揭示NiS@Ta2O5纳米纤维中梯型电荷转移路径及光催化CO2转化性能

doi:10.1016/S1872-2067(23)64478-X

催化学报 ›› 2023, Vol. 51: 193-203.DOI: 10.1016/S1872-2067(23)64478-X

揭示NiS@Ta₂O₅纳米纤维中梯型电荷转移路径及光催化CO₂转化性能

邵秀丽^a^,¹, 李可^a^,¹, 李静萍^a, 程强^a, 王国宏^a^,^*(), 王楷^a^,^b^,^*()

^a湖北师范大学城市与环境学院, 污染物分析与资源化技术湖北省重点实验室, 黄石市土壤污染防治重点实验室, 湖北黄石435002, 中国
^b南洋理工大学化学与生物医学工程学院, 新加坡

收稿日期:2023-05-11 接受日期:2023-06-21 出版日期:2023-08-18 发布日期:2023-09-11
通讯作者: *电子信箱: wangkai@hbnu.edu.cn (王楷), wanggh2003@163.com (王国宏).
作者简介:第一联系人：¹共同第一作者.
基金资助:
国家自然科学基金(52104254);国家自然科学基金(22075072);湖北省自然科学基金(2021CFB242)

Investigating S-scheme charge transfer pathways in NiS@Ta₂O₅ hybrid nanofibers for photocatalytic CO₂ conversion

Xiuli Shao^a^,¹, Ke Li^a^,¹, Jingping Li^a, Qiang Cheng^a, Guohong Wang^a^,^*(), Kai Wang^a^,^b^,^*()

^aCollege of Urban and Environmental Sciences, Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Huangshi Key Laboratory of Prevention and Control of Soil Pollution, Hubei Normal University, Huangshi 435002, Hubei, China
^bSchool of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore

Received:2023-05-11 Accepted:2023-06-21 Online:2023-08-18 Published:2023-09-11
Contact: *E-mail: wanggh2003@163.com (G. Wang), wangkai@hbnu.edu.cn (K. Wang).
About author:First author contact:¹Contributed equally to this work.
Supported by:
National Natural Science Foundation of China(52104254);National Natural Science Foundation of China(22075072);Natural Science Foundation of Hubei Province(2021CFB242)

摘要/Abstract

摘要：

近年来,人口的快速增长和化石燃料的过度使用导致大气中的CO₂含量持续上升.光催化技术是可以解决上述问题的有效途径之一.利用光催化技术将大气中CO₂还原为以CO,CH₄,CH₃OH为代表的气相或液相碳氢燃料是解决能源危机和温室效应的有效策略.为实现高效率光催化CO₂还原反应,半导体光催化剂应具有光吸收范围广、载流子传输路径短及反应活性位点丰富等优点.一维纳米结构光催化剂结合了纳米颗粒和薄膜的优点,有利于材料在光催化反应后从体系中有效分离.特别是通过静电纺丝法制备的纳米纤维光催化剂可以组装成独特的三维网络,在光催化CO₂还原领域中更有利于光催化剂的重复使用.一维Ta₂O₅纳米纤维能够有效缩短光生电子从材料内部到材料表面的传输距离,减少电子和空穴在光催化剂中的复合.但Ta₂O₅的带隙较宽,导致光响应范围窄,而且在单一的半导体材料中,宽可见光吸收范围和强氧化还原能力难以共存.NiS是一种直接带隙硫化物半导体光催化剂,拥有较宽的光响应范围.为了提高单一Ta₂O₅纳米纤维的光催化活性和光吸收范围,构建梯型异质结已被证实是提高光催化活性的一种有前途的策略.梯型异质结不仅能有效地分离光生电子和空穴,而且有利于还原能力低的半导体导带上的电子和氧化能力低的半导体价带上的空穴复合,而氧化还原能力较强的空穴和电子分别被保留.因此,构建新型梯型NiS@Ta₂O₅异质结纤维光催化剂可以解决太阳能利用率低和光生载流子复合速率快的问题,在光催化还原CO₂领域具有重要的理论和现实意义.
本文利用简单的静电纺丝辅助离子交换策略制备了一系列梯型NiS@Ta₂O₅异质结光催化剂(标记为xNSTO, x = 10, 20, 50,代表Ni(OH)₂@Ta₂O₅中Ni(OH)₂的百分含量),采用透射电子显微镜(TEM)和能谱分析观察了光催化剂的形貌及元素分布,结果表明,二维NiS纳米片生长在一维Ta₂O₅纤维上形成均匀分布的核-壳结构.光电流、表面光电压谱及阻抗响应图谱表明,NSTO复合材料具有较高的光响应和较低的阻抗,有利于电子空穴的运输.光催化CO₂还原测试结果表明,20NSTO催化剂拥有最高的CO₂光还原活性(CO产率43.27μmol g^‒1 h^‒1;CH₄产率6.56μmol g^‒1 h^‒1).同时,催化剂经过10次循环测试后催化活性没有明显下降,说明光催化剂具有较好的稳定性.此外,界面内建电场、能带边缘弯曲和库仑协同作用促进了NiS@Ta₂O₅异质结光催化剂相对无用的电子和空穴的复合.原位辐照X射线光电子能谱测试和电子顺磁共振实验结果表明NiS@Ta₂O₅异质结光催化剂中的电子迁移遵循梯型电荷转移路径.综上,本文提供了一种简单的纳米纤维基梯型异质结光催化剂的制备方法,可以优化能带结构以促进光生载流子的分离, 从而实现高效的太阳燃料制备.

关键词: Ta₂O₅纳米纤维, 异质结, 光催化CO₂还原, 电荷分离, 梯型机理

Abstract:

Investigating the charge-transfer behavior of photocatalysts is important to promote the photoreduction of CO₂ into solar fuels. Therefore, in this study, hybrid Ta₂O₅ nanofibers were produced through the in situ growth of freestanding NiS nanosheets. The charge separation and CO₂ photoreduction mechanisms of these nanofibers were investigated using in situ X-ray photoelectron spectroscopy and density functional theory calculations. The results suggested that the NiS@Ta₂O₅ nanohybrids formed an S-scheme heterojunction, which promoted the efficient separation of electron-hole pairs and enhanced CO₂ photoreduction. Compared to the pristine Ta₂O₅ nanofibers, the hybrid nanofibers exhibited a significantly higher CO₂-reduction rate (43.27 μmol g^-1 h^-1 for CO; 6.56 μmol g^-1 h^-1 for CH₄). In situ diffuse reflectance infrared Fourier-transform spectroscopy results confirmed the process of CO₂ hydrogenation and S-scheme charge transfer pathways in NiS@Ta₂O₅ nanohybrids.

Key words: Ta₂O₅ nanofiber, Heterojunction, CO₂ photoreduction, Charge separation, S-Scheme mechanism

邵秀丽, 李可, 李静萍, 程强, 王国宏, 王楷. 揭示NiS@Ta₂O₅纳米纤维中梯型电荷转移路径及光催化CO₂转化性能[J]. 催化学报, 2023, 51: 193-203.

Xiuli Shao, Ke Li, Jingping Li, Qiang Cheng, Guohong Wang, Kai Wang. Investigating S-scheme charge transfer pathways in NiS@Ta₂O₅ hybrid nanofibers for photocatalytic CO₂ conversion[J]. Chinese Journal of Catalysis, 2023, 51: 193-203.

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链接本文: https://www.cjcatal.com/CN/10.1016/S1872-2067(23)64478-X

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图/表 9

Fig. 1. (a) Schematic for the preparation of NiS@Ta2O5 hybrid nanofibers. TEM image of (b) Ta2O5, (c) Ni(OH)2@Ta2O5 and (d) NiS@Ta2O5 hybrid nanofibers. (e) HRTEM and (f) HAADF-STEM images of 20NSTO composites and EDX mapping images of Ta, O, Ni, and S elements.

Fig. 2. PXRD patterns (a), Raman spectra (b), N2 adsorption-desorption isotherms (c), and CO2 adsorption isotherms (d) of as-prepared samples.

Fig. 3. XPS spectra of Ta 4f (a) and O 1s (b) of Ta2O5 and 20NSTO. XPS spectra of Ni 2p (c) and S 2p (d) of NiS and 20NSTO.

Fig. 4. (a) UV-vis diffuse reflectance spectra of Ta2O5, NiS, 10NSTO, 20NSTO, and 50NSTO. Tauc plots (b), VB-XPS spectra (c) and band structure (d) of Ta2O5 nanofibers and NiS nanosheets.

Fig. 5. PL (a), TRPL(b) spectra, Transient photocurrent (c), EIS Nyquist plots (d), SPV spectra (e) and LSV curves (f) of as-prepared samples.

Fig. 6. Time-dependent CH4 (a) and CO (b) production rate over as-prepared samples. Control experiments (c) and the photocatalytic cycle performance (d) of 20NSTO.

Fig. 7. CO2-TPD (a) and CO-TPD (b) profiles of Ta2O5, NiS and 20NSTO. In situ DRIFTS measurements of Ta2O5 (c) and 20NSTO (d) under full spectrum light irradiation in pure CO2.

Fig. 8. Calculated electrostatic potentials of Ta2O5 (a) and NiS (b). Planar-averaged electron density difference ρ(z) (c) and 2D charge density difference (d) for NiS@Ta2O5 heterojunction.

Fig. 9. ESR signals of Ta2O5, NiS, and 20NSTO for (a) DMPO-superoxide radical and (b) DMPO-hydroxyl radical under irradiation for 10 min, respectively. (c) Schematic illustration of NiS@Ta2O5 heterojunction.

参考文献

[1]	V. Hasija, A. Kumar, A. Sudhaik, P. Raizada, P. Singh, Q. Van Le, T. T. Le, V.-H. Nguyen, Environ. Chem. Lett., 2021, 19, 2941-2966.
[2]	R. M. Mohamed, I. A. Mkhalid, M. Alhaddad, A. Basaleh, K. A. Alzahrani, A. A. Ismail, Ceram. Int., 2021, 47, 26779-26788.
[3]	M. Tahir, B. Tahir, J. Mater. Sci. Technol., 2022, 106, 195-210.
[4]	T. Zhang, M. Maihemllti, K. Okitsu, D. Talifur, Y. Tursun, A. Abulizi, Appl. Surf. Sci., 2021, 556, 149828.
[5]	Q. Cheng, Y. Li, Z. Wang, X. Wang, G. Zhang, Appl. Catal. B, 2023, 324, 122274.
[6]	X. Wu, H. Ma, K. Wang, J. Wang, G. Wang, H. Yu, J. Colloid Interface Sci., 2023, 633, 817-827.
[7]	Y. Du, W. Chen, Z. Zhong, L. Zhou, Y. Liu, L. Yang, D. Xiong, K. Wang, Microporous Mesoporous Mater., 2023, 354, 112558.
[8]	K. Wang, H. Wang, Q. Cheng, C. Gao, G. Wang, X. Wu, J. Colloid Interface Sci., 2022, 607, 1061-1070.
[9]	G. Yang, Q. Pan, P. Yang, Y. Liu, Y. Du, K. Wang, Tungsten, 2021, 4, 28-37.
[10]	Y. Peng, B. Cheng, L. Zhang, J. Liu, J. Yu, Sens. Actuat. B, 2023, 385, 133700.
[11]	R. Niu, Q. Liu, B. Huang, Z. Liu, W. Zhang, Z. Peng, Z. Wang, Y. Yang, Z. Gu, J. Li, Appl. Catal. B, 2022, 317, 121727.
[12]	C. Cheng, J. Zhang, B. Zhu, G. Liang, L. Zhang, J. Yu, Angew. Chem. Int. Ed., 2023, 62, e202218688.
[13]	J. Zhang, J. Fu, K. Dai, J. Mater. Sci. Technol., 2022, 116, 192-198.
[14]	L. Wang, D. Wang, Y. Li, Carbon Energy, 2022, 4, 1021-1079.
[15]	N. N. Vu, S. Kaliaguine, T. O. Do, Adv. Funct. Mater., 2019, 29, 1901825.
[16]	K. Wang, Q. Wang, K. Zhang, G. Wang, H. Wang, J. Mater. Sci. Technol., 2022, 124, 202-208.
[17]	L. Liang, X. Li, J. Zhang, P. Ling, Y. Sun, C. Wang, Q. Zhang, Y. Pan, Q. Xu, J. Zhu, Y. Luo, Y. Xie, Nano Energy, 2020, 69, 104421.
[18]	S. Wageh, A. A. Al-Ghamdi, L. Liu, Acta Phys.-Chim. Sin., 2021, 37, 2010024.
[19]	T. Zhang, X. Han, N. T. Nguyen, L. Yang, X. Zhou, Chin. J. Catal., 2022, 43, 2500-2529.
[20]	B. Zhu, X. Hong, L. Tang, Q. Liu, H. Tang, Acta Phys.-Chim. Sin., 2022, 38, 2111008.
[21]	Y. Tang, J. Huang, S. Liu, D. Xiang, X. Ma, X. Yu, M. Li, Q. Guo, J. Colloid Interface Sci., 2021, 596, 468-478.
[22]	K. Wang, X. Shao, Q. Cheng, K. Li, X. Le, G. Wang, H. Wang, Solar RRL, 2022, 6, 2200736.
[23]	S. Wei, Q. Heng, Y. Wu, W. Chen, X. Li, W. Shangguan, Appl. Surf. Sci., 2021, 563, 150273.
[24]	X. Liu, C. Bie, B. He, B. Zhu, L. Zhang, B. Cheng, Appl. Surf. Sci., 2021, 554, 149622.
[25]	L. Ding, D. Li, H. Shen, X. Qiao, H. Shen, W. Shi, J. Alloys Compd., 2021, 853, 157328.
[26]	M. Wang, J. Cheng, X. Wang, X. Hong, J. Fan, H. Yu, Chin. J. Catal., 2021, 42, 37-45.
[27]	W. Zhong, X. Wu, Y. Liu, X. Wang, J. Fan, H. Yu, Appl. Catal. B, 2021, 280, 119455.
[28]	F. Xu, L. Zhang, B. Cheng, J. Yu, ACS Sustainable Chem. Eng., 2018, 6, 12291-12298.
[29]	L. Zhang, J. Zhang, H. Yu, J. Yu, Adv. Mater., 2022, 34, 2107668.
[30]	J. Wang, H. Cheng, D. Wei, Z. Li, Chin. J. Catal., 2022, 43, 2606-2614.
[31]	Z. Zhao, Z. Wang, J. Zhang, C. Shao, K. Dai, K. Fan, C. Liang, Adv. Funct. Mater., 2023, 2214470.
[32]	X. Ruan, C. Huang, H. Cheng, Z. Zhang, Y. Cui, Z. Li, T. Xie, K. Ba, H. Zhang, L. Zhang, X. Zhao, J. Leng, S. Jin, W. Zhang, W. Zheng, S. K. Ravi, Z. Jiang, X. Cui, J. Yu, Adv. Mater., 2023, 35, 2209141.
[33]	S. Wageh, A. A. Al-Ghamdi, O. A. Al-Hartomy, M. F. Alotaibi, L. Wang, Chin. J. Catal., 2022, 43, 586-588.
[34]	K. Wang, X. Shao, K. Zhang, J. Wang, X. Wu, H. Wang, Appl. Surf. Sci., 2022, 596, 153444.
[35]	Z. Zhao, X. Li, K. Dai, J. Zhang, G. Dawson, J. Mater. Sci. Technol., 2022, 117, 109-119.
[36]	B. Liu, C. Bie, Y. Zhang, L. Wang, Y. Li, J. Yu, Langmuir, 2021, 37, 14114-14124.
[37]	J. Peng, J. Shen, X. Yu, H. Tang, Zulfiqar, Q. Liu, Chin. J. Catal., 2021, 42, 87-96.
[38]	K. Wang, H. Qin, X. Shao, L. Jiang, K. Li, J. Wang, L. Zhou, Q. Cheng, G. Wang, H. Wang, Solar RRL, 2022, 7, 2200963.
[39]	H. Deng, X. Fei, Y. Yang, J. Fan, J. Yu, B. Cheng, L. Zhang, Chem. Eng. J., 2021, 409, 127377.
[40]	Y. Huang, K. Dai, J. Zhang, G. Dawson, Chin. J. Catal., 2022, 43, 2539-2547.
[41]	Q. Xu, L. Zhang, B. Cheng, J. Fan, J. Yu, Chem, 2020, 6, 1543-1559.
[42]	K. Wang, L. Peng, X. Shao, Q. Cheng, J. Wang, K. Li, H. Wang, Solar RRL, 2022, 6, 2200434.
[43]	L. Wang, B. Zhu, J. Zhang, J. B. Ghasemi, M. Mousavi, J. Yu, Matter, 2022, 5 4187-4211.
[44]	X. Wu, G. Chen, J. Wang, J. Li, G. Wang, Acta Phys.-Chim. Sin., 2023, 39, 2212016.
[45]	F. Xu, K. Meng, S. Cao, C. Jiang, T. Chen, J. Xu, J. Yu, ACS Catal., 2021, 12, 164-172.
[46]	L. Cheng, B. Li, H. Yin, J. Fan, Q. Xiang, J. Mater. Sci. Technol., 2022, 118, 54-63.
[47]	S. Li, M. Cai, C. Wang, Y. Liu, Adv. Fib. Mat., 2023, 5, 994-1007.
[48]	J. Wang, G. Wang, B. Cheng, J. Yu, J. Fan, Chin. J. Catal., 2021, 42, 56-68.
[49]	X. Shao, K. Wang, L. Peng, K. Li, H. Wen, X. Le, X. Wu, G. Wang, Colloids Surf. A, 2022, 652, 129846.
[50]	J. Yang, J. Wang, W. Zhao, G. Wang, K. Wang, X. Wu, J. Li, Appl. Surf. Sci., 2023, 613, 156083.
[51]	S. Li, C. Wang, Y. Liu, Y. Liu, M. Cai, W. Zhao, X. Duan, Chem. Eng. J., 2023, 455, 140943.
[52]	S. Cao, J. Yu, S. Wageh, A. A. Al-Ghamdi, M. Mousavi, J. B. Ghasemi, F. Xu, J. Mater. Chem. A, 2022, 10, 17174-17184.
[53]	Y. Lin, G. Huang, L. Chen, J. Zhang, L. Liu, Adv. Sustain. Syst., 2022, 7, 2200364.
[54]	S. Li, M. Cai, Y. Liu, C. Wang, R. Yan, X. Chen, Adv. Powder Mater., 2023, 2, 100073.
[55]	F. Xu, K. Meng, B. Cheng, S. Wang, J. Xu, J. Yu, Nat. Commun., 2020, 11, 4613.
[56]	S. Li, M. Cai, Y. Liu, C. Wang, K. Lv, X. Chen, Chin. J. Catal., 2022, 43, 2652-2664.
[57]	L. Zhang, Q. Shen, F. Huang, L. Jiang, J. Liu, J. Sheng, Y. Li, H. Yang, Appl. Surf. Sci., 2023, 608, 155064.
[58]	X. Fei, H. Tan, B. Cheng, B. Zhu, L. Zhang, Acta Phys.-Chim. Sin., 2021, 37, 2010027.
[59]	M. Gu, Y. Yang, L. Zhang, B. Zhu, G. Liang, J. Yu, Appl. Catal. B, 2023, 324, 122227.
[60]	Q. Shang, J. Wang, J. Yang, Z. Wang, G. Wang, K. Wang, X. Wu, J. Li, Appl. Surf. Sci., 2023, 635, 157760.
[61]	K. Wang, H. Qin, J. Li, Q. Cheng, Y. Zhu, H. Hu, J. Peng, S. Chen, G. Wang, S. Chou, S. Dou, Y. Xiao, Appl. Catal. B, 2023, 332, 122763.
[62]	K. Wang, Y. Du, Y. Li, X. Wu, H. Hu, G. Wang, Y. Xiao, S. Chou, G. Zhang, Carbon Energy, 2023, 5, e264.
[63]	Y. Li, Z. Ren, M. Gu, Y. Duan, W. Zhang, K. Lv, Appl. Catal. B, 2022, 317, 121773.
[64]	X. Wu, W. Zhang, J. Li, Q. Xiang, Z. Liu, B. Liu, Angew. Chem. Int. Ed., 2023, 62, e202213124.
[65]	K. Wang, L. Jiang, X. Wu, G. Zhang, J. Mater. Chem. A, 2020, 8, 13241-13247.
[66]	J. Li, W. Pan, Q. Liu, Z. Chen, Z. Chen, X. Feng, H. Chen, J. Am. Chem. Soc., 2021, 143, 6551-6559.
[67]	C. Luo, Q. Long, B. Cheng, B. Zhu, L. Wang, Acta Phys.-Chim. Sin., 2023, 39, 2212026.
[68]	J. Liu, B. Cheng, J. Yu, Phys. Chem. Chem. Phys., 2016, 18, 31175-31183.
[69]	Z. Wang, L. Jiang, K. Wang, Y. Li, G. Zhang, J. Hazard. Mater., 2021, 410, 124948.
[70]	K. Wang, L. Jiang, T. Xin, Y. Li, X. Wu, G. Zhang, Chem. Eng. J., 2022, 429, 132229.

揭示NiS@Ta₂O₅纳米纤维中梯型电荷转移路径及光催化CO₂转化性能

Investigating S-scheme charge transfer pathways in NiS@Ta₂O₅ hybrid nanofibers for photocatalytic CO₂ conversion

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