart M S, Farnum B H, Dares C J, Meyer T J. J Am Chem Soc, 2018, 140:719
63 Sheridan M V, Sherman B D, Coppo R L, Wang D, Marquard S L, Wee K R, Murakami Iha N Y, Meyer T J. ACS Energy Lett, 2016, 1:231
64 Wang D, Sheridan M V, Shan B, Farnum B H, Marquard S L, Sherman B D, Eberhart M S, Nayak A, Dares C J, Das A K, Bullock R M, Meyer T J. J Am Chem Soc, 2017, 139:14518
65 Alibabaei L, Dillon R J, Reilly C E, Brennaman M K, Wee K R, Marquard S L, Papanikolas J M, Meyer T J. ACS Appl Mater Interfaces, 2017, 9:39018
66 Eberhart M S, Wang D, Sampaio R N, Marquard S L, Shan B, Brennaman M K, Meyer G J, Dares C, Meyer T J. J Am Chem Soc, 2017, 139:16248
67 Wang D, Eberhart M S, Sheridan M V, Hu K, Sherman B D, Nayak A, Wang Y, Marquard S L, Dares C J, Meyer T J. Proc Natl Acad Sci U S A, 2018, 115:8523
68 Suryani O, Higashino Y, Mulyana J Y, Kaneko M, Hoshi T, Shigaki K, Kubo Y. Chem Commun, 2017, 53:6784
69 Ogunsolu O O, Murphy I A, Wang J, Das A, Hanson K. ACS Appl Mater Interfaces, 2016, 8:28633

[1]	唐小龙, 李锋, 李方, 江燕斌, 余长林. 单原子催化剂在光催化和电催化合成过氧化氢中的研究进展[J]. 催化学报, 2023, 52(9): 79-98.
[2]	石靖, 郭煜华, 谢飞, 章名田, 张洪涛. 氧化还原活性配体的电子效应对钌催化水氧化反应的影响[J]. 催化学报, 2023, 52(9): 271-279.
[3]	张季, 俞爱民, 孙成华. 非金属掺杂石墨烯异核双原子催化剂氮还原特性研究[J]. 催化学报, 2023, 52(9): 263-270.
[4]	胡金念, 田玲婵, 王海燕, 孟洋, 梁锦霞, 朱纯, 李隽. MXene负载3d金属单原子高效氮还原电催化剂的理论筛选[J]. 催化学报, 2023, 52(9): 252-262.
[5]	洪岩, 王琦, 阚子旺, 张禹烁, 郭晶, 李思琦, 刘松, 李斌. 电化学氮还原氨反应催化剂的最新研究进展[J]. 催化学报, 2023, 52(9): 50-78.
[6]	刘勇, 赵晓丽, 隆昶, 王晓艳, 邓邦为, 李康璐, 孙艳娟, 董帆. 原位构筑动态Cu/Ce(OH)_x界面用于高活性、高选择性和高稳定性硝酸盐还原合成氨[J]. 催化学报, 2023, 52(9): 196-206.
[7]	高晖, 张恭, 程东方, 王永涛, 赵静, 李晓芝, 杜晓伟, 赵志坚, 王拓, 张鹏, 巩金龙. 构建Cu台阶位促进电催化CO₂还原制醇类化学品的研究[J]. 催化学报, 2023, 52(9): 187-195.
[8]	邹心仪, 顾均. 酸性条件下二氧化碳高效电还原策略[J]. 催化学报, 2023, 52(9): 14-31.
[9]	乔蔚, 于立策, 常进法, 杨甫林, 冯立纲. MoSe₂纳米片耦合Pt纳米颗粒用于高效双功能催化甲醇辅助水电解制氢[J]. 催化学报, 2023, 51(8): 113-123.
[10]	周波, 石建巧, 姜一民, 肖磊, 逯宇轩, 董帆, 陈晨, 王特华, 王双印, 邹雨芹. 强化脱氢动力学实现超低电池电压和大电流密度下抗坏血酸电氧化[J]. 催化学报, 2023, 50(7): 372-380.
[11]	王元男, 王立娜, 张可新, 徐靖尧, 武倩楠, 谢周兵, 安伟, 梁宵, 邹晓新. 钙钛矿氧化物在水裂解反应中的电催化研究[J]. 催化学报, 2023, 50(7): 109-125.
[12]	周纳, 王家志, 张宁, 王志, 王恒国, 黄岗, 鲍迪, 钟海霞, 张新波. 富含缺陷的Cu@CuTCNQ复合材料增强电催化硝酸盐还原成氨[J]. 催化学报, 2023, 50(7): 324-333.
[13]	李轩, 蒋兴星, 孔艳, 孙建桔, 胡琪, 柴晓燕, 杨恒攀, 何传新. GaN/In₂O₃的界面工程用于高效电催化CO₂还原制备甲酸[J]. 催化学报, 2023, 50(7): 314-323.
[14]	Sang Eon Jun, Sungkyun Choi, Jaehyun Kim, Ki Chang Kwon, Sun Hwa Park, Ho Won Jang. 用于电化学能量转换反应的非贵金属单原子催化剂[J]. 催化学报, 2023, 50(7): 195-214.
[15]	牛青, 米林华, 陈玮, 李秋军, 钟升红, 于岩, 李留义. 基于共价有机框架的单位点光(电)催化材料的研究进展[J]. 催化学报, 2023, 50(7): 45-82.